Growth of northern deciduous trees under increasing atmospheric humidity: possible mechanisms behind the growth retardation

Regional Environmental Change - Increasing atmospheric humidity—a climate trend predicted for northern Europe—will reduce water flux through vegetation. Diminished transpirational water...     

Application of carbon adsorbents prepared from Brazilian-pine fruit shell for the removal of reactive orange 16 from aqueous solution: Kinetic,equilibrium, and thermodynamic studies

Activated (AC-PW) and non-activated (C-PW) carbonaceous materials were prepared from the Brazilian-pine fruit shell (Araucaria angustifolia) and tested as adsorbents for the removal of reactive orange 16 dye (RO-16) from aqueous effluents. The effects of shaking time, adsorbent dosage and pH on the adsorption capacity were studied. RO-16 uptake was favorable at pH values ranging from 2.0 to 3.0 and from 2.0 to 7.0 for C-PW and AC-PW, respectively. The contact time required to obtain the equilibrium using C-PW and AC-PW as adsorbents was 5 and 4 h at 298 K, respectively. The fractionary-order kinetic model provided the best fit to experimental data compared with other models. Equilibrium data were better fit to the Sips isotherm model using C-PW and AC-PW as adsorbents. The enthalpy and entropy of adsorption of RO-16 were obtained from adsorption experiments ranging from 298 to 323 K.     

Reorienting Systematic Conservation Assessment for Effective Conservation Planning

Abstract: Systematic conservation assessment (an information‐gathering and prioritization process used to select the spatial foci of conservation initiatives) is often considered vital to conservation‐planning efforts, yet published assessments have rarely resulted in conservation action. Conservation assessments may lead more directly to effective conservation action if they are reoriented to inform conservation decisions. Toward this goal, we evaluated the relative priority for conservation of 7 sites proposed for the first forest reserves in the Union of the Comoros, an area with high levels of endemism and rapidly changing land uses in the western Indian Ocean. Through the analysis of 30 indicator variables measured at forest sites and nearby villages, we assessed 3 prioritization criteria at each site: conservation value, threat to loss of biological diversity from human activity, and feasibility of reserve establishment. Our results indicated 2 sites, Yiméré and Hassera‐Ndrengé, were priorities for conservation action. Our approach also informed the development of an implementation strategy and enabled an evaluation of previously unexplored relations among prioritization criteria. Our experience suggests that steps taken to ensure the closer involvement of practitioners, include a broader range of social data, encourage stakeholder participation, and consider the feasibility of conservation action can improve the relevance of assessments for conservation planning, strengthen the scientific basis for conservation decisions, and result in a more realistic evaluation of conservation alternatives.     

Characterization of particulate matter concentrations during controlled indoor activities

Indoor sources have been identified as a major contributor to the increase of particle concentration in indoor environments. The work presented here is a study of the characteristics of particulate matter number size distribution and mass concentration under controlled indoor activities in a laboratory room. The objective is to characterize particulate matter concentrations indoors resulted under the influence of specific sources. Measurements were performed in an empty laboratory (period September–October 2006) using a GRIMM SMPS+C system (particle size range between 11.1 and 1083.3 nm), a DustTrak Aerosol Monitor (TSI) and a P-Trak Ultrafine Particle Counter (TSI). The studied indoor activities included candle burning, hot plate heating, water boiling, onion frying, vacuuming, hair drying, hair spraying, smoking and burning of incense stick. The AMANpsd computer algorithm was used to evaluate the modal structure of measured particle number size distribution data. Furthermore, the change of the particle number size distribution shape under the influence of different emission sources was studied versus time. Finally the particle emission rates were computed. High particle number concentrations were observed during smoking, onion frying, candle burning and incense stick burning. The highest particle mass concentrations were measured during smoking and hair spraying. The shift of the particle size distribution to larger diameters suggests the presence of strong coagulation effect during candle burning, incense stick burning, smoking and onion frying. The size distribution was mainly bimodal during onion frying and candle burning, whereas the size distribution remained unimodal during incense stick burning and smoking experiments.     

