Ludwigia stolonifera for remediation of toxic metals from simulated wastewater

The present study investigated the phytoremediation of simulated wastewater, mimicking wastewater generated by industrial processes containing significant amounts of toxic heavy metal ions. The wetland plant Ludwigia stolonifera was used to study its efficiency in the removal of the three toxic metals Pb, Cd and Cr. Survivability of the plant has been studied in solutions at different concentrations of three metals separately or as a mixture, and the accumulation of these toxic metals for a prolonged period has been evaluated. The plant performed very successful in eliminating Cd, Cr and Pb as single metals of up to 65%, 97% and 99%, respectively, within four days. In addition, the trend of metal uptake revealed negligible dependence on different masses of plant and on various pH-values. L. stolonifera has high potential in eliminating various toxic pollutants from aquatic environments.     

Optimization of biodiesel production from waste cooking oil using ion-exchange resins

Waste cooking oil is a potential substitution of refined vegetable oil for the production of biodiesel due to the low cost of raw material and for solving their disposal problem. In this study, optimization of esterification process of free fatty acids in artificially acidified soybean oil with oleic acid has been carried out using methanol as an agent and ion exchange resin as a heterogeneous catalyst. The esterification reaction has been investigated based on the mass balance of the developed model. The model has been validated against experimental data and effects of temperature and catalyst weight have been analyzed. Thereafter, optimization process has been fulfilled for two different objective functions as conversion of acid oil and benefit. Optimization results indicated that the maximum conversion of acid is 95.95%, which is achievable at 4.48-g catalyst loading and reaction temperature of 120°C. Maximum benefit was obtained as US$0.057 per batch of reaction at a catalyst amount of 1 g and temperature of 120°C.     

The role of some feed additives in fish fed on diets contaminated with cadmium

The decline of cadmium pollution in fish farms is needed by any adequate method. The present study was designed to explore the effect of dietary cadmium contamination and its amelioration by using dietary clay, probiotic (Bactocell®), vitamin C, and vitamin E supplementation in Nile tilapia fish diet on growth rate, feed efficiency, blood components, and cadmium residues. Fish were separated into 15 groups, each group of fish was stocked into three aquaria and each contains 20 fishes. The fish of the first five groups were fed the basal diet, the second five groups were fed the basal diet contaminated with 25 mg cadmium/kg, and the third five groups were fed the same diet contaminated with 50 mg cadmium/kg. Within each dietary cadmium level, the first group was fed the diet without any supplementation, the second was fed the diet supplemented with natural clay (bentonite) at level 3%, the third group was fed the diet supplemented with 1 g Bactocell®/kg, the fourth group was fed the diet supplemented 50 mg vitamin E/kg, and the fifth group was fed the diet supplemented with 100 mg vitamin C/kg. Live body weight, daily body weight gain, and feed intake of Nile tilapia decreased significantly (P < 0.001) with increasing dietary cadmium level, while feed conversion was impaired. Fish group fed on diets contaminated with 50 mg cadmium/kg recorded the lowest live body weight and weight gain. Serum total protein and albumin concentration significantly (P < 0.001) decreased, while serum creatinine, AST, and ALT significantly (P < 0.001) increased with increasing cadmium level in fish diets. Blood hemoglobin and total erythrocyte (RBCs) significantly (P < 0.001 or 0.05) decreased with cadmium contamination in fish diets, while leukocytes were insignificantly affected. Body cadmium residues increased significantly (P < 0.001) by increasing cadmium level in fish diets. Live body weight, daily body weight gain, and feed intake of Nile tilapia increased significantly (P < 0.001) with feed additive supplementation in diets, also while feed conversion improved. Fish group fed on diets supplemented with probiotic Bactocell® or natural clay recorded higher body weight and gain rate than the other experimental groups. Serum total protein, blood hemoglobin, and total erythrocyte increased, while urea-N, creatinine, ALT, AST, and leukocytes decreased as affected with the feed additive supplementation. Feed additive supplementation in fish diets significantly (P < 0.001) decreased cadmium residues in fish bodies. Irrespective of dietary cadmium level, feed additive supplementation in fish diet improved the growth rate and decreased the concentrations of serum creatinine and ALT. The obtained results indicated that feed additive supplementation could modify the function of the kidney and liver in fish exposed to the cadmium toxicity.     

Ecological and agriculture impacts of bakery yeast wastewater use on weed communities and crops in an arid environment

Environmental Science and Pollution Research - The goal of this study was to evaluate the impact of using yeast wastewater (YW) on weed communities. The study showed that all ecological parameters...     

New Poly(aniline-<Emphasis Type="Italic">co</Emphasis>-<Emphasis Type="Italic">o</Emphasis>-phenylenediamine)/Kaolinite Microcomposites for Water Decontamination

Copolymers of aniline and o-phenylenediamine/kaolinite composites were synthesized by 5:1 molar ratios of the respective monomers with different percentages of nanoclay via modified in situ chemical co-polymerization. The results were verified by measuring the FT-IR and UV–vis absorption spectra for PANI-o-PDA/kaolinite composites. The thermal behaviour of the copolymer and composites was studied. PANI-o-PDA/kaolinite composites were thermally more stable than pure copolymer. Surface morphology of copolymer composites was recorded at different magnification power by SEM which revealed whitish micrometric beads distributed all over the field with particle size in the range of 0.122–0.233 μm. This work demonstrates that the PANI-o-PDA/kaolinite composites particles can be considered as potential adsorbents for hazardous and toxic metal ions of water from lake El-Manzala, Egypt. All of Cd(II), Cu(II), and Pb(II) posed dangerous health risk to the local population via fish consumption.     

