The concentrations, distribution and sources of PAHs in agricultural soils and vegetables from Shunde, Guangdong, China

The concentrations, distribution and sources of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in 30 agricultural soil and 16 vegetable samples collected from subtropical Shunde area, an important manufacturing center in China. The total PAHs ranged from 33.7 to 350 μg/kg in soils, and 82 to 1,258 μg/kg in vegetables. The most abundant individual PAHs are phenanthrene, fluoranthene, chrysene, pyrene and benzo(b)fluoranthene for soil samples, and anthracene, naphthalene, phenanthrene, pyrene and chrysene for vegetable samples. Average vegetable–soil ratios of total PAHs were 2.20 for leafy vegetables and 1.27 for fruity vegetables. Total PAHs in vegetable samples are not significantly correlated to those in corresponding soil samples. Principal component analyses were conducted to distinguish samples on basis of their distribution in each town, soil type and vegetable specie. Relatively abundant soil PAHs were found in town Jun’an, Beijiao, Chencun, Lecong and Ronggui, while abundant vegetable PAHs were observed in town Jun’an, Lecong, Xingtan, Daliang and Chenchun. The highest level of total PAHs were found in vegetable soil, followed by pond sediment and “stacked soil” on pond banks. The PAHs contents in leafy vegetables are higher than those in fruity vegetables. Some PAH compound ratios suggest the PAHs derived from incomplete combustion of petroleum, coal and refuse from power generation and ceramic manufacturing, and paint spraying on furniture, as well as sewage irrigation from textile industries. Soil PAHs contents have significant logarithmic correlation with total organic carbon, which demonstrates the importance of soil organic matter as sorbent to prevent losses of PAHs.     

Distribution, sources, and potential risk of polycyclic aromatic hydrocarbons (PAHs) in drinking water resources from Henan Province in middle of China

Distribution and risk assessment of polycyclic aromatic hydrocarbons (PAHs) in drinking water resources have been carried out for the first time in Henan Province, China. Water samples collected from four river systems and their tributaries, as well as groundwater resources, were analyzed according to EPA method 525.2. Total of 68 water samples were collected in 18 cities in Henan province in May, August and November, 2001. Concentrations of sum of 16 priority PAHs in water samples ranged from 15 to 844 ng/L with a mean value of 178 +/- 210 ng/L (n = 68). The spatial and temporal distribution of PAHs showed that the Huanghe and the Huaihe river systems had relatively higher concentrations of total PAHs. Higher concentrations of total PAHs were observed in August and November than in May, with respective mean values of 262, 232 and 33.6 ng/L. Ratios of Ant/(Ant + Phe) and Flur/(Flur + Pyr) were calculated to evaluate the possible sources of PAH contamination, which indicated that the coal combustion sources were the main contributors to PAHs in most drinking water resources. Some petrogenic (or pyrolytic) sources of PAHs were also found. The toxic equivalency factors (TEFs) were used to calculate benzo[a]pyrene equivalents (BaPE) for water samples. The average value of BaPE was 0.6 ng/L. The values in most stations were much lower than the guideline values in drinking water of Chinese Environmental Protection Agency (CEPA, 2.8 ng/L) and the US Environmental Protection Agency (US EPA, 200 ng/L). Overall, the drinking water resources in Henan province showed some carcinogenic potential.     

羊八井地热区典型植物对氟的吸附富集特征探究

采用水浴提取法处理羊八井地热区土壤和植物样品中可溶性氟,并用离子选择性电极法测定提取液及地热水中的氟。结果表明,地热水中氟离子最高为162 mg/L,土壤和植物中水溶性氟分别为347 mg/kg~937 mg/kg和189 mg/kg~164 mg/kg。氟离子在不同植物中的分布差异较大,嵩草属植物富集氟离子的能力最强,故可利用植物修复技术对高氟地热水、土壤净化处理,以降低氟污染。     

用Ames试验检测水源水和自来水中的遗传毒性

用微伤寒沙门氏菌／哺乳动物微粒体酶系的Ａｍａｅｓ试验,研究了不同季节物水源水及管网自来水中的遗传毒性,以ＸＡＤ２树脂为吸附剂,以丙酮－甲醇的混合液为洗脱液,浓率水样中的有机物,并对部分阳性水样进行有机成分的定性分析。结果发现：１３个水样中有７个样品在淡需要代谢活化系统Ｓ９的情况下,可诱导鼠伤寒沙门氏菌碱基移码型菌株的回复突变;不同水样在不同季节不同的诱导作用;同时通过ＧＣ／ＭＳ方法分析,发现阳性水     

街道峡谷内车辆流动对反应性污染物传播特性影响的模拟研究

采用CFD（计算流体力学）数值模拟的研究方法,使用动网格技术,分析简单光化学反应下车辆流动及不同来流风速对双车道三维街道峡谷内污染物传播特性的影响.结果表明,车辆移动改变了峡谷内气流结构,以及背风侧与迎风侧活性污染物浓度分布的相对大小,有利于污染物在峡谷中的传播扩散;来流风使机动车尾气向建筑背风侧汇聚,并随着风速增加而加强,对近迎风侧车道车辆尾气淹没射流的影响比近背风侧车道大.在车辆移动与来流风的综合作用下,污染物的扩散能力得到显著增强.     

