Reconnaissance soil geochemical survey of Gibraltar

The extreme density of population of Gibraltar, situated at the southern tip of Spain, exerts considerable pressure on land use and thus future planning is of utmost importance. An initial reconnaissance soil geochemical survey of Gibraltar was based on 120 surface samples (0–15 cm) taken from a wide range of exposed, either bare soil or vegetated sites, to provide the optimum geographical distribution. The total elemental concentrations of 26 elements (Li, Na, K, Be, Mg, Ca, Sr, Ba, Al, La, Ti, V, Cr, Mo, Mn, Fe, Co, Ni, Cu, Ag, Zn, Cd, Pb, P, S, As) were determined by nitric/percholric acid digestion followed by inductively coupled plasma-atomic emission spectrometry (ICP-AES) analysis. The reconnaissance data shows that the spatial distribution of various elements depended on previous and present land use. Most elements (Ca, Cr, Mg and Mn excluded) exhibited relatively high concentrations in civilian and natural soils. Trends have been established for many elements, and concentrations exceeding guideline values have been found in certain areas of Gibraltar. This reconnaissance of Gibraltar is at present being followed by a more detailed baseline geochemical survey, which will establish the extent and magnitude of the variations in major and trace elements in soils and dusts, assess the impact of industrial, commercial and urban development on the geochemical landscape and to make recommendations concerning sustainable development.     

Kinetics of biochemically driven metal precipitation in synthetic landfill leachate

This study investigates the effectiveness of using metal sulphide and carbonate precipitation mechanisms combined with a landfill‐derived mixed bacterial population. The study was conducted under controlled substrate conditions in anaerobic batch reactors. High chemical oxygen demand (COD):sulphate ratios, butyrate, propionate, and acetate were used anaerobically by bacteria for growth with associated sulphate reduction as well as sulphide and carbonate generation. Propionate and butyrate degradation occurred during sulphate reduction by sulphate‐reducing bacteria while acetate degradation was associated with methanogenesis by methanogenic bacteria. Using low COD, sulphate ratios showed limited acetate utilization, but sulphate reduction still occurred. Precipitation of Cd, Cu, Zn, Ni, and Fe sulphides occurred quickly and was completed in 15 to 30 days, while Ca, Mn, and Mg carbonates formed after 40 to 50 days and some soluble metal remained even after 120 days. The rate of metal precipitation was in the order of Cd>Cu>Zn>Ni>Fe>Mn>Mg>Ca. Bacterially mediated metal precipitation occurred slower than that recognized for chemical precipitation. These findings suggest that contaminant transport models based on chemical equilibrium metal behaviors may over‐predict metal removal by bio‐precipitation. © 2002 Wiley Periodicals, Inc.     

Voices of the Volunteers: an Exploration of the Experiences of Catchment Volunteers in Coastal Queensland, Australia

This paper discusses findings of a study of catchment care volunteers drawn from the east coast of Queensland, Australia. Catchment volunteering includes individuals in not-for profit stewardship groups with a catchment focus. Catchment volunteering was experienced by participants as maintaining a balance of perspectives; developing/maintaining an identity; networking; learning; empowering; and sustainable. An illustrative model (the Outcome Space), representing a set of scales, shows the relationship between conceptions.

Results indicate that catchment volunteering offers many benefits to individuals and local communities. Although there were frustrations at times, many volunteers expressed deep levels of satisfaction about their volunteering experiences. Results suggest that satisfied volunteers are those that manage to balance volunteering with other aspects of their lives; identify strongly with some aspect of volunteering; enjoy learning from their volunteer experiences; and were willing and able to share and apply their new knowledge in a variety of ways. They also made friends with other volunteers; felt valued by others in the group, and believed that what they do is important. For these respondents, volunteering contributes richly to the fabric of their lives, providing meaning and satisfaction in routine activities, enhancing local communities and building sustainability.     

Stewardship Volunteering by Older Australians: The Generative Response

The aim of this paper is to use Erikson's approach to human development, and specifically generativity, as a framework by which to explore older people's experiences of environmental stewardship activities. Using data from a large qualitative study of environmental volunteers resident in the coastal fringes of Queensland, Australia, the paper provides important, illustrative, empirical support for Erikson's theory of generativity in later life. Findings suggest that older people are much more likely to connect their environmental actions with the longer-term future, and express a need to leave a lasting legacy for future generations. According to respondents, the later years are a time to contribute to the environment as part of a broader cycle of life. The environment is also an important site for intergenerational activities. Whilst the work presented here is only a small, localized study, use of Erikson's theory of human development as a framework helps demonstrate the importance of a generative response in later life.     

