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141.
Antifouling biocides are used to prevent the settlement and growth of organisms on submerged surfaces. Irgarol 1051 is currently among the most widely used organic booster biocides worldwide. This study reports Irgarol 1051, its major metabolite M1 (aka GS26575), and diuron concentrations found in selected California marinas. Seasonal water samples (n = 46) were collected during the summer and fall of 2006 from eleven marinas throughout Southern and Northern California. The samples were extracted using solid phase extraction and analysed utilizing liquid chromatography tandem mass spectrometry (LC-MS-MS) with electrospray ionization. All three compounds were detected in all samples, representing a 100% frequency of occurrence and indicating widespread use around the sampled marinas. Irgarol concentrations ranged from 12 to 712 ng L(-1) (average 102 ng L(-1)), M1 concentrations were 1-217 ng L(-1) (average 31 ng L(-1)), and diuron concentrations were 5-27 ng L(-1) (average 13 ng L(-1)). In general, concentrations of both Irgarol (15-712 ng L(-1)) and M1 (1-217 ng L(-1)) were greater in samples collected during the summer, corresponding to the peak of the boating season. The detected diuron concentrations in most cases were greater for fall samples (7-27 ng L(-1)), and probably represented a combination of non-agricultural (rights of way) and agricultural applications of diuron in California. The maximum Irgarol concentration detected in California marinas in summer 2006 (712 ng L(-1)) was five times greater than the Irgarol concentration suggested as the plant toxicity benchmark (136 ng L(-1)). Twenty three percent of samples from California marinas in this study exceeded this benchmark, suggesting that detected Irgarol concentrations may be high enough to cause changes in phytoplankton communities in the sampled marinas.  相似文献   
142.
Polybrominated diphenyl ethers (PBDEs), organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), and polycyclic aromatic hydrocarbons (PAHs) in 25 surface sediments in three cities (Nantong, Wuxi, and Suzhou) in the Yangtze River Delta, eastern China were measured. The mean concentrations were 378, 45.8, 1.98, 4,002 ng/g for PBDEs, OCPs, PCBs, and PAHs, respectively. Their levels in the sediments in the three cities were generally consistent with the city industrialization. PBDEs and OCPs were markedly dominated by deca-BDE (>90 %) and DDTs (>70 %). A principle component analysis of the analytes identified three major factors suggesting different sources of the contaminants in the sediments. PBDEs and the organic carbon in the sediments have common sources from industrial activities; whereas OCPs and PCBs, correlated with the second factor, were mainly from historical sources. The third factor with loadings of PAHs is indicative of various combustion sources. Ecological risk assessment indicated that the potential highest risk is from DDTs, for which 22 sites exceed the effects range low (ERL) values and three sites exceed the effects range median (ERM) value.  相似文献   
143.
采用CFD(计算流体力学)数值模拟的研究方法,使用动网格技术,分析简单光化学反应下车辆流动及不同来流风速对双车道三维街道峡谷内污染物传播特性的影响.结果表明,车辆移动改变了峡谷内气流结构,以及背风侧与迎风侧活性污染物浓度分布的相对大小,有利于污染物在峡谷中的传播扩散;来流风使机动车尾气向建筑背风侧汇聚,并随着风速增加而加强,对近迎风侧车道车辆尾气淹没射流的影响比近背风侧车道大.在车辆移动与来流风的综合作用下,污染物的扩散能力得到显著增强.  相似文献   
144.
