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151.
Bao-Zhong Zhang Hong-Gang Ni Eddy Y. Zeng 《Environmental pollution (Barking, Essex : 1987)》2010,158(5):1876-4972
To determine the potential input sources of polybrominated diphenyl ethers (PBDEs) to fish farming environments in South China, samples of seven various environmental matrices were collected from October 2006-September 2007. Tri- to deca-BDEs were detected in all samples analyzed, with mean concentrations (±standard deviations) at 5.7 ± 3.6 ng/L in pond water, 15 ± 11 ng/g dry wt. in pond sediment, 12 ± 3.8 ng/g dry wt. in bank soil, 21 ± 20 ng/g lipid wt. in fish, and 93 ± 62 ng/g lipid wt. in fish feeds. In addition, BDE-209 was the major constituent in all samples except fish and BDE-47 was predominant in fish samples. Relatively high abundances of BDE-49 were detected in all the samples compared to those in the penta-BDE technical products. Several bioaccumulation factors were evaluated. Finally, statistical analyses suggested that fish feed, as well as pond water at a lesser degree, may have been the major source of PBDEs in freshwater farmed fish. 相似文献
152.
153.
基于层次分析和模糊数学的电解铝生产安全评价 总被引:2,自引:0,他引:2
影响电解铝生产安全状况的因素很多,相互之间具有不确定性和模糊性。建立电解铝生产安全模糊综合评价指标体系,运用层次分析法确定各指标权重,通过专家给出第3层次的模糊关系综合矩阵,对电解铝生产安全性进行模糊综合评价。 相似文献
154.
Methane and carbon dioxide emission from two pig finishing barns 总被引:3,自引:0,他引:3
Agricultural activities are an important source of greenhouse gases. However, comprehensive, long-term, and high-quality measurement data of these gases are lacking. This article presents a field study of CH(4) and CO(2) emission from two 1100-head mechanically ventilated pig (Sus scrofa) finishing barns (B1 and B2) with shallow manure flushing systems and propane space heaters from August 2002 to July 2003 in northern Missouri. Barn 2 was treated with soybean oil sprinkling, misting essential oils, and misting essential oils with water to reduce air pollutant emissions. Only days with CDFB (complete-data-full-barn), defined as >80% of valid data during a day with >80% pigs in the barns, were used. The CH(4) average daily mean (ADM) emission rates were 36.2 +/- 2.0 g/d AU (ADM +/- 95% confidence interval; animal unit = 500 kg live mass) from B1 (CDFB days = 134) and 28.8 +/- 1.8 g/d AU from B2 (CDFB days = 131). The CO(2) ADM emission rates were 17.5 +/- 0.8 kg/d AU from B1 (CDFB days = 146) and 14.2 +/- 0.6 kg/d AU from B2 (CDFB days = 137). The treated barn reduced CH(4) emission by 20% (P < 0.01) and CO(2) emission by 19% (P < 0.01). The CH(4) and CO(2) released from the flushing lagoon effluent were equivalent to 9.8 and 4.1% of the CDFB CH(4) and CO(2) emissions, respectively. The emission data were compared with the literature, and the characteristics of CH(4) and CO(2) concentrations and emissions were discussed. 相似文献
155.
Photocatalytic degradation of 17beta-estradiol (E2) in aqueous medium mediated with titanium dioxide (TiO(2)) was studied. Moreover, effect of TiO(2) dosage on the degradation efficiency was investigated. Particular attention was paid to the identification of intermediates and analysis of photocatalytic degradation mechanism of E2 under neutral and alkaline conditions. The degradation efficiency of E2 increased with increasing concentration of TiO(2) but decreased due to light scattering as TiO(2) concentration was greater than 0.5mgml(-1). Several intermediates were formed during photocatalytic degradation of E2. However, only a few of the compounds could be identified and confirmed by LC-MS and LC-MS/MS. Six intermediates were observed by photocatalytic oxidation under alkaline conditions, namely 2-hydroxyestradiol, 10epsilon-17beta-dihydroxy-1,4-estradien-3-one (DEO), 10epsilon-hydroperoxide-17beta-hydroxy-1,4-estradien-3-one and three kinds of dicarboxylic acids formed by the opening of aromatic ring. In addition to the six intermediates mentioned above, 17beta-hydroxy-1,4-estradien-3-one (EO) was observed under neutral conditions and in the presence of methanol. Based on these intermediates, which were hardly degraded even after E2 was fully degraded, the mechanism of E2 degradation by TiO(2) photocatalysis was elucidated. 相似文献
156.
