Degradation of propyl paraben by activated persulfate using iron-containing magnetic carbon xerogels: investigation of water matrix and process synergy effects

An advanced oxidation process comprising an iron-containing magnetic carbon xerogel (CX/Fe) and persulfate was tested for the degradation of propyl paraben (PP), a contaminant of emerging concern, in various water matrices. Moreover, the effect of 20 kHz ultrasound or light irradiation on process performance was evaluated. The pseudo-first order degradation rate of PP was found to increase with increasing SPS concentration (25–500 mg/L) and decreasing PP concentration (1690–420 μg/L) and solution pH (9–3). Furthermore, the effect of water matrix on kinetics was detrimental depending on the complexity (i.e., wastewater, river water, bottled water) and the concentration of matrix constituents (i.e., humic acid, chloride, bicarbonate). The simultaneous use of CX/Fe and ultrasound as persulfate activators resulted in a synergistic effect, with the level of synergy (between 35 and 50%) depending on the water matrix. Conversely, coupling CX/Fe with simulated solar or UVA irradiation resulted in a cumulative effect in experiments performed in ultrapure water.     

A data synthesis on the biochar properties and implications for air,soil, and water quality in Brazil

Biochar has been intensively researched worldwide. In Brazil, there is a variety of feedstock production that can be turned into soil amendments of high performance through biochar conversion, especially solid wastes. However, advances in biochar research in Brazil have not been systematically evaluated to indicate possible gaps and suggest future research for eco-friendly applications. Thus, in this work we evaluated biochar properties and effects on air, water, and soil quality based on data gathered from researches performed in Brazil. Biochar has been mainly evaluated as soil conditioner (37%), material characterization (17%), water treatment (12%), and greenhouse gases emissions (9%). Based on the data synthesis of 68 feedstocks used for biochar production, we observed that the pyrolysis temperature profoundly affects biochar properties. Meta-analysis indicated benefits of biochar addition to soils for chemical, physical, microbiological and biochemical attributes that have resulted in increases in root growth (+30%), and plant shoots (+45%). Pyrolysis temperature and feedstock are key choices to design biochar properties aiming to retain dyes, aromatic hydrocarbon, pesticides, and metals in water and wastewater treatment. It was also observed an increase in CO₂ and a decrease in N₂O emissions after biochar application to soils in short-term experiments. Although there is a growing interest in the development of electrochemical sensors and biochar-based fertilizers, technological applications of biochar are still incipient in Brazil. Future research should prioritize long-term and mechanistically evaluations of biochar under field conditions and the development of eco-friendly technological applications.     

Enhanced biological nitrogen and phosphorus removal from sewage driven by fermented glycerol: comparative assessment between sequencing batch- and continuously fed-structured fixed bed reactor

Environmental Science and Pollution Research - The nutrient biological removal from sewage, especially from anaerobic reactor effluents, still represents a major challenge in conventional sewage...     

Turbulence investigation in the roughness sub-layer of a near wall flow

The turbulence behaviour along a wall roughened by pyramidal elements was analysed in the region extending from the apex of the roughness elements up to the external limit of the roughness sub-layer. The data used for the analysis were obtained by particle image velocimetry technique. The rough wall turbulent boundary layer flow is characterized by a relatively low Reynolds number. All the results on the rough wall were compared with data referring to the canonical flow on a smooth wall turbulent boundary layer. Mean values and turbulence quantities for the two flows collapse when approaching the external limit of the roughness sublayer. The quadrant analysis of the Reynolds shear stress, in the region near the surface, shows that the contribution of the sweep motions is about equivalent for the two flows (except for wall distances lower than 40 viscous units). The contribution of the ejection motions appears to be more important over the smooth wall than over the rough wall with increasing differences approaching the wall. The probability density functions of the streamwise fluctuating velocity field for the rough wall case appear to be positively skewed in the zone very close to the pyramid apex, in contrast with the behavior observed for the smooth wall case at corresponding distances from the wall. The integral and Taylor scales for the rough wall case appear to be strongly reduced by the presence of the roughness, while the Kolmogorov microscale shows higher values.     

Development of a green and efficient methodology for the heterocyclic aromatic amine determination in biomass samples generated from cigarette combustion and tobacco

Environmental Science and Pollution Research - A green methodology was developed for the analysis of ten heterocyclic aromatic amines (HAAs) in biomass samples from cigarette combustion such as...     

