悬浮物对半滑舌鳎稚鱼的急性毒性效应

研究了不同浓度悬浮物对半滑舌鳎(Cynoglossus semilaevisG櫣nther)浮游阶段和伏底阶段稚鱼的急性毒性效应。实验结果表明,悬浮物对浮游阶段稚鱼的48 hLC50和96 hLC50(95%可信限)分别为588.2 mg/L(518.7~666.9 mg/L)和488.7 mg/L(428.6~557.2 mg/L),安全浓度(SC)为48.87 mg/L;水温(tw)为23℃时,对伏底阶段稚鱼的48 hLC50和96 hLC50(95%可信限)分别为3 034.6 mg/L(2769.8~3324.8 mg/L)和2117.2 mg/L(1932.1~2320.1 mg/L),SC为211.72mg/L;tw为26℃时,对伏底阶段稚鱼的48 hLC50和96 hLC50(95%可信限)分别为1684.0 mg/L(1543.4~1837.3 mg/L)和1657.1 mg/L(1522.7~1803.4 mg/L),SC为165.71 mg/L。     

化工生产企业员工提高业务素质和安全技能的探讨

针对当前化工生产企业的安全现状,分析了化工生产企业当前存在的问题及其原因,并探讨了应对这些问题的相应对策,以促进员工业务素质和安全技能水平的提高,激发员工"关爱安全,关爱生命"的本能意识。     

Can phosphate compounds be used to reduce the plant uptake of Pb and resist the Pb stress in Pb-contaminated soils？

The effects of di erent phosphate-amendments on lead (Pb) uptake, the activities of superoxide dismutase (SOD) and the level of malondialdehyde (MDA) in cauliflower (Brassica oleracea L.) in contaminated soils with 2500, or 5000 mg P2O5/kg soil of hydroxyapatite (HA), phosphate rock (PR), single-superphosphate (SSP) and the mix of HA/SSP (HASSP) were evaluated in pot experiments. Results showed that the Pb concentrations in shoots and roots decreased by 18.3%–51.6% and 16.8%–57.3% among the treatments respectively compared to the control samples. The e ciency order of these phosphate-amendments in reducing Pb uptake was as follows: HASSPt HA > SSP t PR.With the addition of SSP, HA and the mix of HA/SSP, the SOD activity in shoot was reduced markedly (P < 0.05) compared with that in the control group. For example, the SOD activities in shoot by the treatments of HASSP, SSP, and HA in 5000 mg P2O5/kg were found to be only 51.3%, 56.2%, and 56.7%, respectively. Similar e ects were also observed on the level of MDA in the shoots with a decrease in 24.5%–56.3%. The results verified the inference that phosphate compounds could be used to reduce the plant uptake of Pb and resist the Pb stress in the plant vegetated in Pb-contaminated soils.     

Characterization of organic matter in total suspended particles by thermodesorption and pyrolysis-gas chromatography-mass spectrometry

The organic matter in tropospheric aerosol plays an important role in atmospheric physical and chemical processes. The bulk of organic matter, representing a significant proportion of the total suspended particulate (TSP) mass, is bound to polymeric material whose structure and properties are largely unknown. Here we used thermodesorption gas chromatography/mass spectrometry (Td- GC/MS) to study organic compounds of low molecular mass and pyrolysis gas chromatography/mass spectrometry (Py-GC/MS) to characterize the chemical structure of macromolecules in TSP samples collected in di erent seasons from di erent sites in Guangzhou. n-Alkanes, fatty acids and nitriles were the predominant compounds in the thermodesorption products, whereas aromatics, fatty acids, nitriles and n-alkanes/alkenes were the major compounds in the pyrolysates. The results indicated that aromatics were main units in macromolecules. The fatty acids and nitriles formed from carboxylic ammonium salts were detected in both thermodesorption products and pyrolysates at a certain concentration, indicating the importance of these compounds in TSP formation. The TSP source mainly determined the occurrence of compounds in samples from urban, suburban and forest sites, whereas the TSP source and formation process maybe controlled the seasonal variation in compounds detected. High levels of nitriles in summer samples from suburban and forest sites coincide with the release of ammonium from the land and of fatty acids from vegetation at these sites.     

颗粒污泥接种UASB反应器处理废纸造纸废水的试验研究

采用颗粒污泥接种UASB厌氧反应器处理废纸造纸废水,对其可生化性及能降解程度进行研究。通过持续近2个月的运行实验可知：在进水CODCr质量浓度为2000—3000mg,L的情况下,COD容积负荷最高可达到20kg/（m3·d）左右,水力停留时间可缩短至4h,有机污染物的去除率稳定保持在80％-90％的范围内,并且运行稳定。     

低分子量有机酸对岩源磷释放的实验研究

低分子量有机酸是微生物和植物根系分泌物中重要的组成部分.采用浸泡实验比较了4种常见低分子量有机酸(草酸、酒石酸、柠檬酸、苹果酸)对巢湖北岸东部富磷地层中岩源磷的释放量,并对浸提后的部分残渣进行磷的赋存形态分析.结果表明,当有机酸浓度小于5mmol·L-1时,柠檬酸的释磷量最大;大于5mmol·L-1时,草酸和酒石酸的释磷量最大,此时释磷量与有机酸的浓度具有一定的线性关系,其增加趋势远大于浓度小于5mmol·L-1时的增加趋势,而其中草酸和酒石酸又远大于柠檬酸和苹果酸.在有机酸溶液终止pH≥4时,有机酸溶液终止pH与释磷量有较好的线性关系.在50mmol·L-1相同浓度时,草酸对各赋存形态磷转化作用均最大,酒石酸次之.而4种酸对有机磷释放率最大,均高达97%以上,对闭蓄态磷的释放率最小.     

