The variability of PCDD/F concentrations in the effluent of wastewater treatment plants with regard to their hydrological environment

The occurrence, concentrations, patterns, and loads of 17 2,3,7,8-substituted congeners of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were determined in treated wastewater collected at the outlets from 14 wastewater treatment plants (WTPs), divided into three size categories. The analysis also considered the effect of wastewater outflow on the final concentrations of PCDDs/Fs, as the samples were collected during flooding and stable hydrological conditions. None of the studied WTPs were found to completely remove toxic congeners of PCDDs/Fs from wastewater: the PCDD concentrations in the outgoing effluent during stable wastewater flow ranged from 2.99 to 177.19 pg/L, PCDFs from 6.05 to 51.30 pg/L, and the Toxic Equivalent (TEQ) was between 0.94 and 4.87 pg/L. The results from high wastewater flow were less diversified, ranging from 5.04 to 8.85 pg/L for PCDDs, from 11.47 to 32.33 pg/L for PCDFs and from 2.00 to 4.65 pg/L for TEQ. The smallest WTPs demonstrated the highest average total and TEQ concentrations due to limited volume, short retention time and outdated technology, and, hence, insufficient treatment efficiency. The largest WTPs have the potential to substantially affect the quality of river water, as despite being associated with the lowest concentrations, they released much greater volumes of treated wastewater and, hence, the greatest amounts of analyzed compounds. Elevated TEQ values were observed at high flow in all WTP size categories indicating the impact of high and stable wastewater flow on the concentrations of the observed PCDDs/Fs.     

Behavior of fluopyram and tebuconazole and some selected pesticides in ripe apples and consumer exposure assessment in the applied crop protection framework

The supervised field trials were conducted in a commercial apple orchard in 2016. The trials were an attempt to determine a model for dissipation and toxicological evaluation of fluopyram, tebuconazole, captan, tetrahydrophthalimide (THPI), pirimicarb, spirodiclofen, and boscalid residues detected in fruit of Red Jonaprince, Lobo, and Gala varieties immediately before harvest. The analysis also covered amounts of pesticides still present in remnants of calyx in Lobo and Gala varieties immediately before harvest. Laboratory samples of ripe apples were collected within 14 days of the treatment. Levels of pesticide residues detected in the samples changed at a constant exponential rate, and the residue levels found in ripe apples of Red Jonaprince, Gala, and Lobo varieties immediately before harvest were below maximum residue levels (MRL). Overall, captan residues in remnants of calyx were at a level of 22.3% for the Gala variety and 9.3% for the Lobo variety. Likewise, the long-term daily intake of the detected substances by a Polish adult consumer was low, ranging from 0.02% ADI for pirimicarb to 0.72% ADI for captan.     

Prenatal exclusion of metachromatic leukodystrophy by estimation of arylsulphatase a activity in chorion and cultured amniotic fluid cells

Chorion biopsy specimens were used for prenatal assay of arylsulphatase A activity in a pregnant woman whose two children had died from metachromatic leukodystrophy (MLD). As in two subsequent pregnancies chorion arylsulphatase A was in the control range, it was concluded that both fetuses were healthy. Absence of MLD in the fetus from the first pregnancy was confirmed after assay of arylsuphatase A activity in fetal organs. The second pregnancy resulted in delivery of a healthy child.     

Association between resiliency and posttraumatic growth in firefighters: the role of stress appraisal

The purpose of this study was to establish the relation between resiliency and the level of positive changes, comprising posttraumatic growth in a group of firefighters experiencing job-related traumatic events and the mediating role of stress appraisal in this relation. The study was performed on a group of 100 firefighters from firefighting and rescue brigades, out of which 75 admitted to experiencing a traumatic event. Firefighters covered by the study were on average 31.51 years old (SD?=?6.34). A Polish version of Posttraumatic Growth Inventory, the Resiliency Assessment Scale and Stress Appraisal Questionnaire were used in the study. The results have shown that 22.7% of firefighters displayed low, 58.6% average and 18.7% high intensity of positive changes resulting from a traumatic event. Resiliency poorly correlates with posttraumatic growth expressed in changes in self-perception, and strongly correlates with stress appraisal, negatively correlates with threat and harm/loss and positively correlates with challenge. Appraisal of stress as a threat and challenge appeared to be mediators of the relationship between resiliency and posttraumatic growth.     

