Geochemical speciation of trace metals in sediments of the northern Nile Delta Lake by sequential extraction technique

ABSTRACT

The present study was performed to investigate surface sediment samples from Lake Edku of the Nile Delta Lagoons, Egypt. The Lake is important for fishing in the region. The importance of research is to understand the mobility and bioavailability of each studied metal. The study was carried out on 10 sampling sites during 2017. The sediments were subjected to the technique of sequential extraction to examine the chemical forms of some trace metals (Fe, Mn, Zn, Cu, Pb and Ni). Five stage extractions were done as the following order: soluble and exchangeable, carbonate, iron and manganese oxides, organic matter fraction and residual fraction. Attained results from the five fractions showed variations in the concentrations of metal contents of different sites under study. The overall metal concentrations (%) in the initial four extractable fractions (exchangeable, carbonate, oxides and organic matter fractions) were assessed to configure the mobility of each studied metal. The risk assessment code (RAC) represents the summation of exchangeable and carbonate fractions, it was between low and medium risk for aquatic environment. The range percentage of RAC for the metals was in the following order: 1.8–13, 4–23.5, 15–26, 5.7–19.5, 9–25 and 4.8–18.2 for Fe, Mn, Zn, Cu, Pb and Ni, respectively. Approximately 30% of the total copper was associated to the organic fraction, which may represent a high mobility of copper in these sediments. The highest mobility of metals in the sediments could be confirmed by its bioavailability factor (BF), which was within the ranges of 0.32–0.61, 0.36–0.59, 0.64–0.83, 0.36–0.72, 0.37–0.62 and 0.52–0.78 for Fe, Mn, Zn, Cu, Pb and Ni, respectively. The BF exhibited the following order: Zn > Ni > Cu > Pb ≈ Mn?>?Fe. The high levels of BF for the studied metals may represent the potentiality for toxic metals to be easily released into the aquatic environment.     

Biosurfactant electrospun nanofibers exhibit minimal side effects on the structure and function of the liver tissue in male rat model

Environmental Science and Pollution Research - Oil spills can result in significant damage to marine estuaries, rivers, lakes, wetlands, and shorelines. Electrospun nanofibers containing...     

In situ evaluation of the genotoxic potential of the river Nile: I. Micronucleus and nuclear lesion tests of erythrocytes of Oreochromis niloticus niloticus (Linnaeus, 1758) and Clarias gariepinus (Burchell, 1822)

This study aimed to investigate the genotoxic potential of chemicals present along the course of the river Nile using frequencies of micronuclei (MN) and nuclear lesions (NL) in erythrocytes of Nile tilapia Oreochromis niloticus niloticus and African catfish Clarias gariepinus, as biomarkers. Results showed that most of the physicochemical parameters detected and heavy metal concentrations were significantly higher in the water collected from the estuaries of the river Nile compared to other sites of the upper Nile. The frequencies of MN and NL in peripheral blood erythrocytes of Nile tilapia and African catfish were significantly higher in estuary sites in Damietta and Rosetta compared to upper sites. The lowest level of genotoxicity was observed at two sites (Aswan and Kena), considered to be less contaminated. Our results suggested that higher frequencies of MN and NL determined at Damietta and Rosetta sites may be indicative of damage produced by pollutants in these areas. The most remarkable result was that MN and NL frequencies appear to be strongly related to water quality at different sites examined, indicating that MN frequencies may serve as a reliable biomarker for testing genotoxicity in situ. The positive correlation between MN and NL induction suggested that NL may be a useful complementary assay for genotoxicity analyses when fish are used as experimental animals. It was also found that seasonal variations in MN and NL frequencies might contribute to a better understanding of genotoxic responses in the field. The use of fish as indicator organisms for monitoring the presence of genotoxic-inducing contaminants in the environment seemed justified because the effects of exposure to a “complex mixture” such as river water were obtained. Nile tilapia appears to be a more suitable bioindicator species than African catfish in studying genotoxic chemical pollution in the river Nile attributed to a higher sensitivity.     

Risk-based maintenance (RBM): a quantitative approach for maintenance/inspection scheduling and planning

The overall objective of the maintenance process is to increase the profitability of the operation and optimize the total life cycle cost without compromising safety or environmental issues. Risk assessment integrates reliability with safety and environmental issues and therefore can be used as a decision tool for preventive maintenance planning. Maintenance planning based on risk analysis minimizes the probability of system failure and its consequences (related to safety, economic, and environment). It helps management in making correct decisions concerning investment in maintenance or related field. This will, in turn, result in better asset and capital utilization.

This paper presents a new methodology for risk-based maintenance. The proposed methodology is comprehensive and quantitative. It comprises three main modules: risk estimation module, risk evaluation module, and maintenance planning module. Details of the three modules are given. A case study, which exemplifies the use of methodology to a heating, ventilation and air-conditioning (HVAC) system, is also discussed.     

