农业非点源污染环境影响及防治

非点源污染也称面源污染,因其污染的时空范围广,不确定性大,污染严重,对其治理及管理的难度也较大.由于化肥和农药的大量使用,农业非点源已成为中国水环境的主要污染源.文章中对农业非点源污染的特点、来源和危害进行了系统论述,并提出防治农业非点源污染的具体措施建议.     

Evaluation of soil washing process with carboxymethyl-β-cyclodextrin and carboxymethyl chitosan for recovery of PAHs/heavy metals/fluorine from metallurgic plant site

Polycyclic aromatic hydrocarbons(PAHs)/heavy metals/fluorine(F) mixed-contaminated sites caused by abandoned metallurgic plants are receiving wide attention. To address the associated environmental problems,this study was initiated to investigate the feasibility of using carboxymethyl-β-cyclodextrin(CMCD) and carboxymethyl chitosan(CMC) solution to enhance ex situ soil washing for extracting mixed contaminants. Further,Tenax extraction method was combined with a first-three-compartment model to evaluate the environmental risk of residual PAHs in washed soil. In addition,the redistribution of heavy metals/F after decontamination was also estimated using a sequential extraction procedure. Three successive washing cycles using50 g/L CMCD and 5 g/L CMC solution were effective to remove 94.3% of total PAHs,93.2% of Pb,85.8% of Cd,93.4% of Cr,83.2% of Ni and 97.3% of F simultaneously. After the 3rd washing,the residual PAHs mainly existed as very slowly desorbing fractions,which were in the form of well-aged,well-sequestered compounds; while the remaining Pb,Cd,Cr,Ni and F mainly existed as Fe–Mn oxide and residual fractions,which were always present in stable mineral forms or bound to non-labile soil fractions. Therefore,this combined cleanup strategy proved to be effective and environmentally friendly.     

用磁稳流化床过滤含尘气体的实验研究

研究磁场强度、气体表观流速比、铁磁性颗粒平均粒径、床层厚度、粉尘在滤料中的积累等因素对除尘效率的影响．结果表明,在磁稳状态,磁稳流化床的过滤效率大于９９％,且随床层厚度的增加和铁磁颗粒粒径的减小而增大．另一方面,随着床内粉尘的积累,磁稳流化床将退出磁稳状态,使过滤效率下降．退出磁稳状态的临界饱和点粉尘量与磁场强度有关,当磁场强度为４３００Ａ／ｍ,临界饱和点粉尘与铁磁颗粒的质量百分比约为６．７％．     

Efficient adsorption of Mn(Ⅱ) by layered double hydroxides intercalated with diethylenetriaminepentaacetic acid and the mechanistic study

In this study, greatly enhanced Mn(II) adsorption was achieved by as-synthesized diethylenetriaminepentaacetate acid intercalated Mg/Al layered double hydroxides(LDHsDTPA). The adsorption capacity of LDHs-DTPA was 83.5 mg/g, which is much higher than that of LDHs-EDTA(44.4 mg/g), LDHs-Oxalate(21.6 mg/g) and LDHs(28.8 mg/g). The adsorption data of aqueous Mn(II) using LDHs-DTPA could be well described by the pseudosecond order kinetics and Langmuir isotherm model. Thermodynamics study results also showed that the adsorption process of Mn(II) by LDHs-DTPA was exothermic as indicated by the negative ΔH value. Furthermore, based on the structural, morphological and thermostable features, as well as FT-IR and XPS characterizations of LDHs-DTPA and the pristine LDHs, the adsorption mechanism of Mn(II) was proposed. The carboxyl groups of DTPA were proposed to be the main binding sites for Mn(II), and the hydroxyl groups of LDHs also played a minor role in the adsorption process. Among the three common regeneration reagents, 0.1 mol/L Na_2CO_3 was the best for reusing LDHs-DTPA in Mn(II)adsorption. Besides, the Mn(II) adsorption performance could be hindered in the presence of typical inorganic ions, especially cations. Further specific modifications of LDHs-DTPA are suggested to get more selective adsorption of Mn(II) in practical applications.     

热液中金的沉淀机理研究综述

金的沉淀机理是了解热液金矿床成矿机制的关键。本文总结了金从热液中沉淀机理的最新研究成果，介绍了各种主要含金配合物的溶解度拨制机制，阐述了矿物表面吸附／还原以及电化学富集等矿物表面作用对金沉淀行为的制约。     

西藏生态经济系统的能值分析与可持续发展研究

在简要分析西藏的自然、社会经济概况及其在中国的战略地位基础上，运用能值理论与方法，对其主要资源的贮存价值、总能值用量、能值的流入流出情况、人口承载力、能值投入率、能值使用强度、环境负荷等指标进行了系统研究，并与其他国家的有关指标进行了比较研究，提出了进一步开发西藏资源、实现可持续发展目标的政策建议。     

硫化氢分解制取氢和硫技术的进展

介绍了 H2 S分解制氢和硫的热力学、动力学最新研究成果 ,综述了 H2 S分解制氢和硫的各种工艺技术的新进展 ,并对这些工艺技术进行了分析和评述。 H2 S分解制氢的同时回收硫是一种很有前途的治理废气减轻污染的方法。     

贵州水城青山铅锌矿床地球化学研究

通过对青山铅锌矿床矿石矿物、蚀变围岩、含矿层、辉绿岩的稀土元素、硫、碳、氧同位素及黔西北岩石地层中铅锌含量的研究，笔者认为，成矿金属并非源于岩浆岩，而源于深部的沉积岩，碳、硫分别源于碳酸盐岩和含矿地层的硫酸盐硫；大气降水经深循环再上升形成成矿介质水。     

不同耐性作物中几种酶活性对Cd胁迫的反应

为探讨作物对重金属毒害的耐受机理,本文采用盆栽试验及生理生化分析方法,研究了作物体内酶系统在耐受Cd胁迫中的作用。结果表明,在Cd胁迫下,耐性作物体内,SOD和PPO的活性未受明显影响或活性略增强,CAT活性明显增强;POD及硝酸还原酶活性的变化无明显规律。这说明,SOD、CAT和PPO活性的维持和提高是作物耐受Cd胁迫的物质基础之一。     

一株产絮凝剂的黑曲霉的分离及培养条件优化

从活性污泥中筛选出一株产絮凝剂的霉菌,初步鉴定为黑曲霉(Aspergillus niger).其所产生的微生物絮凝剂对高岭土悬浊液具有良好的絮凝作用.通过培养条件优化,其所产生的微生物絮凝剂对高岭土悬浊液的絮凝率从85.6%提高到98.7%,实验结果表明,(1)黑曲霉孢子最佳接种量为9.33×108 个/L;(2)产絮凝剂适宜的碳源为蔗糖,氮源为尿素,用量分别为30.00、1.600 g/L;(3)最佳培养条件为:查氏液体培养基初始pH 7.0,培养温度30℃,摇床转速180 r/min,培养时间120 h;(4)在最佳培养条件下微生物絮凝剂的产量为1.805 g/L;(5)絮凝性能比较结果表明,微生物絮凝剂的絮凝性能优于传统絮凝剂.