炼油工业废水局部零排放技术策略

针对我国部分炼油企业含盐废水难以达标排放这一现状,从实际情况出发,提出部分废水实施零排放处理的措施。分析了炼油废水实施零排放处理诸方面的问题,并围绕"预处理—减量化—深度浓缩—分盐结晶"的技术路线进行了探讨。     

硫化氢捕消剂的应用试验研究

针对硫化氢气体的特点,研制了在泄漏事故中用于清除硫化氢气体的硫化氢捕消剂;开展了密闭空间和开放空间硫化氢清除应用试验,结果表明,硫化氢捕消剂能够有效地清除泄漏在空气中的硫化氢气体。     

核电厂厂址保护范围与要求探讨

核电厂厂址选择需要综合考虑各种自然和人为因素,一种宝贵的稀缺资源,考虑核电的长远规划,为防止由于人为因素使核电厂厂址及其周围环境条件遭到破坏,有必要采取有效的措施对核电厂厂址实施保护。核电厂厂址保护内容主要涉及核电厂安全、事故应急条件以及环境相容性等方面,保护范围可分为拟征地范围和非居住区、规划限制区、外围地带等,其中拟征地范围和非居住区是厂址保护中最为核心的区域,应当予以重点保护。通过对相关的保护范围和要求展开探讨,以期对今后核电厂厂址确定相关保护范围和要求具有一定的参考意义。     

济南市大气污染防治三区划定研究

根据《山东省区域性大气污染物综合排放标准》(DB37/2376-2013)实施要求,开展济南市市域范围大气污染防治三区划定。划定过程以地理信息系统空间分析技术为手段,根据各区域大气环境承载力、人口密度分布和生态环境敏感程度三个因素的空间分布差异,实现三区划分,形成划定初步方案。同时,结合相关规划和重点企业/工业园区空间布局状况,对初步划定方案进行调整,形成三区划定最终方案,并在此基础上提出各分区大气污染控制措施。     

中国矿业大学南湖校区噪声污染等级监测研究

以中国矿业大学南湖校区为例,采用分功能区监测布点的方法对校园各功能区人群密集地点的噪声污染等级进行监测和分析,以探明大学校园内各功能区人员密集时噪声所能达到的最大声级,并进行评价分析.结果表明:在人流密集状态下,校园内的各测点噪声等级均在60dB以上,处于噪声超限状态.故虽然校园内各测点全天的等效声级不超限或基本达到《声环境质量标准》(GB 3096-2008)的要求,但实质上校园声环境却时常处于"亚健康"状态.     

Ca and OH release of ceramsites containing anorthite and gehlenite prepared from waste lime mud

Lime mud is a kind of solid waste in the papermaking industry, which has been a source of serious environmental pollution. Ceramsites containing anorthite and gehlenite were prepared from lime mud and fly ash through the solid state reaction method at 1050°C. The objective of this study was to explore the efficiency of Ca^2 + and OH⁻ release and assess the phosphorus and copper ion removal performance of the ceramsites via batch experiments, X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that Ca^2 + and OH⁻ were released from the ceramsites due to the dissolution of anorthite, gehlenite and available lime. It is also concluded that gehlenite had stronger capacity for Ca^2 + and OH⁻ release compared with anorthite. The Ca^2 + release could be fit well by the Avrami kinetic model. Increases of porosity, dosage and temperature were associated with increases in the concentrations of Ca^2 + and OH⁻ released. Under different conditions, the ceramsites could maintain aqueous solutions in alkaline conditions (pH = 9.3–10.9) and the release of Ca^2 + was not affected. The removal rates of phosphorus and copper ions were as high as 96.88% and 96.81%, respectively. The final pH values of both phosphorus and copper ions solutions changed slightly. The reuse of lime mud in the form of ceramsites is an effective strategy.     

