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341.
Catherine A. Engelman William E. GrantMiguel A. Mora Marc Woodin 《Ecological modelling》2012,224(1):90-102
We describe an ecotoxicological model that simulates the sublethal and lethal effects of chronic, low-level, chemical exposure on birds wintering in agricultural landscapes. Previous models estimating the impact on wildlife of chemicals used in agro-ecosystems typically have not included the variety of pathways, including both dermal and oral, by which individuals are exposed. The present model contains four submodels simulating (1) foraging behavior of individual birds, (2) chemical applications to crops, (3) transfers of chemicals among soil, insects, and small mammals, and (4) transfers of chemicals to birds via ingestion and dermal exposure. We demonstrate use of the model by simulating the impacts of a variety of commonly used herbicides, insecticides, growth regulators, and defoliants on western burrowing owls (Athene cunicularia hypugaea) that winter in agricultural landscapes in southern Texas, United States. The model generated reasonable movement patterns for each chemical through soil, water, insects, and rodents, as well as into the owl via consumption and dermal absorption. Sensitivity analysis suggested model predictions were sensitive to uncertainty associated with estimates of chemical half-lives in birds, soil, and prey, sensitive to parameters associated with estimating dermal exposure, and relatively insensitive to uncertainty associated with details of chemical application procedures (timing of application, amount of drift). Nonetheless, the general trends in chemical accumulations and the relative impacts of the various chemicals were robust to these parameter changes. Simulation results suggested that insecticides posed a greater potential risk to owls of both sublethal and lethal effects than do herbicides, defoliants, and growth regulators under crop scenarios typical of southern Texas, and that use of multiple indicators, or endpoints provided a more accurate assessment of risk due to agricultural chemical exposure. The model should prove useful in helping prioritize the chemicals and transfer pathways targeted in future studies and also, as these new data become available, in assessing the relative danger to other birds of exposure to different types of agricultural chemicals. 相似文献
342.
Vincent Thieu Gilles Billen Josette Garnier Marc Benoît 《Regional Environmental Change》2011,11(2):359-370
Nitrogen contamination of ground and surface water in the Seine, Somme and Scheldt watersheds, as well as in the receiving
coastal marine zones, results in severe ecological problems. Previous modelling results showed that the implementation of
classical management measures involving improvement of wastewater purification and “good agricultural practices” are not sufficient
to obviate these problems. A more radical scenario was therefore established, consisting of a generalised shift to organic
agriculture of all agricultural areas in the three basins, with the additional constraints that livestock is fed only on local
fodder production. This scenario involves an increased livestock density in the Seine and Somme and a decrease in livestock
in the Scheldt basin. It leads to a significant reduction of agricultural production that finally brings the three basins
closer to autotrophy/heterotrophy equilibrium. Nitrate concentrations in most of the drainage network would drop below the
threshold of 2.25 mgN/l in the most optimistic hypothesis. The excess of nitrogen over silica (with respect to the requirements
of marine diatoms) delivered into the coastal zones would be decreased by a factor from 2 to 5, thus strongly reducing, but
not entirely eliminating the potential for marine eutrophication. 相似文献
343.
Marc J. Stern S. Andrew Predmore Michael J. Mortimer David N. Seesholtz 《Journal of environmental management》2010,91(6):1350-1356
We conducted an online survey (n = 3321) followed by five focus groups with Forest Service employees involved in compliance with the National Environmental Policy Act (NEPA) to explore agency views of how NEPA should be implemented within the agency. We filter these perceptions through the lenses of different functional groups within the agency, each with its own role in agency compliance with NEPA and its own suite of perceived accountabilities. In doing so, we uncover areas of consensus regarding valued practices as well as tensions between employees with different roles in NEPA compliance. General consensus exists regarding the importance of the effective functioning of interdisciplinary teams, but opinions about what constitutes an effective team vary. Findings suggest that NEPA serves as a playing field for competing accountabilities felt by line officers, disciplinary specialists, and advisory personnel within the agency, as each attempts to exert influence over NEPA processes and their outcomes. 相似文献
344.
345.