Results of breeding bird censuses in 1979 and 1980 were used to compare the relationships of both species and guilds to forest habitats in the White Mountains of New Hampshire. Several age classes of 11 forest cover types were studied: northern hard-woods (Fagus-Betula-Acer), spruce (Picea), spruce-fir (Picea-Abies), birth (Betula), swamp hardwoods (Acer-Pinus-Tsuga), pine (Pinus strobus andP. resinosa), balsam fir (Abies), aspen (Populus tremuloides andP. grandidentata), northern red oak (Quercus), oak-pine (Quercus-Pinus), and hemlock (Tsuga). All types were even-aged; only northern hardwoods had an additional uneven-aged condition. Forest cover types were also pooled to consider generalized habitats: hardwoods, mixed forest, or softwoods. Results of ordinations based on censuses of 74 bird species indicate that foraging guilds are more related to general cover types than are nesting substrate guilds, but bird species reflect habitat differences to a greater degree than do either guild scheme. Also, considerable overlap occurs in bird species distribution between hardwoods and mixed forests; softwoods show little overlap with other types. Discriminant function and classification analyses revealed that bird species composition can be used to correctly classify general forest habitats more accurately (83.8%) than either foraging (63.2%) or nesting substrate guilds (58.4%). These results indicate that, of the habitats studied, avian species compositions are more characteristic than are foraging or nesting substrate guild composition, which tend to be similar across forest habitats.  相似文献   
145.
Flood area and damage estimation in Zhejiang,China   总被引:1,自引:0,他引:1  
A GIS-based method to estimate flood area and damage is presented in this paper, which is oriented to developing countries like China, where labor is readily available for GIS data collecting, and tools such as, HEC-GeoRAS might not be readily available. At present local authorities in developing countries are often not predisposed to pay for commercial GIS platforms. To calculate flood area, two cases, non-source flood and source flood, are distinguished and a seed-spread algorithm suitable for source-flooding is described. The flood damage estimation is calculated in raster format by overlaying the flood area range with thematic maps and relating this to other socioeconomic data. Several measures used to improve the geometric accuracy and computing efficiency are presented. The management issues related to the application of this method, including the cost-effectiveness of approximate method in practice and supplementing two technical lines (self-programming and adopting commercial GIS software) to each other, are also discussed. The applications show that this approach has practical significance to flood fighting and control in developing countries like China.  相似文献   
146.
通过对松花江河冰的物理力学性能试验和松花江公路大桥桥墩的流冰动压力测量、桥面的脉动测量 ,依据国内外对冰 -结构相互作用的分析 ,提出了适合我国黑龙江冰情特点的春季流冰冰荷载的计算方法。  相似文献   
147.
灾害保险是筹措防灾救灾资金的重要手段.本文运用委托-代理理论建立了自然灾害的保险模型,对自然灾害的最优保险合同和保险费率进行了研究,为开展自然灾害的保险业务提供了理论依据.  相似文献   
148.
149.
从区域可持续发展的观点出发,根据湖北省具体区域特征,通过构建湖北省区域可持续发展指标体系和评估方法,得出湖北省12个地市人口、资源、环境、经济和社会5个系统的可持续发展指数以及区域综合可持续发展指数。从总体上看,湖北省区域可持续发展水平处于偏低水平,其中武汉市是唯一具有强可持续发展能力的城市,但优势地位不明显;其它城市可持续发展5个系统均存在发展不平衡状况,且城市特色不突出。  相似文献   
150.
在考虑人为恐怖袭击行为情况下,采用地铁轨道区模型实体火灾试验研究了地铁轨道区的火灾场景。得出了模拟地铁轨道区在火灾中的热释放速率,烟气浓度,温度,烟密度的变化规律。通电模拟短路以致引燃方式着火的最大热释放速率为9.66kW。浇洒煤油方式点火,轨道区最大热释放速率达到了204kW。随着电缆的点燃,燃烧进行的较为缓慢,烟气上升至隧道顶,沿着顶部向开口外扩散。C02的浓度变化较为缓慢。至10’41″达到c02释放峰值5027.7ppm;至10’41″时C0浓度达到最大354.0ppm。在轨道区问燃烧过程中,高温烟气始终沿着隧道顶部扩散,低于1.5m的空间是相对安全的;高于1.7m的空间是相对危险区域。火灾中烟气是首先弥漫整个房顶,然后再往下漫延的。  相似文献   
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