全文获取类型
收费全文 | 207篇 |
免费 | 0篇 |
国内免费 | 3篇 |
专业分类
安全科学 | 3篇 |
废物处理 | 18篇 |
环保管理 | 15篇 |
综合类 | 27篇 |
基础理论 | 33篇 |
污染及防治 | 83篇 |
评价与监测 | 14篇 |
社会与环境 | 16篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 4篇 |
2022年 | 4篇 |
2021年 | 3篇 |
2020年 | 2篇 |
2019年 | 3篇 |
2018年 | 5篇 |
2017年 | 3篇 |
2016年 | 9篇 |
2015年 | 5篇 |
2014年 | 4篇 |
2013年 | 20篇 |
2012年 | 10篇 |
2011年 | 13篇 |
2010年 | 5篇 |
2009年 | 16篇 |
2008年 | 18篇 |
2007年 | 16篇 |
2006年 | 9篇 |
2005年 | 5篇 |
2004年 | 10篇 |
2003年 | 3篇 |
2002年 | 7篇 |
2001年 | 5篇 |
2000年 | 4篇 |
1999年 | 5篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1989年 | 1篇 |
1985年 | 1篇 |
1984年 | 4篇 |
1982年 | 4篇 |
1980年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有210条查询结果,搜索用时 31 毫秒
161.
Montse Mari Martí Nadal Marta Schuhmacher Jos L. Domingo 《Environment international》2009,35(7):1034-1039
Most fly ashes produced in municipal waste incinerators of Catalonia (Spain) are deposited in a hazardous waste landfill (HWL) placed in Castellolí (Barcelona). This facility means a concern for the population living nearby. In response to this, we performed a probabilistic study focused on assessing human health risks derived from environmental exposure to heavy metals and polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) around the HWL. Concentrations of various metals and PCDD/Fs were determined in soil and air samples collected at the HWL, and in 4 locations around it. Health risks were evaluated according to the distance from the sampling locations to the HWL (near and far-sites). In general terms, metal and PCCD/F levels were relatively low in air and soil samples. However, concentrations of PCDD/Fs, as well as those of some metals, were found to be relatively higher in the HWL and Castellolí (the nearest village) samples than in those collected far away, resulting in a slight increase of exposure to those pollutants. Anyhow, the current concentrations of metals and PCDD/Fs suggest that it is highly unlikely that there are any additional non-carcinogenic and carcinogenic risks for the population living near the HWL. 相似文献
162.
Shinji Saito Ippei Nagao Hiroshi Kanzawa 《Atmospheric environment (Oxford, England : 1994)》2009,43(29):4384-4395
To understand the characteristics of non-methane hydrocarbon (NMHC) abundance in an urban air of Nagoya, one of the metropolitan areas of Japan, 48 species of C2–C11 NMHCs were measured with a measurement system, developed in this study, by using gas chromatography with flame ionization detection (GC/FID) continuously for one year from December 2003 to November 2004.Annual mean concentration of NMHCs in normal and propylene equivalent (PE) in Nagoya was compared with those in four urban areas of Seoul, London, Lille, and Dallas to extract characteristics of urban air. While the absolute values of the normal and PE concentrations of alkanes, alkenes, alkyne, and aromatics were significantly different among these urban areas, the proportions of each chemical group to the total NMHC were not so different.In Nagoya, the total normal concentration was high from November to February and low from June to August. The pattern of the seasonal variation was influenced mainly by that of alkanes. On the other hand, the total PE concentration was high from July to December and low from January to June. The pattern of the seasonal variation was influenced mainly by those of alkenes and aromatics. Particularly the normal concentration of isoprene was high from May to September because of large emission associated with activity of plants. As the results, in summer, the PE concentration of isoprene was especially high, and its contribution to the total NMHCs measured in this study was approximately 40%. The total PE concentrations were high in summer when the concentration of OH radicals is also high, suggesting that the productions of ozone and secondary organic aerosol (SOA) are likely to be promoted in summer of Nagoya. 相似文献
163.
