全文获取类型
收费全文 | 207篇 |
免费 | 0篇 |
国内免费 | 3篇 |
专业分类
安全科学 | 3篇 |
废物处理 | 18篇 |
环保管理 | 15篇 |
综合类 | 27篇 |
基础理论 | 33篇 |
污染及防治 | 83篇 |
评价与监测 | 14篇 |
社会与环境 | 16篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 4篇 |
2022年 | 4篇 |
2021年 | 3篇 |
2020年 | 2篇 |
2019年 | 3篇 |
2018年 | 5篇 |
2017年 | 3篇 |
2016年 | 9篇 |
2015年 | 5篇 |
2014年 | 4篇 |
2013年 | 20篇 |
2012年 | 10篇 |
2011年 | 13篇 |
2010年 | 5篇 |
2009年 | 16篇 |
2008年 | 18篇 |
2007年 | 16篇 |
2006年 | 9篇 |
2005年 | 5篇 |
2004年 | 10篇 |
2003年 | 3篇 |
2002年 | 7篇 |
2001年 | 5篇 |
2000年 | 4篇 |
1999年 | 5篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1989年 | 1篇 |
1985年 | 1篇 |
1984年 | 4篇 |
1982年 | 4篇 |
1980年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有210条查询结果,搜索用时 15 毫秒
101.
An efficient sampling method for dioxins from flue gas, an efficient automatic purification and fractionation method by a new HPLC system using a sulfuric acid-silica/silica column, a Nitro column and a PGC column, and sensitive determination method by an economical HRGC/LRMS using a programmable temperature vaporization (PTV) injector were developed. It was confirmed that the dioxins could be easily collected by the proposed simple sampling train consisting of only two bottles, and the extracted sample could be purified sufficiently and separated as mono-ortho PCBs, non-ortho PCBs and PCDDs/PCDFs completely with the proposed HPLC system. The peak areas of GC/MS were increased linearly with the injection volume up to 40 microl by the PTV technique, and the sensitivity could be increased to 20 times higher than usual. This convenient measuring method can drastically reduce operation time, consumption of hazardous solvent and cost. 相似文献
102.
Recycle technology for waste plastics containing polyvinyl chloride (PVC) has been developed in the Hokkaido National Industrial
Research Institute for the production of solid and liquid fuel, and has established a recycling process which includes a dechlorination
process for PVC plastics, and a two-stage catalytic pyrolysis process for plastics using zeolite catalysts. The dechlorination
equipment consists of a two-axis screw extruder with a heating element, which can remove chlorine up to 99.9 wt. % from PVC
containing plastics as hydrogen chloride. The product had about 44 000 kJ/kg calorific value and was fed into the next oil
production process, although it could also be used as a solid fuel. Natural and synthetic zeolite were used as catalysts for
the two-stage catalytic process, which produced a light oil with a boiling point which was between those of kerosene and gasoline.
The yield of this oil reached 82 wt. %. The chemical type was analyzed using liquid chromatography, and was found to have
many aromatic compounds. These technologies make it possible to produce a nonpolluting, high-calorie solid fuel and a liquid
fuel very efficiently.
Received: July 19, 2000 / Accepted: September 21, 2000 相似文献
103.
Teruyuki Kobayashi Akinori Sugiyama Yoshiyuki Kawase Terumi Saito Joris Mergaert Jean Swings 《Journal of Polymers and the Environment》1999,7(1):9-18
To determine the properties of enzymes from bacteria that degrade polypropiolactone (PPL), we isolated 13 PPL-degrading bacteria from pond water, river water, and soil. Nine of these strains were identified as Acidovorax sp., three as Variovorax paradoxus, and one as Sphingomonas paucimobilis. All the isolates also degraded poly(3-hydroxybutyrate) (PHB). A PPL-degrading enzyme was purified to electrophoretical homogeneity from one of these bacteria, designated Acidovorax sp. TP4. The purified enzyme also degraded PHB. The molecular weight of the enzyme was estimated as about 50,000. The enzyme activity was inhibited by diisopropylfluorophosphate, dithiothreitol, and Triton X-100. The structural gene of the depolymerase was cloned in Escherichia coli. The nucleotide sequence of the cloned DNA fragment contained an open reading frame (1476 bp) specifying a protein with a deduced molecular weight of 50,961 (491 amino acids). The deduced overall sequence was very similar to that of a PHB depolymerase of Comamonas acidovorans YM1609. From these results it was concluded that the isolated PPL-degrading enzyme belongs to the class of PHB depolymerases. A conserved amino acid sequence, Gly-X1-Ser-X2-Gly (lipase box), was found at the N-terminal side of the amino acid sequence. Site-directed mutagenesis of the TP4 enzyme confirmed that 20Ser in the lipase box was essential for the enzyme activity. This is the first report of the isolation a PHB depolymerase from Acidovorax. 相似文献
104.
Harriet Meinander Mari Hellsten 《International journal of occupational safety and ergonomics》2004,10(3):263-269
One of the objectives of the European SUBZERO project was to study the influence of sweat evaporation and condensation on the heat transmission properties of cold protective clothing. With the sweating thermal manikin Coppelius, water vapour transfer through and water condensation in the clothing can be determined simultaneously with the thermal insulation. In this study, 4 cold protective ensembles, intended for use temperatures between 0 and -50 degrees C, were measured with the dry manikin and at 2 different sweating rates. In addition, the ensembles were measured with non-sweating thermal manikins and in wear trials. 相似文献
105.
