超声波辅助提取杜仲籽油的工艺优化

以杜仲籽为原料,应用超声波辅助法提取杜仲籽油.在单因素试验的基础上,通过正交试验确定了超声波辅助提取杜仲籽油的较佳工艺条件.结果表明,杜仲籽油的较佳提取工艺条件为料液比12ml/g,提取温度50℃,提取时间15min,超声波功率225W,在该条件下杜仲籽油得率27.24%.     

China's Total Emission Control Policy:a Critical Review

As part of a comprehensive environmental management system, many countries establish emission control targets for mass emissions of a pollutant. Such targets are often the key objective of an environmental policy, such as an emission trading program. In China, however, it is more than just an objective of one particular policy; it has become a concept that has influenced many national environmental policies and activities. The objective of this article is to review the implementation of the total emission c...     

Food chain transfer of cadmium and lead to cattle in a lead–zinc smelter in Guizhou, China

Cadmium (Cd) and Lead (Pb) are environmental pollutants. Environmental samples and bovine tissues were collected from the areas around a lead–zinc smelter in Guizhou, China for Cd, Pb, zinc (Zn) and copper (Cu) analysis. Cd in soil (10 mg/kg) and feed (6.6 mg/kg) from the polluted areas was 10 times higher than the Chinese Standards, resulting in higher Cd in bovine kidney (38 mg/kg) and liver (2.5 mg/kg). Pb in feed (132 mg/kg) from the polluted area was much higher than unpolluted areas, causing higher Pb levels in bovine tissues. Environmental Zn was elevated, but bovine tissue Zn was normal. Cu in bovine liver decreased with increased Cd and Pb. Metals in drinking water and in bovine muscle were within the Standard range. Thus, in the areas of this lead–zinc smelter, the environment has been contaminated with Cd and Pb, which has been transferred to cattle through the food chain.     

混凝法深度处理印染废水中试研究

采用"高效混凝沉淀-过滤"深度处理工艺处理印染废水二级生化出水,并将混凝沉淀污泥回流.实验结果表明,混凝剂聚合氯化铝加入量为160 mg/L时,COD去除率平均可达34.6%,TP去除率平均达到87.9%,平均出水TP为0.3 mg/L.气相色谱-质谱分析和元素分析结果表明混凝沉淀工艺对有机物和TP的去除效果良好.     

硫酸渣制备高纯度硫酸亚铁

以高铁硫酸渣为原料,采用酸浸一还原-除杂-结晶-重结晶-干燥工艺,合成高纯度硫酸亚铁.通过反应温度、反应时闻对硫酸渣中铁的浸出率的影响,以及结晶温度、干燥温度,干燥时间、于燥时间对硫酸亚铁产品纯度的影响做分析实验,得出最佳酸浸条件:硫酸渣与硫酸的固液比为1:3,硫酸质量分数为20%-25%,反应温度为80℃,反应时间为6 h,搅拌强度为200 r/min;最佳结晶精制条件:结晶溶液pH值1:3,温度为60℃,温度海60℃;除杂最佳条件:pH值约为4.5;冷却结晶温度控制在20℃,结晶秣过程为30℃于燥6 h.     

活性炭在焦化废水深度处理中的应用研究

采用活性炭对焦化废水生化处理系统的外排水进行深度处理,实验研究了不同因素对废水COD的去除情况.结果表明,不需其他工艺辅助,仅在1 g/L的活性炭吸附20 min后即可将废水COD降到110 mg/L,出水无色澄清,符合排放要求.     

论“安全”及“安全性”的概念

对当前有关安全概念的多种定义均存在内涵或外延不准确的问题进行研讨;将与安全问题相关的客观事物区分为"可遭受损害事物"和"可导致损害事物",并分别对应于"安全"概念和"安全性"概念;在明确所涉及对象事物的基础上,对安全概念与安全性概念准确把握各自的内涵和外延,分别给出用"属加种差"方式描述的定义。笔者认为:安全是"具有特定功能或属性的事物,在内部和外部因素及其相互作用下,足以保持其正常的、完好的状态,而免遭非期望损害的现象";安全性是"某事物在一定的条件下和一定的时间内,导致其他事物或其自身发生非期望损害的能力"。     