防烟空气幕防烟有效性模拟实验研究

利用火灾模拟软件FDS,以四川消防研究所高层实验塔二层为原型建立模型,对防烟空气幕的防烟有效性进行研究。本次实验在前室内设置测点,测定前室内的温度及CO浓度。实验结果表明:在未设置防烟空气幕时,前室内1.25m高度以上的测点温度稳定后均在35～45℃之间,CO浓度最大达到180ppm;在设置风幕后,前室内1.25m高度以上的测点温度稳定后在20～30℃之间,CO浓度最大为75.7ppm。因此,防烟空气幕能有效的减少烟气的进入量,降低进入前室的烟气的温度及有害气体浓度,为人员的安全疏散赢得时间。     

一起瓦斯事故后的思考

介绍了峰峰集团公司小屯矿14443回采工作面基本情况和瓦斯事故发生及处理经过,分析了事故原因,针对该事故从5个方面提出值得思考的问题.     

建设项目竣工验收监测中环保设施运行效益分析

本文针对建设项目环境保护设施竣工验收监测，指出对环保设施运行进行效益分析的必要性，并根据河南省环境监测中心站在竣工验收监测中收益分析的实践，提出了效益分析的一般思路，并给出环保设施运行效益分析的实例。     

减排措施与气象因子对2013—2019年中国大陆地区PM2.5浓度变化的贡献

利用地面气象观测站数据计算的大气自净能力指数（Atmospheric Self-cleaning ability Index，简称ASI）和环境监测站PM_2.5实测数据，评估了中国大陆地区2014—2019年相对于2013年（"大气国十条"实施初期）污染物总体排放率的相对变化，给出了PM_2.5浓度削减量中气象条件和减排措施的相对贡献.研究结果显示，2014年全国排放率总体已下降，2017年各地区全面实现减排，较2013年全国平均减排36.11%，2019年减排幅度进一步加大，至48.50%，其中中东部地区整体减排力度大于西部和东北部地区.2015和2016年秋冬，重点区域持续性重污染频发现象的出现是不利气象条件背景与减排略有放松共同作用的结果，但持续的减排措施对于遏制空气质量的恶化起到了积极作用.2019年，京津冀、汾渭平原、长三角等9个重点区域PM_2.5浓度相较2013年明显降低，高空气质量至少一半以上的原因来源于人为减排，气象因子的贡献相对较小，仅为3%~18%，一些区域气象因子对PM_2.5的改善甚至起到负作用.2013年"大气国十条"实施以来，全国各重点区域有效的污染排放控制确实对空气质量改善起到了决定性作用.本文研发的分离气象和减排措施对PM_2.5浓度变化中相对贡献的方法，使用的定量关系简单、明确，所使用的数据客观、可靠，有利于快速估算和决策.     

车辆悬架螺旋弹簧断裂失效行为研究

目的 判定车辆悬架螺旋弹簧失效的原因,提出改进措施.方法 通过分析和测试其化学成分、氢含量、非金属夹杂物、力学性能、金相组织、断口形貌等,研究车辆悬架螺旋弹簧的失效行为.结果 试件弯曲变形内侧的剪切应力值最大,容易引起应力集中.材料最后断裂区为韧窝和沿晶的混合断裂,且断后伸长率偏低.喷丸并未完全去除脱碳层及表层的其他原始缺陷,表层形成疲劳缺陷的可能性增高.喷丸造成螺旋弹簧表层存在较深的凹坑,凹坑边缘形成明显凸起棱边,引起应力集中,且材料表层存在折叠缺陷.在循环应力作用下,凹坑处折叠缺陷端部首先成为裂纹萌生点,在循环应力作用下,裂纹持续扩展,最终疲劳断裂.结论 减小钢丸粒径,降低喷丸压力,以避免过深的凹坑及尖锐的凸起棱边,并适当增加喷丸过程的表层去除深度;调整热处理工艺,适度降低材料强度、提高韧性,使断后伸长率大于10％.改进轧制工艺,消除材料的折叠缺陷,加强材料缺陷检测.