Effect of mono-ortho and di-ortho substituted polychlorinated biphenyl (PCB) congeners on leopard frog survival and sexual development

We tested the effect of mono-ortho and di-ortho PCB congeners on northern leopard frog (Rana pipiens) hatching success, survival and sexual development. Embryos and tadpoles were exposed to two levels (0.5 and 50 microg/l) of two PCBs. PCBs 101 and 70 were selected because they were present in amphibians collected in the Fox River-Green Bay ecosystem and they have the theoretical structural requirements to be able to bind to the estrogen receptor and mediate estrogenic responses. The exposure of leopard frog embryos and tadpoles to PCB 70 and 101 did not significantly affect hatchability, survival, deformities or growth. There were significant departures from the expected 50:50 sex ratio in tadpoles/froglets exposed to PCB 101 and PCB 70. In all the cases of significant departure, the bias was towards higher number of females. Decrease in the proportion of male gonads and increase in the proportion of intersex gonads were observed with increasing PCB tissue concentrations. The effects of PCB congeners on sexual differentiation occur at concentrations higher than observed in frogs in the Fox River/Green Bay ecosystem.     

Adaptive management of marine mega-fauna in a changing climate

Management of marine mega-fauna in a changing climate is constrained by a series of uncertainties, often related to climate change projections, ecological responses, and the effectiveness of strategies in alleviating climate change impacts. Uncertainties can be reduced over time through adaptive management. Adaptive management is a framework for resource conservation that promotes iterative learning-based decision making. To successfully implement the adaptive management cycle, different steps (planning, designing, learning and adjusting) need to be systematically implemented to inform earlier steps in an iterative way. Despite the critical role that adaptive management is likely to play in addressing the impacts of climate change on marine mega-fauna few managers have successfully implemented an adaptive management approach. We discuss the approaches necessary to implement each step of an adaptive management cycle to manage marine mega-fauna in a changing climate, highlighting the steps that require further attention to fully implement the process. Examples of sharks and rays (Selachimorpha and Batoidea) on the Great Barrier Reef and little penguins, Eudyptula minor, in south-eastern Australia are used as case studies. We found that successful implementation of the full adaptive management cycle to marine mega-fauna needs managers and researchers to: (1) obtain a better understanding of the capacity of species to adapt to climate change to inform the planning step; (2) identify strategies to directly address impacts in the marine environment to inform the designing step; and (3) develop systematic evaluation and monitoring programs to inform the learning step. Further, legislation needs to flexible to allow for management to respond.     

Germination of Medicago sativa is inhibited by soluble compounds in cement dust

Deposition of cement dust on soils and plant surfaces is known to affect plant growth and the species composition of plant communities, but little is known about its effects (and those of its pH and constituents) on germination. Therefore, the aim of this study was to assess the toxicity of an aqueous cement extract, constituents of the extract and pH on the germination of seeds of a selected species, Medicago sativa. First, the effects of the extract were tested in assays with concentrations and exposure durations ranging from 0 to 1.0 g/mL and 4 to 96 h, respectively. At 0.8 g/mL, the extract strongly inhibited germination; a 4-h exposure reduced the germination rate, from 77?±?1.8 to 50?±?2.6 % (mean ± SE), while 8-h exposure completely inhibited it. Further, treatment at this concentration killed the non-germinating seeds, thus the inhibition was due to toxic effects. Neither the pH of the extract nor the concentration of its main soluble elements separately (K, Ca, S, Na, or Cr) caused the toxicity since germination rates were not significantly reduced when these variables were tested individually. However, a mixture of the elements in solution reduced germination rates, suggesting that they have adverse synergistic effects.     

Acute exposition to Roundup Transorb® induces systemic oxidative stress and alterations in the expression of newly sequenced genes in silverside fish (Odontesthes humensis)

Environmental Science and Pollution Research - Roundup Transorb® (RDT) is a glyphosate-based herbicide commonly used in agricultural practices worldwide. This herbicide exerts negative effects...     

An Assessment of Spontaneous Vegetation Recovery in Aggregate Quarries in Coastal Sand Dunes in Buenos Aires Province,Argentina

Sand dune quarries are a location of common aggregate mining activity developed in coastal areas, especially in the southeast Buenos Aires province, Argentina. In this article, spontaneous plant development after extraction activity ceased was evaluated. Five areas (three quarried and two natural/conservation areas) were sampled for plant cover and composition as well as sediment characterization. Different indexes, principal component analysis, and cluster analyses were applied to compare the areas. The dominant families observed in four of the five areas were Asteraceae, Poaceae, and Cyperaceae, and most of the species are commonly found in sandy and humid soils and/or modified/anthropized ones. Percentages of plant cover increased with time because of the cessation of active aggregate extraction. Indexes and multivariate analyses showed that it was possible to distinguish quarried and natural areas based on composition and vegetation cover. The distribution of plant species among the four areas responded to the presence of mining activity, but it also responded to the topographical position and consequently the depth of the groundwater level. Besides these differences, the four areas shared many native species. The results might indicate that once the activity has ceased, quarried areas may spontaneously and quickly develop a plant community with some similarities to those present in the nonquarried areas. However, given that the extracting activity involves the removal of the soil, revegetation of this type of environment depends on the presence of natural areas in the surroundings, which can serve as a source of seeds and propagules for plant regeneration.     