中国出口隐含碳排放影响因素研究——基于反事实法的分析

中间消耗的"消耗规模与部门构成"是影响中国出口碳排放的重要因素。基于世界投入产出数据库(WIOD)1995—2015年数据,在部门归类与形式变换基础上,本文选取"单位产出碳排放量"、"完全消耗系数"与"出口值"为中国出口隐含碳排放的影响因子,构建"因子变动—反事实构造—效果评价"分析框架,借助规模指数与结构指数对影响因子的变化动态进行描述,并通过反事实构造对"因子变动"的影响效果进行评价。研究发现:"单位产出碳排放量"规模指数单调递减,Spearman偏度系数为右偏态,说明相比于意愿产出而言,非意愿产出"碳排放量"具有内在的规模不经济;"中间消耗"规模指数与碳偏向性指数在截面上始终处于高位水平,时序上出现了显著的递增趋势,说明中国单位出口值的中间消耗量偏大,消耗投入在结构上偏向于高碳部门,与"技术前沿国"美国存在显著"技术差距";"出口值"规模指数呈现"平缓扩张——快速攀升——V型震荡"的阶段性特征,结构指数经历了以基期2002年为顶点、"先下降、后上升、再平稳"的变化轨迹,说明"出口值"作为最具弹性的影响因子,受"亚洲金融危机"、"加入世界贸易组织"与"美国次债危机"等外部冲击的影响明显,对出口碳排放的推动作用存在伸缩性与阶段性差异。从"因子变动"影响效果来看,中国产出、中间消耗与出口的部门构成具有内生关联,均显著偏向于高碳部门,对出口隐含碳排放增长产生了叠加性的"正向"扩张效应。基于此,本文认为,总量控制与结构优化的视角需从产品环节向中间消耗环节扩展,现阶段应深化要素市场改革,加速要素禀赋升级,借力要素价格机制与差别化产业规制政策,从上游环节抑制出口碳排放的输入来源。     

华东某铀矿区稻米中放射性核素铀污染特征及健康风险评价

为查明华东某铀矿区稻米中放射性核素铀污染现状及健康风险问题,测定铀矿区和对照区共136件稻米样品中放射性核素U含量,采用单因子污染指数法评价放射性铀污染,并开展U元素健康风险评价。结果表明:(1)研究区稻米中U含量平均值为1.46 ng·g~(–1),各亚区稻米中U含量平均值从大到小顺序为:开采矿井区水冶场区含矿未采区废弃矿井区江西省背景值对照区;(2)稻米单因子污染指数为1.25,属于轻度污染。其中,开采矿井区和水冶厂区为轻度污染,废弃矿井区和对照区未受污染;(3)首次计算提出江西省大米U元素致癌风险最大斜率系数为1.04×10~3(d·kg)·mg~(–1)。各亚区稻米中成人和儿童致癌风险指数高低顺序均为:开采矿井区水冶厂区含矿未采区废弃矿井区对照区。儿童直接饮食稻米具有一定的致癌风险;开采矿井区和水冶厂区的成人存在一定致癌风险,含矿未采区和废弃矿井区以及对照区均无致癌风险。     

Arsenic and other trace elements in groundwater and human urine in Ha Nam province,the Northern Vietnam: contamination characteristics and risk assessment

The contamination characteristics of arsenic and other trace elements in groundwater and the potential risks of arsenic from the groundwater were investigated. Elevated contamination of arsenic, barium and manganese was observed in tube-well water of two villages (Chuyen Ngoai and Chau Giang) in Ha Nam province in the Northern Vietnam. Concentrations of As in the groundwater ranged from 12.8 to 884 µg/L with mean values in Chuyen Ngoai and Chau Giang were 614.7 and 160.1 µg/L, respectively. About 83 % of these samples contained As concentrations exceeding WHO drinking water guideline of 10 μg/L. The mean values of Mn and Ba in groundwater from Chuyen Ngoai and Chau Giang were 300 and 657 μg/L and 650 and 468 μg/L, respectively. The mean value of Ba concentration in groundwater in both Chuyen Ngoai and Chau Giang was about 22 % of the samples exceeded the WHO guideline (700 µg/L). Arsenic concentrations in human urine of residents from Chuyen Ngoai and Chau Giang were the range from 8.6 to 458 µg/L. The mean values of Mn and Ba in human urine of local people from Chuyen Ngoai were 46.9 and 62.8 μg/L, respectively, while those in people from Chau Giang were 25.9 and 45.9 μg/L, respectively. The average daily dose from ingesting arsenic for consuming both untreated and treated groundwater is from 0.02 to 11.5 and 0.003 to 1.6 μg/kg day, respectively. Approximately, 57 % of the families using treated groundwater and 64 % of the families using untreated groundwater could be affected by elevated arsenic exposure.