组合人工湿地对城镇污水处理厂尾水中有机物的去除特征研究

采用物理分级和三维荧光光谱法,研究了组合人工湿地对城镇污水处理厂尾水中不同形态有机物的去除特征.结果表明,组合人工湿地对污水处理厂尾水具有较好的深度处理效果,出水水质基本可以达到国家地表水环境质量标准(GB38382-2002)Ⅲ或Ⅳ类水标准.组合人工湿地处理系统对尾水中CODCr和BOD5总体去除率分别达到35.2%和44.3%,对尾水中总有机碳(TOC)、溶解性有机碳(DOC)、颗粒有机碳(POC)的平均去除率分别为46.9%、45.9%、48.3%.组合人工湿地系统不同单元对尾水中有机物的去除贡献率存在差异,其中,潜流湿地单元对尾水中CODCr和BOD5及其不同组分有机碳的去除效率较高.试验期间,由于藻类滋生,表流湿地单元出水中有机物含量波动较大,去除效果明显降低,藻类被打捞后,出水水质明显改善.三维荧光光谱分析结果显示,各个处理单元取样点的水样三维荧光光谱均出现4个明显的荧光峰.人工湿地各单元出水溶解性有机质(DOM)中,类蛋白和类腐殖酸物质含量较高,类富里酸物质含量较低.人工湿地对类蛋白和类腐殖酸物质有较强的去除作用.     

序批式颗粒污泥系统中磷的变化和去向分析

在实验室序批式活性污泥法(SBR)处理系统中以普通活性污泥为接种污泥,采用厌氧-好氧的运行方式提高系统的除磷效果.同时培养颗粒污泥,并对系统中磷的变化和去向进行分析.结果表明,整个试验共运行146 d,成熟颗粒污泥平均粒径为603μm,污泥体积指数(SVI)约为30 mL.g-1,COD去除率可达90%,磷的去除率可达95%左右.颗粒污泥系统除厌氧放磷和好氧聚磷以外,还存在明显的污泥颗粒积磷现象.磷的去除途径主要为:系统排泥(出水悬浮物和专门排泥)和污泥积磷.由厌氧末期颗粒污泥的X射线衍射(XRD)分析结果可知,化学沉淀是污泥积磷的一种重要方式,大量的金属离子会与磷形成无机盐沉积在污泥颗粒上.     

近48a宁夏寒潮的变化特征及可能影响的成因初步分析

利用1961—2008年宁夏日温度及逐月北半球500 hPa环流特征量、北极涛动指数(AOI)和NCAR/NCEP再分析资料,对宁夏寒潮频次变化的气候特征进行了分析,并对影响其变化的可能原因进行了讨论,结果表明:宁夏寒潮活动各地差异较大,主要出现在春季;近48年,春秋季寒潮频次呈弱增加趋势,冬季呈弱减少趋势;寒潮频次与AOI、气温呈负相关,与西伯利亚高压、东亚冬季风强度及入侵中国的冷空气活动频次呈正相关,相关关系在秋冬季明显,春季不明显;在气候变暖的大背景下,从20世纪80年代末开始,随着AOI从负位相转为正位相,冬季西伯利亚高压和东亚冬季风强度的减弱使得宁夏地表温度持续升高,是宁夏冬季寒潮频次减少的可能原因;春季也有类似的变化,不同的是:20世纪80年代中期以前,西伯利亚高压对寒潮活动作用更显著,之后,随气温持续增暖,冷空气活动对寒潮频次的影响更明显;秋季,西伯利亚高压和冷空气活动对寒潮的影响更直接明显。研究还发现,进入21世纪后,随着全球持续增暖,北极涛动对西伯利亚高压和东亚冬季风的影响有所减弱。因此,北极涛动、西伯利亚高压、冷空气活动频次、东亚冬季风、气温这几者之间的相互反馈作用是宁夏寒潮频次变化的可能原因。     

海伦地区水热耦合特征及其对大豆产量的影响

农业是受气候变化影响的主要敏感行业之一,气候变暖带来的气温升高以及降水格局的改变对农作物生产有利有弊。论文基于黑龙江海伦地区1978—2004年生长季≥10℃有效积温、降水量和统计年鉴中的大豆产量数据,以积温和降水在季节上的匹配程度作为判断水热耦合的指标,采用气候波动指数、减产风险指数作为大豆产量受气候波动影响程度的指标,研究了在生长季降水量下降和≥10℃有效积温增加的趋势下水热耦合的年际和年内变化特征及其对大豆产量的影响,并分析了偏干旱、正常和湿润年份大豆产量受气候波动影响的特征和减产风险性。结果表明,大豆气候波动指数和产量减产风险指数从大到小均依次为偏干旱年、偏湿润年和正常年,说明海伦地区受气候暖干化影响较大。