Effect of Harvest on Leaf Development of the Asian Palm Livistona rotundifolia

Although palms are the most commonly harvested tree family in the world, they are susceptible to overexploitation, and many harvest schemes are not sustainable. We assessed the impact of leaf harvesting of the Asian palm, Livistona rotundifolia , in North Sulawesi, Indonesia, to determine the effect of harvest intensity on subsequent growth and to determine if current harvest practices are ecologically sustainable. We conducted experimental harvests of two intensities and compared results with a control. Leaf emergence, expansion, opening, and maturation were monitored for 1 year. Leaves in heavy and light harvest treatments grew and opened significantly faster than control leaves. Final leaf size was a function of harvest intensity: control leaves were larger (4.06 m) than light-harvest leaves (3.62 m) and heavy-harvest leaves (2.62 m). Census results for palms in harvested and unharvested areas indicated that palm density was twice as high and reproductive-sized palms were 10 times more common in the unharvested area. We judged current harvest practices to be nonsustainable. Recommendations for sustainable harvesting include reduction of harvest intensity and waste and preservation of reproductive-sized palms.     

The pit-trapping foraging strategy of the ant lion,Myrmeleon immaculatus DeGeer (Neuroptera: Myrmeleontidae)

Summary Larvae of Myrmeleon immaculatus in large pits captured both large and samll prey, while larvae in small pits captured only the small prey. Larvae in small pits did not respond to large ants, although they always responded by sand-flinging to small ants. Larvae in medium-sized pits often captured large ants only after prolonged and vigorous sand-flipping. Larvae in large pits usually captured large ants with relatively little sand-flipping. Pit enlargement and pit relocation in the laboratory were not significantly correlated with reduction of rations in the first 3 weeks after a pit was built. However, after a month without food, larvae on the average moved once every 10 days, built successively smaller pits, and moved longer distances before building a new pit. In the field pits were dug primarily in response to microclimatological factors and possibly edge-effects. The presence or absence of suitable prey at a site, per se, had no effect on whether or not a larva would dig a pit there. We conclude that these sit-and-wait predators have a relatively large repertoire of behavior that enhances their foraging success, and we contrast it with previously made optimal foraging models relating to pit locations, pit relocations, pit size and ant lion responses.     

The measurement of intracellular zinc in human intestinal mucosa using x-ray microanalysis

The zinc content of intestinal epithelial cells in human jejunum and ileum has been measured using X-ray microanalysis. The range of values was wide, the highest being found in stem cells and enterocytes. Significant differences were found in jejunum from gastric carcinoma patients and ileum from Crohn's disease patients compared with patients with non malignant, non inflammatory disease.     

Trends in natural-resource commodity prices: An analysis of the time domain

This paper attempts to reconcile the theoretical predictions of increasing real prices for nonrenewable natural-resource commodities obtained from Hotelling-style models with the empirical findings of falling prices for these commodities. A theoretical model for relative-price movements is derived for the case of exogenous technical change and endogenous change in the grade of ores mined. The model suggests a U-shaped time path for relative prices. The implied price movements are tested for all the major metals and fuels and the model parameters are found to be statistically significant for 11 out of the 12 commodities tested.     

Histological demonstration of immunoreactive metallothionein in sections of human and rat tissue

Immunoreactive metallothionein has been demonstrated in formalin fixed sections of rat and human tissue using a DNP hapten sandwich staining procedure and antibody to zinc-induced rat liver metallothionein II.MT was found in rat liver, duodenum, jejunum and ileum and in human liver and ileum both intracellularly in hepatocytes and enterocytes and extracellularly in portal vessels, sinusoids and canaliculi in the liver and in the lamina propria of the intestine.Changes in intensity of staining were related in the rat to the feeding/fasting status of the animal and whether exogenous zinc had been administered. In man least MT was found in the ileum of patients with Crohn's disease and most in patients with non-inflammatory bowel disease.These results confirm that MT is an important physiological metal-binding protein in man and animals and is concerned in zinc transport and binding in rats.