Al0-Gr-Fe0活化O2类Fenton氧化降解土霉素的研究

采用高能球磨-高温烧结-液相还原法制备了能活化O₂原位产生H₂O₂/^·OH的新型功能材料（Al⁰-Gr-Fe⁰）,通过XRD、SEM、EDS和VSM对Al⁰-Gr-Fe⁰进行了表征,探讨了水中土霉素（OTC）在Al⁰-Gr-Fe⁰/O₂体系中的降解效能和降解途径.结果表明,在初始pH值为6、Al⁰-Gr-Fe⁰投加量为2g/L的条件下反应60min后,OTC和TOC的去除率分别达到100.00%和92.93%.循环使用4次后,Al⁰-Gr-Fe⁰对OTC的去除率仍有79.27%.通过自由基猝灭试验和自由基捕获试验确定了Al⁰-Gr-Fe⁰/O₂体系降解OTC的主要活性物种是^·OH.Al⁰-Gr-Fe⁰/O₂体系对OTC的降解归因于：Al⁰-Gr-Fe⁰高选择性还原O₂为H₂O₂/^·OH;Al⁰-Gr-Fe⁰中的Al⁰还原能促进Fe的循环,从而提高了Fe的催化活性,促进了H₂O₂分解产生^·OH.     

论市场经济条件下农业资源的综合开发

本文论述了农业资源综合开发的含义与特点,社会主义市场经济对农业资源综合开发提出的新要求及对策,并以江苏省南通市为例具体探讨了如何开展与社会主义市场经济相适应的农业资源综合开发。     

Activated fly ash/slag blended cement

This paper presents the results of the preparation of an ecological cementing material from granulated blast-furnace slag (GBFS) and Class C fly ash (CCFA). The desulphurization gypsum, calcined at 600–800 °C for 0.5–1.5 h, works as the main ingredient of the activator in the cementing material. The optimized formulation of the cementing material was obtained with the aid of factorial design method: slag, 70%; CCFA, 18%; activator, 12%. The “partial super-fine grinding process” was adopted to improve the performance, i.e., 85% of the mixture is ground to Blaine fineness of 3500 cm²/g, 15% further ground to around 5000 cm²/g. The compressive strength of 28 days of the cement mortar is up to 49 MPa and flexural strength 8.4 MPa. The hydration products, investigated by SEM and X-ray diffraction, are mainly ettringite and C–S–H gel.     

水利产业结构的合理划分与战略调整

水利产业是国民经济的基础产业，水利产业的快速发展对社会经济可持续发展和生态环境提供了重要的支撑和保障。水利产业可按生产产品、生产方式等不同来划分结构，如何调整和优化我国当前的水利产业结构，使其逐步合理化、高度化具有重要意义。着重分析了新的朝阳产业——水务产业的调整方向。     

重质燃料油中主要芳烃在自然条件下的风化规律

文章在自然环境条件下对重质燃料油进行了风化模拟实验,采用气质(GC/MS)联用仪分析了重质燃料油中主要芳烃组分及其变化。结果表明:该重质燃料油中主要芳烃为苯类(C_nB)、萘(C_nN)类、菲(C_nP)类、二苯并噻吩(C_nD)类;在自然条件下,经过1周的风化,C_nB和C_0N完全损失;经过6周风化,C_1N完全损失;经过12周的风化,C_2N完全损失,3环的PAHs无明显变化。同时指出C_2D/C_2P和C_3D/C_3P的比值以及烷基化二苯并噻吩的同分异构体分布可用于区别其它油品,并且风化后变化不大,仍可较好地用于油品的鉴定。     

我国危化品公路运输风险管理现状及其防灾对策

分析了危险化学品公路运输事故特点,总结了我国危险化学品公路运输事故风险管理现状,指出我国目前存在的不足。基于对危险化学品公路运输事故特点和管理现状充分认识基础上,结合我国的实际情况,提出了建设性的防灾对策及建议。     

SCREENING THE RELOCATION STRATEGIES OF WATER QUALITY MONITORING STATIONS BY COMPROMISE PROGRAMMING1

Water quality monitoring network designs historically have tended to use experience, intuition, and subjective judgment in siting monitoring stations only sporadically. Better design procedures for optimizing monitoring systems with respect to multiple criteria decision analysis had rarely been put into practice up front when the needs for intensive monitoring became critical. This paper describes a systematic relocation strategy that is organized to identify several significant planning objectives and consider a series of inherent constraints simultaneously. The planning objectives considered in this analysis are designed to enhance the detection possibility for lower compliance areas, reflect the emphasis for different attainable water uses at different locations, promote the potential detection for the lower degradation areas of pollutants, increase the protection degree of those areas with higher population density in the proximity of the river system, and strengthen the pre‐warning capability of water quality for water intakes. The constraint set contains the limitations of budget, the equity implication, and the detection sensitivity in the water environment. A case study in the Kao‐Ping River Basin, South Taiwan, demonstrates the application potential of this methodology based on a seamless integration between the optimization and the simulation models. It enables identification of the optimal locational pattern stepwise using the embedded screening and sequencing capacity in a compromise programming model. However, a well calibrated and verified water quality model is an indispensable tool in support of this multiobjective evaluation. Extra sampling procedures become necessary for the sites with sparse environmental information. Comparison of planning outcomes of compromise programming is made against previously achieved analyses by using weighted programming and fuzzy programming.     

咪唑类离子液体捕集CO_2性能的定量结构-性质相关性(QSPR)研究

CO_2是主要的温室气体,大量CO_2的存在严重影响着人类的生存环境和生态平衡,而咪唑型离子液体具有独特的气体溶解性,在CO_2的捕集分离中有很好的应用前景。基于定量结构-性质相关性(QSPR)原理,研究了咪唑类离子液体捕集CO_2的性能与其结构参数之间的内在定量关系。应用遗传算法获得与捕集量最为密切相关的一组描述符作为输入参数,随后,分别采用多元线性回归算法及支持向量机结合粒子群优化算法建立了咪唑类离子液体捕集CO_2的性能与其描述符之间的线性和非线性模型。多元线性回归算法得出训练集和测试集的复相关系数分别为0.765和0.814,支持向量机算法得出训练集和测试集的复相关系数分别为0.987和0.933。对预测模型进行了评价验证以及稳定性分析,结果表明,2种模型具有良好的稳定性能和预测能力。     

油污染全场模拟的湍浮力流动k-ε模型

以通用的k-ε湍流模型为基础,针对油—水两相流动体系的特点,提出了油污染全场模拟的湍浮力流动k-ε模型.模型不仅在控制方程中计及了密度变化,而且在控制方程中加进了浮力项,并对湍流Schmidt数也作了浮力修正.从而计及了浮力对紊动的影响.结果表明,模型的模拟效果非常满意.     

长江中下游中生代沉积盆地的含矿建造

本文讨论了长江中下游地区中生代沉积盆地演化与成矿作用的关系。印支旋回本区在挤压构造环境下，形成坳褶盆地和海退序列的含矿建造；早中三叠世在局限台地-萨布哈环境下形成周冲村组富铁碳酸盐、铅锌、膏（盐）等合矿建造；中三餐世与三角洲前线亚相有关的沉积环境下形成黄马青组含铜砂岩建造。南象运动是一次变格运动，其界面直接控制象山组砂岩铀矿。晚自垩世与拉伸引张构造有关，形成断陷盆地中的巨厚膏盐矿产．作者认为盆地演化及卤水流体是本区多旋回成矿作用最本质的因素。