Evaluation of energy savings by using high efficiency motors in a thermal power station

This paper presents potential energy savings by installing high-efficiency motors instead of existing ones and their impact on greenhouse gases emissions reductions. This research study of the energy efficiency of electric motors has been performed in a typical thermal power plant. In the literature, the focus has been mainly on separate and away electric motors from operating facilities. The important advantage of this paper over other studies is that it uses the actual motors’ efficiency in the evaluation. The gains both in terms of electrical energy savings and in terms of financial economy by using high-efficiency motors have been discussed. As a result, the energy saving can be expected as 12.6% at the operating rate. This excellent result also reduces greenhouse gas emission by 1,423 tons every year. The analysis of the data provided an overview on energy losses often generated by the degradation and rewinding of electrical motors. This study represents very encouraging results that will help energy managers of industrial plants to become more involved in energy efficiency strategies.     

Current levels of airborne polyfluorinated telomers in Japan

Fluorotelomer alcohols (FTOHs), a class of per- and poly-fluorochemicals (PFCs), are environmental contaminants characterized by high volatility and are therefore prone to long-range atmospheric transport. In this study, airborne FTOHs were identified in Japan using a newly developed passive air sampler containing activated carbon felts. Air sampling was conducted at 33 sites all over Japan from April to June 2007. 8:2 FTOH, the dominant analyte, ranged from <32 to 2466pgm(-3) (mean: 241pgm(-3)) followed by 6:2 FTOH from n.d. to 768pgm(-3) (mean: 51.6pgm(-3)), 10:2 FTOH from <17 to 113pgm(-3) (mean: 26.8pgm(-3)) and 8:2 FTOAcryl from n.d. to 480pgm(-3) (mean: 25.8pgm(-3)). 8:2 FTOMethacryl was not detected above detection limit (3pgm(-3)) in all samples. The highest concentration of total investigated PFCs was found in Chiba (35 degrees 43'20' N 140 degrees 39'46' E) (2152-3181pgm(-3)). On the other hand, in three locations of Higashi-Yodogawa (34 degrees 44' N 135 degrees 32' E), high levels of 8:2 FTOAcryl (239pgm(-3), 109-480pgm(-3)) were detected, the levels of which were comparable to those of 8:2 FTOH (mean: 175pgm(-3), range: 115-292pgm(-3)). This study is the first national wide-scale survey of FTOHs and 8:2 FTOAcryl across Japan, showing that 8:2 FTOH was ubiquitous in the environment in Japan.     

Pollution prevention through process integration

 Process integration is a holistic approach to process design and operation. It emphasizes the unity of the process units and objectives. Therefore, it provides a unique framework for integrating environmental issues with other process objectives such as profitability, yield enhancement, debottlenecking and energy reduction. This paper presents a review of recent advances in the area of pollution prevention through process integration. First, the alternative methods for industrial waste reduction are discussed. Then, process integration is defined and categorized into three main components: synthesis, analysis and optimization. Next, mass integration science and methods are reviewed with special emphasis on their critical role in pollution prevention. Throughout the paper, various tools and techniques are described and illustrated. Received: 7 July 1998 / Accepted: 8 September 1998     

Vulnerability of tourism to climate change on the Mediterranean coastal area of El Hammam–EL Alamein,Egypt

Environment, Development and Sustainability - The north-western Mediterranean coast of Egypt, including the study area from El Hammam to EL Alamein, is a hub for economic and coastal tourism...     

Investigation of activated carbon/ethanol for low temperature adsorption cooling

Commercially available adsorption cooling systems use water/silica gel, water/zeolite and ammonia/ chloride salts working pairs. The water-based pairs are limited to work above 0°C due to the water high freezing temperature, while ammonia has the disadvantage of being toxic. Ethanol is a promising refrigerant due to its low freezing point (161 K), nontoxicity, zero ozone depletion, and low global warming potential. Activated carbon (AC) is a porous material with high degree of porosity (500–3000 m²/g) that has been used in wide range of applications. Using Dynamic Vapour Sorption (DVS) test facility, this work characterizes the ethanol adsorption of eleven commercially available activated carbon materials for cooling at low temperature of ?15°C. DVS adsorption results show that Maxsorb has the best performance in terms of ethanol uptake and adsorption kinetics compared to the other tested materials. The Maxsorb/ethanol adsorption process has been numerically modeled using computational fluid dynamics (CFD) and simulation results are validated using the DVS experimental measurements. The validated CFD simulation of the adsorption process is used to predict the effects of adsorbent layer thickness and packing density on cycle uptake for evaporating temperature of ?15°C. Simulation results show that as the thickness of the Maxsorb adsorbent layer increases, its uptake decreases. As for the packing density, the amount of ethanol adsorbed per plate increases with the packing density reaching maximum at 750 kg/m³. This work shows the potential of using Maxsorb/ethanol in producing low temperature cooling down to ?15°C with specific cooling energy reaching 400 kJ/kg.