Mona L. Jacobsen Veerle L.B. Jaspers Tomasz M. Ciesielski Bjørn M. Jenssen Mari E. Løseth Nathalie Briels 《毒物与环境化学》2017,99(5-6):938-952
Blood clinical-chemical parameters (BCCPs) are used to investigate physiological consequences attributed to exposure to anthropogenic stressors, such as exposure to Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP) and Dechlorane Plus (DP), which are flame retardants (FRs), on avian health. Japanese quail (Coturnix japonica) were used as a model species to investigate individual and mixture effects of both FRs by injecting different concentrations (5, 50, or 500 ng/µL) of either of these compounds as well as a 1:1 mixture of both into fertilized eggs. To estimate post-hatching effects, 18 BCCPs were evaluated from 101 chicks at day 14. Albumin levels were found to be significantly elevated in the groups exposed to high doses of TDCIPP alone as well as a mixture of TDCIPP and DP. However, during the course of the study, the initial corn-based feed had to be substituted by a fishmeal-based feed. The 8 days consuming the new feed played a significant role on 12 of 18 BCCPs measured. Consequently, it is recommended that dietary habits need to be considered when investigating the physiological impact of contaminants using BCCPs as biomarkers in growing nestlings both in controlled in vivo and field experiments. 相似文献
106.
Influence of irrigation methods and use of an adjuvant on the persistence of the carbaryl (1-naphthyl N-methylcarbamate) on pakchoi [Brassica rapa L. subsp. chinensis (Rupr.) Olsson] was studied using a commercial enzyme linked immunosorbent assay kit. After applying carbaryl at a.i. 10.6 g L(-1) with or without an adjuvant (Latron B-1956) to leaves, plants were provided water daily by either overhead or basal application. Pesticide residue on leaf tissues was examined immediately after pesticide application and on 2, 4, 6, and 8 d after pesticide application. Use of the adjuvant did not affect the initial deposit of the pesticide, however pesticide persistence was improved with the adjuvant regardless of irrigation. Overhead irrigation contributed to rapid loss of the pesticide by washing carbaryl from the leaf surface. The longest half-life of carbaryl (6.5 d) was detected on plants receiving basal irrigation plus the adjuvant while the shortest half-life (2 d) was observed when plants were treated with overhead irrigation and no adjuvant. 相似文献
107.
García-Lorenzo ML Pérez-Sirvent C Martínez-Sánchez MJ Molina-Ruiz J Tudela ML 《Environmental monitoring and assessment》2012,184(11):7041-7052
The distribution of trace elements throughout mining areas is an important issue because abandoned tailings could be a major source of environmental pollution. In order to analyze the spatial variation of trace elements in a zone where mining activities took place and to identify pollution sources in the study area, a three-step study was carried out at a regional, at a local, and a detailed scale. In addition, a conceptual model of trace elements dispersion was established and confirmed by a geographic information system. The results obtained allowed to establish points affected by primary, secondary, and tertiary contamination, according to their proximity to contamination sources and as a function of attenuation processes which could take place in the studied area. 相似文献
108.
109.
Abalos M Parera J Estévez A Solé M Fabregat MC Piña B Navarro A Abad E 《Chemosphere》2011,82(1):64-71
Aquacultured fish gilthead seabream (Sparusaurata), previously exposed to low levels of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) trough the diet for a 13 months period, were fed on a clean feed for another 22 months. Gilthead seabream is a protandrous hermaphrodite species and this “decontamination” period coincided with the stages of sex differentiation, maturity and reproduction of the fish. PCDD/F levels in the fish tissues (i.e. muscle, liver, perivisceral fat and gonads), expressed in pg WHO-TEQ g−1 fresh weight, showed a general decreasing trend during the “decontamination” period. However, this general trend varied among tissues and was also dependent on sex and lipid contents. Toxicological effects affecting fish behaviour and hepatic marker responses were also evaluated. The results pointed out that exposure to PCDD/Fs did not have an impact on fish development and reproduction, since the proportion of sexes found after the sex reversal process was within the normal range described for this species. In addition, long-term exposure to low PCDD/F levels did not significantly affect the response of most of the biochemical markers considered. On the contrary, some of them (e.g. EROD activity) showed variations in their responses during the sex differentiation process and onwards. Finally, the hepatic AhR mRNA levels increased during dioxin exposure but they returned to values typical for non-exposed fish after the “decontamination” period. 相似文献
110.
Yankovich TL Kim SB Baumgärtner F Galeriu D Melintescu A Miyamoto K Saito M Siclet F Davis P 《Journal of environmental radioactivity》2011,102(1):26-34
To improve understanding of environmental tritium behaviour, the International Atomic Energy Agency (IAEA) included a Tritium and C-14 Working Group (WG) in its EMRAS (Environmental Modelling for Radiation Safety) program. One scenario considered by the WG involved the prediction of time-dependent tritium concentrations in freshwater mussels that were subjected to an abrupt increase in ambient tritium levels. The experimental data used in the scenario were obtained from a study in which freshwater Barnes mussels (Elliptio complanata) were transplanted from an area with background tritium concentrations to a small Canadian Shield lake that contains elevated tritium. The mussels were then sampled over 88 days, and concentrations of free-water tritium (HTO) and organically-bound tritium (OBT) were measured in the soft tissues to follow the build-up of tritium in the mussels over time.The HTO concentration in the mussels reached steady state with the concentration in lake water within one or two hours. Most models predicted a longer time (up to a few days) to equilibrium. All models under-predicted the OBT concentration in the mussels one hour after transplantation, but over-predicted the rate of OBT formation over the next 24 h. Subsequent dynamics were not well modelled, although all participants predicted OBT concentrations that were within a factor of three of the observation at the end of the study period. The concentration at the final time point was over-predicted by all but one of the models. The relatively low observed concentration at this time was likely due to the loss of OBT by mussels during reproduction. 相似文献