Preparation,Characterization, and Rapid Adsorption of Hg<Superscript>2+</Superscript> on Nanoscale Aramid-based Adsorbent

A series of nanaoscale aramid-based adsorbents were prepared by the functionalization of poly (p-phenylene terephthalamide) (PPTA) with different content of ethylenediamine (EDA). Their structures were characterized by field emission scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis, and elemental analysis. Metal ions, including Hg²⁺, Pb²⁺, Ag⁺, Cu²⁺, Cd²⁺, and Ni²⁺ were chosen as the models to explore the binding behaviors of PPTA–ECH–EDA in aqueous medium. Results showed that PPTA–ECH–EDA exhibited higher adsorption capacity for Hg²⁺ due to their nanoscale structures. In particular, the adsorption rate was so high that equilibrium was achieved within 15 min for Hg²⁺. The adsorption of Hg²⁺ on PPTA–ECH–EDA followed the pseudo second-order model well. Langmuir and Freundlich models were employed to fit the isothermal adsorption, and the results revealed that Freundlich isotherm was a better model to predict the experimental data. The adsorption mechanism was revealed by X-ray photoelectron spectroscopy. It is preconceived that PPTA–ECH–EDA could be used as an effective adsorbent for fast removal of heavy ions from wastewater.     

BiPO_4-BiVO_4复合光催化剂的制备及其光催化性能

采用水热法制备了BiPO_4-BiVO_4复合光催化剂,运用XRD,SEM,UV-Vis DRS技术对其进行了表征,并以亚甲基蓝为目标降解物考察了复合光催化剂在模拟太阳光下的光催化性能。实验结果表明:当BiPO_4与BiVO_4的摩尔比(磷钒比)为2∶8时BiPO_4-BiVO_4的光催化性能最优,光照180 min时对亚甲基蓝(初始质量浓度5mg/L)的降解率达96.20%,反应速率常数为0.018 1 min-1,明显优于单纯BiPO_4和BiVO_4。表征结果显示:单斜相的BiPO_4与BiVO_4晶粒实现了复合生长,BiPO_4-BiVO_4(磷钒比2∶8)的晶粒粒径比单纯BiPO_4和BiVO_4小;复合光催化剂在紫外光和可见光区均具有较好的光响应,且其禁带宽度较BiPO_4明显减小。     

开封市公园灰尘重金属含量及潜在生态风险

采集河南省开封市区4个典型公园(清明上河园、龙亭公园、铁塔公园、相国寺)52个地表灰尘样品,采用原子荧光(AFS)法、电感耦合等离子体发射光谱法(ICP)和电感耦合等离子体质谱(ICP-MS)法测定灰尘重金属含量,并用调整后的Hkanson潜在生态危害分级标准对重金属潜在生态危害进行评价。结果表明:灰尘Cd、Hg、Pb、Zn、Cu富集显著。重金属单项生态风险指数(E)顺序为HgCdPbCuNiZnCoCrMnTi,除Hg和Cd出现强烈以上生态风险外,其他重金属风险轻微。所有公园灰尘重金属潜在生态总风险(RI)均在很强等级以上,其大小依次为RI相国寺RI龙亭公园RI铁塔公园RI清明上河园。灰尘Hg和Cd对RI的平均贡献率分别为45.28%和46.77%,是最主要的风险因子。     

滨州市生态环境质量综合评价研究

随着社会经济的迅速发展,生态环境问题,特别是城市生态环境问题日益突出.依据生态城市建设的相关理论,采用层次分析法,通过建立城市生态环境质量评价指标体系和适宜度模型,对滨州市生态环境质量进行现状评价与分析.结果表明,滨州市生态环境质量现状综合指数为Ⅰ级,近五年波动提升趋势明显;但各指标发展不平衡,适宜度指数差异明显.针对生态环境质量存在的问题,参考国内外改善城市生态环境质量的措施,提出相应意见及建议,从而为滨州及同类城市生态环境建设提供一定借鉴.