2-Nitroso-1-naphthol as a selective reagent for preconcentration of cobalt by vortex assisted combined with solidification of organic droplet and its determination by flame atomic absorption spectrometry

Highly rapid and selective vortex-assisted liquid–liquid microextraction based on solidification of organic drop has been used for determination of cobalt ion. 2-Nitroso-1-naphthol (2N1N) was used as a selective complexing agent to form stable cobalt–2N1N complex which can be extracted with 1-undecanol at a short time by the assistance of vortex agitator system followed by its determination using flame atomic absorption spectrometry. In vortex assisted, vigorous vortex stream as well as the vibrant effect of vortex system cause very fine droplets of extraction solvent to be produced and extraction occurred at a short time. Some parameters influencing the extraction process such as pH of samples, concentration of 2-nitroso-1-naphthol, extraction solvent volume, extraction time, ionic strength and surfactant addition, as well as interferences were evaluated in detail and optimum conditions were selected. At the optimum conditions, the calibration curve was linear in the range of 15 to 400 μg L^?1 of cobalt ions. The relative standard deviation based on ten replicate analysis of sample solution containing 50 μg L^?1 of cobalt was 3.4 %. The detection limit (calculated as the concentration equivalent to three times of the standard deviation of the blank divided by the slope of the calibration curve after preconcentration) was 5.4 μg L^?1. The accuracy of the proposed method was successfully evaluated by the analysis of certified reference materials. This selective and highly rapid method was used for determination of cobalt ions in different water samples.     

Mechanical,Morphological and Dynamic Mechanical Analysis of Pineapple Leaf/Washingtonia Trunk Fibres Based Biophenolic Hybrid Composites

In this article, flexural, impact and dynamic mechanical properties of the Pineapple leaf fibres (PALF) and Washingtonia trunk fibres (GW) based bio-phenolic hybrid composites were examined. The pure and hybrid composites were fabricated using the hand lay-up technique with an overall fibre weight ratio of 50% in which GW and PALF were maintained in the fibre weight ratios of 50:50, 30:70, and 70:30 denoted as 1G1P, 3G7P, and 7G3P, respectively. Hybrid composites displayed better flexural strength, flexural modulus and impact strength than the GW composites and better viscoelastic properties than the PALF composites. Results revealed that 1G1P hybrid composites exhibited 25% and 12% improvements in flexural strength and modulus compared to the GW composites. 3P7K composites showed a twofold increase in impact strength than GW composites. The storage modulus of the pure and hybrid composites declined rapidly beyond the glass transition temperature. Furthermore, it was observed that the values of storage modulus for all the composites at 150 °C were similar regardless of the composite configuration. The Peak of loss modulus was found to increase in the following order: GW?>?7G3P?>?3G7P?>?1G1P?>?PALF. Furthermore, the temperature at the peak tan delta was improved, and a reduction in the tan delta peak was observed for hybrid composites compared to the pure composites. Finally, the PALF and GW hybrid combinations can be suitable for use in various applications such as textiles, machinery part production industries, medicine, automobiles, etc.

     

Distribution of Alkalinity, Ph, Salinity and Carbon Dioxide Components in the Coastal Waters of Alexandria

The ara studied is located between El-Dikheila Harbour in Elmex Bay and Mandara, at longitude 29° 47' and 30° East and latitude 31° 17' North. the aim of the work is to look at carbon dioxide components in this areA and the effect of waste water discharged on their concentrations. Surface and bottom water samples were collected from 12 stations during January, April, August and November, 1995. Total alkalinity, salinity, temperature and pH were measured. Carbonate alkalinity, total alkalinity, partial pressure and dissolved carbon dioxide, carbonate and bicarbonate ions were calculated, since the studied area includes two differetn sources of pollution. It wAs found conventient to refer El-Mex Bay as region “A” which contains stations from I to VI and the area located between Kayet Bey outfall and Mandara which contains stations from VII to XII as region “B”. When specific alkalinity is used As A tracer for El-Umum drain water it is observed that the drain water could reach Sidi Bishr area especially in August and November, while in January and April drain water did not reach this area.     

Novel Composite Films Based on Acrylic Fibers Waste/Nano-chitosan for Congo Red Adsorption

Journal of Polymers and the Environment - The current research aimed to use waste to treat waste; to recycling of acrylic fibers waste combined with nano-chitosan for use as an adsorbent to remove...     

Development of Smart Colorimetric Sensing Films Carbohydrate-Based with Soybean Wax and Purple Cauliflower Anthocyanins for Visual Monitoring of Shrimp Freshness

Journal of Polymers and the Environment - Novel pH-colorimetric intelligent films were designed from agar and methylcellulose matrix (AM) with soybean wax (SBW) in several percentages (5, 10, 15,...     

Detection of Norovirus and Hepatitis A Virus in Strawberry and Green Leafy Vegetables by Using RT-qPCR in Egypt

Food and Environmental Virology - There is an upward trend of consumption of organic fresh vegetables due to consumer demand for healthy foods without chemical additives. On the other hand, the...