First evidence of polybrominated diphenyl ether (flame retardants) effects in feral barbel from the Ebro River basin (NE, Spain) 总被引:1,自引:0,他引:1
Polybrominated diphenyl ethers (PBDEs) are chemicals of environmental concern due to their lipophilic, persistent and bioaccumulable characteristics as well as for their potential endocrine disrupting role. Former studies carried out in a tributary of the Cinca river (Ebro basin, NE Spain) revealed high levels of PBDEs in fish due to the discharges of effluents rich in PBDEs coming from a nearby industrial park in Barbastro. In this study, several biomarkers of pollutants exposure were measured in barbel, Barbus graellsii, before (upstream) and after (downstream) the main industrial site (Barbastro) in the Vero river. The results evidenced an enhanced hepatic phase I and II metabolism (measured as reductases, glutathione S transferase and uridinediphospho-glucuronosyltransferase), and of the antioxidant enzyme glutathione peroxidase. Conversely, fishes collected from downstream reaches had their phase I CYP1A dependent ethoxyresorufin O-deethylase, antioxidant diaphorase and brain cholinesterase activities depleted. In addition, the histological study of the liver and kidney of these fish evidenced an increase of the number and size of macrophage aggregates in most individuals collected downstream. Bivariate correlated analyses showed that the above mentioned biomarkers were correlated to measured PBDE congeners, thus indicating that the observed biological effects were unlikely to be related to other environmental factors than PBDEs. Overall, the measured biochemical and histological markers provide new evidence that in field exposed fish, PBDEs levels were associated with high activities of phase I and II metabolic enzymes, oxidative stress in liver, neurotoxicity in brain and histopathological effects in both liver and kidney. 相似文献
164.
Senichi Masuda Shunji Ago Tsutomu Itoh Hiroshi Saito Nobuo Furuya 《Journal of the Air & Waste Management Association (1995)》2013,63(3):241-242
Three experiments were designed to determine the effects of SO2 concentration on two Southeastern oat varieties—Caroiee and Coker 227. The plants were grown under uniform conditions prior to and after the experimental growth period. During the 7 to 14 day experimental growth period the plants were subjected to four growth temperatures (18/14, 22/18, 26/22 and 30/26° C day/night temperatures) and exposed 2 or 4 times to specific concentrations of SO2 (from 0 to 4 ppm) for 1.5 or 3.0 hr periods. In the first two experiments, the exposure temperatures were varied (18° to 30° C). In the third design, the exposure temperatures remained constant and two exposure relative humidities (55 and 80%) were used. Injury and growth reductions were more severe in Coker 227 than in Caroiee. Root dry weight (RDW) was affected more than top dry weight (TDW). Plants were more sensitive at the higher growth temperatures. Exposure temperatures had little to variable effects. Plants were more sensitive at 80% than at 55% relative humidity. Biomass was reduced at 0.4 ppm SO2 after four 3 hr exposures and at 0.75 ppm after two 1.5 hr exposures, but growth was also increased as often. These concentrations approached the accepted threshold for adverse effects to sensitive vegetation. Foliar injury was highly correlated with growth reductions. 相似文献
165.
Hiroshi H. Saito T. Bond Calloway Jr. Daro M. Ferrara Alexander S. Chol Thomas L. White Luther V Glbson Jr. 《Journal of the Air & Waste Management Association (1995)》2013,63(10):1242-1253
Abstract After strontium/transuranics removal by precipitation followed by cesium/technetium removal by ion exchange, the remaining low-activity waste in the Hanford River Protection Project Waste Treatment Plant is to be concentrated by evaporation before being mixed with glass formers and vitrified. To provide a technical basis to permit the waste treatment facility, a relatively organic-rich Hanford Tank 241-AN-107 waste simulant was spiked with 14 target volatile, semi-volatile, and pesticide compounds and evaporated under vacuum in a bench-scale natural circulation evaporator fitted with an industrial stack off-gas sampler at the Savannah River National Laboratory. An evaporator material balance for the target organics was calculated by combining liquid stream mass and analytical data with off-gas emissions estimates obtained using U.S. Environmental Protection Agency (EPA) SW-846 Methods. Volatile and light semi-volatile organic compounds (<220 °C BP, >1 mm Hg vapor pressure) in the waste simulant were found to largely exit through the condenser vent, while heavier semi-volatiles and pesticides generally remain in the evaporator concentrate. An OLI Environmental Simulation Program (licensed by OLI Systems, Inc.) evaporator model successfully predicted operating conditions and the experimental distribution of the fed target organics exiting in the concentrate, condensate, and off-gas streams, with the exception of a few semi-volatile and pesticide compounds. Comparison with Henry's Law predictions suggests the OLI Environmental Simulation Program model is constrained by available literature data. 相似文献
166.