The transfer of active ingredients of insecticides and fungicides from an orchard to beehives

This investigation was undertaken to determine whether active ingredients (AIs) of currently recommended plant protection products (PPPs) could be transferred to beehives from apple and pear trees. A field trial was carried out with apple trees of Ligol and Idared variety, and pear trees of Conference variety. For pest and diseases control of fungal origin, recommended PPPs were applied. Samples of flowers from the above-mentioned varieties of fruit trees, of bees, brood and honey from beehives located in their direct neighborhood were collected regularly and analyzed for the presence of lambda-cyhalothrin (an insecticide) and cyprodinil, captan, fluopyram, kresoxim-methyl, penthiopyrad and trifloxystrobin (fungicides). In samples of flowers of Ligol variety, fluopyram residues (on average 0.621 µg single flower^?1) were at the highest levels, whereas in samples of pear flowers of Conference variety, and in flowers of Idared variety, captan residues (on average, respectively, 0.705 and 165.7 µg single flower^?1). In samples of bees and honey, residues of five AIs were detected, and in brood six AIs, whereby in each case captan residues prevailed, respectively, up to 585.2, 51.52 and 126.5 µg kg^?1 bees and honey. In the honey, significantly larger residues of captan were found out than maximum residue level (MRL) for this AI – 103.04% MRL. In the case of any AI, the daily intake did not exceed 0.002% acceptable daily intake (ADI).     

Life cycle assessment of hydrotreated vegetable oil from rape,oil palm and Jatropha

A life cycle assessment of hydrotreated vegetable oil (HVO) biofuel was performed. The study was commissioned by Volvo Technology Corporation and Volvo Penta Corporation as part of an effort to gain a better understanding of the environmental impact of potential future biobased liquid fuels for cars and trucks. The life cycle includes production of vegetable oil from rape, oil palm or Jatropha, transport of the oil to the production site, production of the HVO from the oil, and combustion of the HVO. The functional unit of the study is 1 kWh energy out from the engine of a heavy-duty truck and the environmental impact categories that are considered are global warming potential (GWP), acidification potential (AP), eutrophication potential (EP) and embedded fossil production energy. System expansion was used to take into account byproducts from activities in the systems; this choice was made partly to make this study comparable to results reported by other studies. The results show that HVO produced from palm oil combined with energy production from biogas produced from the palm oil mill effluent has the lowest environmental impact of the feedstocks investigated in this report. HVO has a significantly lower life cycle GWP than conventional diesel oil for all feedstocks investigated, and a GWP that is comparable to results for e.g. rape methyl ester reported in the literature. The results show that emissions from soil caused by microbial activities and leakage are the largest contributors to most environmental impact categories, which is supported also by other studies. Nitrous oxide emissions from soil account for more than half of the GWP of HVO. Nitrogen oxides and ammonia emissions from soil cause almost all of the life cycle EP of HVO and contribute significantly to the AP as well. The embedded fossil production energy was shown to be similar to results for e.g. rape methyl ester from other studies. A sensitivity analysis shows that variations in crop yield and in nitrous oxide emissions from microbial activities in soil can cause significant changes to the results.     

White rot fungi can be a promising tool for removal of bisphenol A,bisphenol S,and nonylphenol from wastewater

Environmental Science and Pollution Research - Endocrine-disrupting chemicals (EDC) are a wide group of chemicals that interfere with the endocrine system. Their similarity to natural steroid...