Innovative design of an LDPE reactor bay against gas explosion using a risk-based approach coupled with high fidelity computer tools

High pressure tubular reactors for the production of Low Density Polyethylene (LDPE) are, for safety reasons, enclosed in a protective bay open towards the sky. They are becoming longer and larger due to production capacity increases. TECHNIP has historically designed these reactor bays based on Licensor information, which include more or less empirical correlations. Further capacity developments require the design of these concrete enclosures to be challenged. With this in mind, the present study shows the interest of implementing an innovative methodology based upon a risk-based approach to define new design criteria for the enclosure walls. The method, which combines both risk analysis with computational fluid dynamics modelling (3D CFD) and non-linear finite element analysis (NLFEA) tools, allows a clear determination of the design overpressure loads applied on walls and offers an optimisation of the concrete wall thickness. The CFD study also leads to a better understanding of the ventilation and efficiency of safety systems (gas detection, depressurisation) with possibility for improvement of the hazardous area classification rating.     

Comparing Waste-to-Energy technologies by applying energy system analysis

Even when policies of waste prevention, re-use and recycling are prioritised a fraction of waste will still be left which can be used for energy recovery. This article asks the question: How to utilise waste for energy in the best way seen from an energy system perspective? Eight different Waste-to-Energy technologies are compared with a focus on fuel efficiency, CO₂ reductions and costs. The comparison is carried out by conducting detailed energy system analyses of the present as well as a potential future Danish energy system with a large share of combined heat and power as well as wind power. The study shows potential of using waste for the production of transport fuels. Biogas and thermal gasification technologies are hence interesting alternatives to waste incineration and it is recommended to support the use of biogas based on manure and organic waste. It is also recommended to support research into gasification of waste without the addition of coal and biomass. Together the two solutions may contribute to alternate use of one third of the waste which is currently incinerated. The remaining fractions should still be incinerated with priority to combined heat and power plants with high electric efficiency.     

Environmentally Friendly Polyurethane Composites: Preparation, Characterization and Mechanical Properties

The waterborne polyurethane (PU) prepolymer was prepared based on isophorone diisocyanate (IPDI), polyester polyol (N220), dimethylol propionic acid (DMPA) and hydroxyethyl methyl acrylate (HEMA). The modified waterborne polyurethane–acrylate (PUA) emulsions were obtained with different proportions of acrylate (butyl acrylate and methyl methacrylate) and initiating agent by in situ dispersion technique. The structures and thermal properties of prepared PU and PUA were analyzed and characterized with FT-IR, UV–Vis spectroscopy and DSC. The PUA hybrid samples had lower glass transition temperature of hard segment and higher decomposition temperatures than PU sample. Performances of the emulsion and film were studied by means of apparent viscidity, particle size and polydispersity, surface tension and mechanical properties. The results indicated that the particle sizes of the PUA dispersions were larger than those of the pure PU and the solvent resistance, mechanical properties of PUA films was improved compare with the unmodified polyurethane film. The film had the biggest hardness and the least water absorption when the BA/MMA mass ratio 5:5 modified PU. The obtained PUA have great potential application such as coatings, leather finishing, adhesives, sealants, plastic coatings and wood finishes.     

The Plume Volume Molar Ratio Method for Determining NO2/NOx Ratios in Modeling—Part II: Evaluation Studies

ABSTRACT

A previous paper¹ discusses the methodology for a new method for deriving the nitrogen dioxide/nitrogen oxide (NO₂/NO_x) ratio in plumes that originally are composed mainly of (NO_x). It is called the Plume Volume Molar Ratio Method (PVMRM). This paper documents its performance against six different data sets. These performance evaluations show that the PVMRM can realistically predict the NO₂ fraction at close-in receptors yet still provide conservative estimates so that the air quality standards can be protected.     

Photochemical Reactivities of Paraffinic Hydrocarbon-Nitrogen Oxide Mixtures Upon Addition of Propylene or Toluene

Effects associated with photochemical air pollution were measured during irradiation of n-butane-nitrogen oxide or n-butane-ethane-nitrogen oxide mixtures, with small amounts of propylene or toluene added. The effects measured including nitrogen dioxide and oxidant dosages, yields of formaldehyde and peroxy-acetyl nitrate, and eye irritation response. The results obtained clearly show that beneficial effects result from selective changes in hydrocarbon composition as well as from reduction of total hydrocarbon concenfration. Exclusion of olefins and alkylbenzenes was highly effective in reducing oxidant dosage, formaldehyde and peroxyacetyl nitrate concentrations, and eye irritation response. The only penalty was a modest increase in nitrogen dioxide dosage. A large reduction in nitrogen oxide concentration reduced nitrogen dioxide dosage and eye irritation response, but with the penalty of a large increase in oxidant dosage. The desirability of preferentially reducing olefins and alkylbenzenes rather than paraffinic hydrocarbons, acetylene, and benzene is strongly supported by this study. Research and development efforts should be directed toward preferential hydrocarbon control by mechanical or catalytic control