Premasis Sukul Marc Lamshöft Sebastian Zühlke Michael Spiteller 《Journal of environmental science and health. Part. B》2013,48(6):431-441
The main process controlling soil-pesticide interaction is the sorption-desorption as influenced by active soil surfaces. The sorption phenomena can influence translocation, volatility, persistence and bioactivity of a pesticide in soil. The present investigation was conducted on natural and artificial soils in order to enumerate the effect of soil components such as montmorillonite and ferrihydrite on the sorption behaviour of the fungicide metalaxyl and if sorption-desorption of the chiral pesticide affects the enantiomeric ratio. The sorption-desorption characteristics of metalaxyl were investigated by batch equilibration technique in a natural soil, two artificial soils, and in pure montmorillonite and ferrihydrite. After extraction, pesticide residues were analyzed by conventional and chiral chromatography using tandem mass spectrometry. A KdSorp (2.3–6.5) suggests low level sorption of metalaxyl with an appreciable risk of run-off and leaching. Thus, metalaxyl poses a threat to surface and ground water contamination. Furthermore, desorption tests revealed a hysteretic effect (H ≤ 0.8) in natural and artificial soils. Significant amount of metalaxyl was found tightly bound to the adsorbents without desorbing readily after desorption cycle. Desorption of 22–56% of the total amount of the retained metalaxyl was determined. This study reveals that an artificial soil derived from different soil constituents can be used to assess their influence on sorption/desorption processes. The present investigation showed that both montmorillonite and ferrihydrite play a significant role in the sorption of metalaxyl. The sorption doesn't influence the enantiomeric ratio of racemic metalaxyl. 相似文献
346.
Anneke Roosma Bas Godschalk Reinout Lageman Maurice Henssen Marc Van Bemmel 《补救:环境净化治理成本、技术与工艺杂志》2006,17(1):69-79
A residential area that was formerly part of a silver factory site severely contaminated with chlorinated solvents was remediated using an in situ electro‐bioreclamation technique. Electro‐bioreclamation is a method for heating soil and groundwater combined with soil vapor and low‐yield groundwater extraction and enhanced reductive dechlorination (ERD). During the first two years of remediation in the source area (the intensive phase), a total of 80 kg of volatile organic compounds (VOCs) was removed by heating combined with ERD. After another two years of ERD in the source and plume areas (the attenuation phase), the VOC concentrations were reduced to a level below 100 μg/L in groundwater. Given these satisfying results, electro‐reclamation in combination with ERD turned out to be a successful in situ remediation technique for removing VOCs. © 2006Wiley Periodicals, Inc. 相似文献
347.
348.
Ecological impacts of water-quality problems have developed in the western United States resulting from the disposal of seleniferous
agricultural wastewater in wetland areas. Overt effects of selenium toxicosis occurred at five areas where deformities of
wild aquatic birds were similar to those first observed at Kesterson National Wildlife Refuge in the west-central San Joaquin
Valley of California. These areas are: Tulare Lake Bed Area, California, Middle Green River Basin, Utah, Kendrick Reclamation
Project Area, Wyoming, Sun River Basin, Montana, and Stillwater Wildlife Management Area, Nevada. Potential for ecological
damage is indicated at six more sites in Oregon, Colorado, the Colorado/Kansas border, and South Dakota out of 16 areas in
11 states where biological tissue data were collected. This conclusion is based on the fact that selenium bioaccumulated in
bird livers to median levels that had exceeded or were in the range associated with adverse reproductive effects. Selenium
concentrations in samples of fish and bird eggs support these conclusions at a majority of these areas. Reason for concern
is also given for the lower Colorado River Valley, although this is not exclusively a conclusion from these reconnaissance
data. Biogeochemical conditions and the extent of selenium contamination of water, bottom sediment, and biota from which this
assessment was made are given here. In a companion paper, the biogeochemical pathway postulated for selenium contamination
to take place from natural geologic sources to aquatic wildlife is defined. 相似文献
349.
350.
Françoise Muller Sophie Dreux Jean-François Oury Dominique Luton Serge Uzan Michèle Uzan Michel Levardon Marc Dommergues 《黑龙江环境通报》2002,22(11):1001-1004
Women having access to prenatal care late in pregnancy may still wish to benefit from maternal serum screening for Down syndrome. Therefore, we established reference values for α-feto protein (AFP) and free β-human chorionic gonadotrophin (β-hCG), and assessed the diagnostic value of maternal serum marker screening at 18–35 weeks' gestation based upon a series of 4072 sera from unaffected pregnancies and 118 sera from pregnant women with fetuses affected by Down syndrome. Using a 1/250 risk cut-off, a detection rate of 72.9% (95% CI = 71.5–74.3%) was achieved with a false-positive rate of 7.51% (95% CI = 6.71–8.3%). This was not significantly different from the percentages observed in our 14–17 weeks routine screening (50 596 patients): 71.9% (95% CI = 71.5–72.3%) and 6.48% (95% CI = 6.28–6.68%), respectively. Detection and screen-positive rates were, respectively, 51.3% (95% CI = 35.6–67.0%) and 5.95% (95% CI = 5.12–6.68%) in women aunder 35 years of age, and 84.8% (95% CI = 76.9–92.7%) and 24% (95% CI = 20.7–27.3%) in women aged 35 years and over. In conclusion, maternal serum marker screening is feasible at 18 weeks' gestation and later, which may be of interest in selected cases. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献