157.
基于改进熵权的灰色关联模型在湿地水质综合评价中的应用 总被引:13,自引:1,他引:12
湿地是自然界生物多样性较为丰富的生态系统,具有很大的生态功能及生态学价值,湿地水质评价需要综合考虑各指标的属性.介绍了基于改进熵权的灰色关联模型在湿地水质综合评价中的应用.以黑龙江省扎龙国家级自然保护区湿地调查采样数据为例,通过构建灰色关联决策矩阵,同时采用改进熵值法确定权重,再由计算各样本的灰色关联度来确定其所属级别,进而对保护区水质采样点的水质进行综合评价.基于改进熵权的灰色关联度模型,为湿地生态系统水质综合评价提供了新的思路. 相似文献
158.
Although the sorption mechanism of hydrophobic organic pollutants on soils or sediments has been widely studied, the effects of coexisting heavy metals are seldom reported, especially the role of dissolved organic carbon (DOC) in sorption interactions involving heavy metals. This paper investigates the sorption interactions of phthalate esters (diethyl phthalate, DEP, and di-n-butyl phthalate, DnBP) and copper on Yellow River sediment in the presence of DOC. The results indicate that the sorption hardly varies for DEP but increases up to 20% for DnBP as the copper concentration increases in a water-sediment system with extremely low concentration of DOC. The copper-induced sorption of DnBP could be due to its complexation with copper, as well as its hydrophobicity. In a water-sediment system with the addition of 6.34 mg l(-1) of commercial humic acid (HA), the sorption of DEP is decreased by up to 37%, and that of DnBP is enhanced by up to 41%, as copper is gradually added. This finding is also consistent with the results for a river water-sediment system containing 8.1 mg l(-1) natural DOC. The copper-influenced sorption of DEP and DnBP are found to be due to the binding of copper to DOC that leads to the configuration change of DOC and thus to its enhanced sorption to sediment. By using polarograph and fluorescence spectrograph techniques, the complexation competition among coexisting phthalates, copper and DOC is examined. The resulting data confirm the significant role of DOC in sorption interactions. 相似文献
159.
以好氧颗粒污泥为接种污泥,通过全氟辛烷磺酸(PFOS)长期驯化实现耐PFOS颗粒的培养,考察不同驯化时期的污泥基本特性,并结合微生物群落演替过程、微生物表型分布以及功能途径的变化情况,以揭示其耐受机制.结果表明,好氧颗粒污泥经历解体、再形成和成熟3个阶段后可在PFOS暴露下稳定维持.驯化成熟后的好氧颗粒污泥表面丝状菌减少,并且被大量胞外聚合物(EPS)所包裹,结构更加致密.驯化期间颗粒污泥中存在大量抗性细菌以及维持颗粒稳定相关细菌,主要包括unclassified_f__Comamonadaceae、Defluviicoccus、Dongia、Rhodoplanes、Flavobacterium、Thauera、Azospira、Candidatus_Competibacter、Azoarcus和norank_f__A4b,且部分菌属间存在显著的正相关性.群体感应途径和细菌趋化途径相关基因丰度在解体期上调,在颗粒形成和成熟期恢复至初始水平,说明细菌的群体感应效应和趋化性能够在颗粒应激过程中起重要作用.因此,好氧颗粒污泥可以通过特定菌群积极响应、促进细菌趋化作用和群体感应作用、提高EPS... 相似文献
160.
基于雨量(强)条件的泥石流预测预报研究现状、问题与建议 总被引:2,自引:0,他引:2
在对基于雨量(强)条件泥石流预测预报现状综合分析的基础上,提出了目前降雨型泥石流预测预报中存在的问题:①前期降雨对泥石流发生的贡献问题;②前期降雨对泥石流影响的衰减问题;③前期有效降雨天数的确定问题;④前期降雨和短历时降雨的权重衡量问题;⑤基于前期有效雨量的泥石流预测预报模式的确定问题。提出了降雨型泥石流预测预报程式框架和相关建议:①基于雨量(强)条件的泥石流预测预报应同机理研究密切结合;②单沟泥石流临界雨量条件和预测预报应同泥石流类型密切结合;③区域泥石流临界雨量条件和预测预报应同环境地质背景密切结合。 相似文献