167.
Buapan Puangsin Shuji Fujisawa Ryota Kuramae Tsuguyuki Saito Akira Isogai 《Journal of Polymers and the Environment》2013,21(2):555-563
Hemp bast holocellulose fiber (Cannabis sativa L. Subsp. Sativa) was oxidized by TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl radical)-mediated oxidation at various NaClO addition levels in water at pH 10. When carboxylate contents of the oxidized products were 1.5–1.7 mmol/g, TEMPO-oxidized cellulose nanofibrils almost completely dispersed at the individual nanofibril were obtained by mechanical disintegration of the TEMPO-oxidized hemp bast holocelluloses in water, where the nanofibrillation yields were 98–100 %. The sugar composition analysis revealed that most of hemicelluloses originally present in the hemp bast holocellulose were degraded and removed from the solid oxidized products, providing almost pure TEMPO-oxidized celluloses. X-ray diffraction patterns of all TEMPO-oxidized hemp bast holocelluloses had the same cellulose I crystal structure and similar crystallinity indices and crystal widths, indicating that carboxylate groups formed by the oxidation were selectively present on the crystalline cellulose microfibril surfaces in the holocellulose. However, the weight recovery ratios and viscosity-average degrees of polymerization of the TEMPO-oxidized hemp bast holocelluloses decreased to 69–59 % and 470–380, respectively, when their carboxylate contents increased to 1.5–1.7 mmol/g by the TEMPO-mediated oxidation. Atomic force microscopy height images showed that the nanofibril widths were 2.7–2.9 nm, and the average nanofibril lengths decreased from 590 to 400 nm as the NaClO addition level was increased from 7.5 to 12.5 mmol/g in the TEMPO-mediated oxidation. 相似文献
168.
169.
Albertinho B. de Carvalho Mina Kato Mariângela M. Rezende Pedro Afonso de P. Pereira Jaílson B. de Andrade 《Environmental science and pollution research international》2013,20(3):1565-1573
Studies have investigated the exposure levels of carbonyl compounds (CC) in the indoor and outdoor air of homes, vehicles, workplaces, urban and industrial areas, and rural sites. However, an investigation of these emissions and occupational exposure to CC in charcoal production facilities has not been previously conducted. The objective of this study was to measure the atmospheric concentrations of several CC to assess the exposure of workers of two charcoal plants located north of Salvador, Bahia, Brazil. Stationary and personal samples were collected using Sep-Pak® C18 cartridges that were coated with a 0.2 % acidic solution of 2,4-dinitrophenylhydrazine. The quantification of the resulting 2,4-dinitrophenylhydrazone derivatives was conducted using a high-performance liquid chromatography system with UV detection. In the personal samples, the concentrations of formaldehyde, acetaldehyde, propanone, furfural, and C4 isomers (n-butanal-isobutanal-butanone) ranged from 12 to 139, 38 to 165, 136 to 483, 39 to 114, and 63 to 132 μg?m?3, respectively. In the stationary samples, the concentrations of these CC ranged from 20 to 160, 111 to 284, 328 to 644, 70 to 163, and 100 to 176 μg?m?3, respectively. When compared to the occupational exposure limits for 8 h, the concentrations of formaldehyde were often greater than the levels recommended by the American National Institute for Occupational Safety and Health, which indicates a health risk for charcoal workers. These results are the first reported concerning the occupational exposure to CC in charcoal plants. 相似文献
170.