Local voices on renewable energy projects: the performative role of the regulatory process for major offshore infrastructure in England and Wales

There is currently a considerable emphasis on delivering major renewable energy infrastructure projects. Such projects will have impacts on local communities; some impacts may be perceived as positive but others will be viewed more negatively. Any just regulatory process for considering and permitting such infrastructure will need to heed the concerns that local communities voice. But what counts as a local voice? In this paper it is argued that the regulatory process plays a performative role, constructing what counts as a local voice. Furthermore, this has consequences for how regulatory deliberations proceed and the outcomes of regulatory processes. The empirical basis for this argument is a study of major offshore renewable energy infrastructure in England and Wales and the way that it is regulated through a specific regime – the Nationally Significant Infrastructure Projects (NSIPs) regime established by the Planning Act 2008. Through a detailed study of eight projects that have passed through the regime, the analysis unfolds the way that the voices of local residents, local businesses, local NGOs and local authorities are constructed in the key boundary object of the Examining Authority’s report; it then draws out the implications for the mitigation measures that are negotiated. The research suggests that what counts as a local voice is constrained by how the performative role of the NSIPs regulatory regime differentiates between interests and suggests that new ways of giving voice to local people are required.     

Pervaporation of ethanol produced from banana waste

Banana waste has the potential to produce ethanol with a low-cost and sustainable production method. The present work seeks to evaluate the separation of ethanol produced from banana waste (rejected fruit) using pervaporation with different operating conditions. Tests were carried out with model solutions and broth with commercial hollow hydrophobic polydimethylsiloxane membranes. It was observed that pervaporation performance for ethanol/water binary mixtures was strongly dependent on the feed concentration and operating temperature with ethanol concentrations of 1–10%; that an increase of feed flow rate can enhance the permeation rate of ethanol with the water remaining at almost the same value; that water and ethanol fluxes was increased with the temperature increase; and that the higher effect in flux increase was observed when the vapor pressure in the permeate stream was close to the ethanol vapor pressure. Better results were obtained with fermentation broth than with model solutions, indicated by the permeance and membrane selectivity. This could be attributed to by-products present in the multicomponent mixtures, facilitating the ethanol permeability. By-products analyses show that the presence of lactic acid increased the hydrophilicity of the membrane. Based on this, we believe that pervaporation with hollow membrane of ethanol produced from banana waste is indeed a technology with the potential to be applied.     

Cap and trade schemes on waste management: A case study of the Landfill Allowance Trading Scheme (LATS) in England

The Landfill Allowance Trading Scheme (LATS) is one of the main instruments used in England to enforce the landfill diversion targets established in the Directive 1999/31/EC of the European Parliament and of the Council of 26 April 1999 on the landfill of waste (Landfill Directive). Through the LATS, biodegradable municipal waste (BMW) allowances for landfilling are allocated to each local authority, otherwise known as waste disposal authorities (WDAs). The quantity of landfill allowances received is expected to decrease continuously from 2005/06 to 2019/20 so as to meet the objectives of the Landfill Directive. To achieve their commitments, WDAs can exchange, buy, sell or transfer allowances among each other, or may re-profile their own allocation through banking and/or borrowing. Despite the goals for the first seven years – which included two target years (2005/06 and 2009/10) – being widely achieved (the average allocation of allowances per WDA was 22.9% higher than those finally used), market activity among WDAs was high and prices were not very stable. Results in terms of waste reduction and recycling levels have been satisfactory. The reduction of BMW landfilled (in percentage) was higher during the first seven years of the LATS period (2005/06–2011/12) (around 7% annually) than during the previous period (2001/02–2004/05) (4.2% annually). Since 2008, the significance of the LATS diminished because of an increase in the rate of the UK Landfill Tax. The LATS was suppressed after the 2012/13 target year, before what it was initially scheduled. The purpose of this paper is to describe the particularities of the LATS, analyse its performance as a waste management policy, make a comparison with the Landfill Tax, discuss its main features as regards efficiency, effectiveness and the application of the “polluter pays” principle and finally discuss if the effect of the increase in the Landfill Tax is what made the LATS ultimately unnecessary.     

Plastic pollution in freshwater ecosystems: macro-, meso-, and microplastic debris in a floodplain lake

Plastic pollution is considered an important environmental problem by the United Nations Environment Programme, and it is identified, alongside climate change, as an emerging issue that might affect biological diversity and human health. However, despite research efforts investigating plastics in oceans, relatively little studies have focused on freshwater systems. The aim of this study was to estimate the spatial distribution, types, and characteristics of macro-, meso-, and microplastic fragments in shoreline sediments of a freshwater lake. Food wrappers (mainly polypropylene and polystyrene), bags (high- and low-density polyethylene), bottles (polyethylene terephthalate), and disposable Styrofoam food containers (expanded polystyrene) were the dominant macroplastics recorded in this study. Contrary to other studies, herein macroplastic item surveys would not serve as surrogates for microplastic items. This is disadvantageous since macroplastic surveys are relatively easier to conduct. Otherwise, an average of 25 mesoplastics (mainly expanded polystyrene) and 704 microplastic particles (diverse resins) were recorded per square meter in sandy sediments. Comparisons with other studies from freshwater and marine beaches indicated similar relevance of plastic contamination, demonstrating for the first time that plastic pollution is a serious problem in the Paraná floodplain lakes. This study is also valuable from a social/educational point of view, since plastic waste has been ignored in the Paraná catchment as a pollutant problem, and therefore, the outcome of the current study is a relevant contribution for decision makers.