Indicators of deforestation in the Southern Brazilian Pre-Amazon

In recent years, Amazonian deforestation has become a question of global concern. Deforestation in Amazon is a complex phenomenon in nature and has been related to traditional agriculture expansion. In this work, land use, socioeconomic and conservation indicators, combined with statistical analysis, were used to understand forces associated with patterns of deforestation. This approach was applied in Southern Brazilian Pre-Amazon in Mato Grosso State, which represents an extensive rain forest-savanna ecotone, located in the south border of Amazon biome. Based on data from the last two agricultural censuses (1995/1996–2006), we compared agricultural expansion in this area and Mato Grosso state. Results have shown that 85 % of state deforestation was concentrated in Southern Pre-Amazon and was closely related to increase in number of cattle and pasture area. PCA results pointed that population (92 %), number of cattle (86.5 %), pastures (84.2 %) and tractors (78.4 %) were variables with highest positive correlation to deforestation. It showed that GDP contributes to an individual axis and has a low correlation to deforestation (37.8 %). Conservation units and indigenous reserves also contribute to a single axis and were negatively correlated to temporary crops area. Results revealed a significant reduction in production and commercialization of extractive products in the region, revealing that the main, almost only conservation policy in Mato Grosso remains the creation of Special Areas. We suggest that further studies are necessary to screen development alternatives to simple cutting trees down. It is important to diversify strategies for deforestation control, and development aspects must be more seriously considered to reach a sustainable deforestation control policy.     

A perspective on radical transformations to sustainability: resistances,movements and alternatives

A transformation to sustainability calls for radical and systemic societal shifts. Yet what this entails in practice and who the agents of this radical transformation are require further elaboration. This article recenters the role of environmental justice movements in transformations, arguing that the systemic, multi-dimensional and intersectional approach inherent in EJ activism is uniquely placed to contribute to the realization of equitable sustainable futures. Based on a perspective of conflict as productive, and a “conflict transformation” approach that can address the root issues of ecological conflicts and promote the emergence of alternatives, we lay out a conceptual framework for understanding transformations through a power analysis that aims to confront and subvert hegemonic power relations; that is, multi-dimensional and intersectional; balancing ecological concerns with social, economic, cultural and democratic spheres; and is multi-scalar, and mindful of impacts across place and space. Such a framework can help analyze and recognize the contribution of grassroots EJ movements to societal transformations to sustainability and support and aid radical transformation processes. While transitions literature tends to focus on artifacts and technologies, we suggest that a resistance-centred perspective focuses on the creation of new subjectivities, power relations, values and institutions. This recenters the agency of those who are engaged in the creation and recuperation of ecological and new ways of being in the world in the needed transformation.     

Service quality evaluation in the context of a technology laboratory

The intent of this research is to investigate how the customers of a technological control laboratory for civil construction materials perceived the quality of the services delivered by the lab, specifically in regard to the service of concrete compression testing. The popular SERVQUAL scale, a multidimensional instrument used to capture customer expectations and perceptions, was used as a model for the application of a survey. Exploratory factor analyses were employed to evaluate customers’ perceptions and experiences of service quality in regard to the dimensions and accompanying attributes of the SERVQUAL scale. Twenty attributes, which were grouped within five dimensions (Reliability, Assurance, Tangibles, Responsiveness, and Empathy), were identified, explaining 80.417% of the variance between customer expectations and perceptions and characterizing these dimensions on a modified SERVQUAL scale. Analysis of the results allowed us to identify discrepancies in perceived service quality compared with customers’ expectations. Most of the identified gaps between expectations and perceptions resulted in negative values.     

Spatial distribution and concentration assessment of total petroleum hydrocarbons in the intertidal zone surface sediment of Todos os Santos Bay, Brazil

The primary objective of this study was to investigate the concentrations and spatial distribution of the total petroleum hydrocarbons (TPHs) in the intertidal zone surface sediment of Todos os Santos Bay, Brazil, to assess the distribution and degree of contamination by TPHs, measure the level of TPH degradation in the surface sediment, and identify the organic matter sources. The surface sediment used in this study was collected in 50 stations, and TPHs, isoprenoid alkanes (pristane and phytane), and unresolved complex mixture (UCM) were analyzed by gas chromatography with a flame ionization detector. The total concentrations ranged from 0.22 to 40,101 μg g^?1 dry weight and showed a strong correlation with the total organic carbon (TOC) content. The highest TPH concentrations were observed in samples from the mangrove sediments of a river located near a petroleum refinery. Compared with other studies in the world, the TPH concentrations in the intertidal surface sediment of Todos os Santos Bay were below average in certain stations and above average in others. An analysis of the magnitude of UCM (0.11 to 17,323 μg g^?1 dry weight) and the ratios nC17/Pr and nC18/Ph suggest that an advanced state of oil weathering, which indicates previous contamination. The molar C/N ratios varied between 5 and 43, which indicate organic matter with a mixed origin comprising marine and continental contributions.     

Toxicity Identification Evaluation (Phase I) of water and sediment samples from a tropical reservoir contaminated with industrial and domestic effluents

The Funil Reservoir (Rio de Janeiro State, Brazil) is an environment degraded by constant discharge of nutrients and pollution coming from the most industrialized region of the country. As a consequence of eutrophication, there are continuous cyanobacteria blooms, which cause acute and chronic toxicity to zooplankton. In this context, Phase I of Toxicity Identification Evaluation (TIE) was performed on Daphnia similis using water and interstitial water from the reservoir, with the aim of identifying classes of compounds responsible for toxicity. The results indicated that water toxicity was due to cyanobacteria resulting from blooms in the reservoir and surfactants. Metals, especially copper, contributed to sediment toxicity. This research is the first attempt to describe the nature of toxicity in this reservoir using this method.