Toxicity of tire debris leachates

Data on the indicators of environmental impact of tire debris, originated from the tire abrasion on roads, are extremely scarce, while it is well known that tires may produce deleterious effects. Tire debris contains significant quantities of zinc (Zn) which may be released by tire rubber. We have used tire particles (TD) produced in laboratory from new rubber. Two sets of experiments were set up to obtain eluates. One set used 50 and 100 g/L TD to produce eluates at pH 3-7. The Zn quantity was measured with a Inductively Coupled Plasma-Atomic Emission Spectrometry. The eluates at 1%,10%,50%,100% concentrations in culture media were tested on Raphidocelis subcapitata, Daphnia magna and Xenopus laevis embryos (FETAX test). The other set of experiments was performed putting 250 mg/L TD in a column with glass beads to control particle dispersion during the elution process. We demonstrate that factors such as pH, size and particles aggregation deeply influence the elution process, that the amount of Zn leached from particles is related to their aggregation rather than their quantity. These results, even though do not reflect the real environmental toxicity of the leachates, can be successfully used for comparative purposes allowing an initial assessment of the potential effect of tire derived particles.     

Deflection, acceleration, and force corridors for small females in side impacts

OBJECTIVE: This study was undertaken to develop biomechanical corridors applicable to the small-sized female in side impacts. METHODS: Sled tests were conducted using post mortem human subjects at a velocity of 6.7 m/s. Three chestbands were used to compute deflection-time histories at the axilla, xyphoid process, and tenth rib levels. Triaxial accelerometers were fixed to the upper and lower spine and sacrum to record acceleration-time histories. Specimens contacted the load wall with varying initial conditions (rigid and padded; flat wall and offset) from which impact forces to the thoracic, abdominal, and pelvic regions were obtained using load cell data. Adopting signal processing and mass-based scaling methods, corridors were derived for forces, accelerations, and chest deflections at three levels for all initial conditions. RESULTS: All time history corridors were expressed as mean plus/minus one standard deviation and provided in the article. CONCLUSIONS: Acceleration-, deflection-, and force-time corridors obtained for the chest and pelvic regions of the human body will assist in the assessment of anthropomorphic test devices used in crashworthiness evaluations.     

Validity and reliability of a job factors questionnaire related to the work tasks of physical therapists

Physical therapists engage in work tasks that expose them to occupational risk factors related to musculoskeletal disorders. Due to the gap in the literature on instruments focused on those workers, this study adapted a job factors questionnaire to physical therapists, and assessed its psychometric properties. The questionnaire was adapted and its content validity was established. The psychometric properties were evaluated among 142 physical therapists. Reliability was verified using the temporal-stability design and internal consistency. Construct validity was assessed with the known-groups technique. Test-retest results demonstrated intraclass correlation coefficients between .82 and .90 (p < .001). Cronbach's α of .91 verified the reliability of the questionnaire. The known-groups technique demonstrated a statistically significant difference on the scores of the items when physical therapists were compared to office workers. The results indicated that the adapted questionnaire had acceptable psychometric properties for assessing problematic job factors among physical therapists working in hospitals.     

THOR dummy chest deflection response in oblique and lateral far-side sled tests

Abstract

Objective: The focus of this study is side impact. Though occupant injury assessment and protection in nearside impacts has received considerable attention and safety standards have been promulgated, field studies show that a majority of far-side occupant injuries are focused on the head and thorax. The 50th percentile male Test Device for Human Occupant Restraint (THOR) has been used in oblique and lateral far-side impact sled tests, and regional body accelerations and forces and moments recorded by load cells have been previously reported. The aim of this study is to evaluate the chestband-based deflection responses from these tests.

Methods: The 3-point belt–restrained 50th percentile male THOR dummy was seated upright in a buck consisting of a rigid flat seat, simulated center console, dashboard, far-side side door structure, and armrest. It was designed to conduct pure lateral and oblique impacts. The center console, dashboard, simulated door structure, and armrest were covered with energy-absorbing materials. A center-mounted airbag was mounted to the right side of the seat. Two 59-gage chestbands were routed on the circumference of the thorax, with the upper and lower chestbands at the level of the third and sixth ribs, respectively, following the rib geometry. Oblique and pure lateral far-side impact tests with and without airbags were conducted at 8.3 m/s. Maximum chest deflections were computed by processing temporal contours using custom software and 3 methods: Procedures paralleling human cadaver studies, using the actual anchor point location and actual alignment of the InfraRed Telescoping Rods for the Assessment of Chest Compression (IR-TRACC) in the dummy on each aspect—that is, right or left,—and using the same anchor location of the internal sensor but determining the location of the peak chest deflection on the contour confined to the aspect of the sensor; these were termed the SD, ID, and TD metrics, respectively.

Results: All deformation contours at the upper and lower thorax levels and associated peak deflections are given for all tests. Briefly, the ID metrics were the lowest in magnitude for both pure lateral and oblique modes, regardless of the presence or absence of an airbag. This was followed by the TD metric, and the SD metric produced the greatest deflections.

Conclusion: The chestbands provide a unique opportunity to compute peak deflections that parallel current IR-TRACC-type deflections and allow computation of peak deflections independent of the initial point of attachment to the rib. The differing locations of the peak deflection vectors along the rib contours for different test conditions suggest that a priori attachment is less effective. Further, varying magnitudes of the differences between ID and TD metrics underscore the difficulty in extrapolating ID outputs under different conditions: Pure lateral versus oblique, airbag presence, and thoracic levels. Deflection measurements should, therefore, not be limited to an instrument that can only track from a fixed point. For improved predictions, these results suggest the need to investigate alternative techniques, such as optical methods to improve chest deflection measurements for far-side occupant injury assessment and mitigation.     

Metal ion uptake from aqueous solution by olive stones: a carbon-13 solid-state nuclear magnetic resonance and potentiometric study.

The use of biomasses that result from the agriculture and food industries in removing heavy metals from wastewaters is attracting increasing interest. We present a joined potentiometric and cross polarization magic angle spinning (CP-MAS) carbon-13 (13C) nuclear magnetic resonance (NMR) study on the interaction of olive stones with copper(II), nickel(II), and cadmium(II). The potentiometric measurements allow both to distinguish two kind of basic sites in the olive stones and to postulate the coordination models for the three studied metals. The NMR spectral analysis allows the attribution of the different signals to the components of the olive stone matrix. A comparison of CP-MAS 13C NMR spectra of the samples after metal treatment suggests a specific complexation between metal ions and hydroxyl groups on guaiacyl and syringyl moieties.     

Probability distributions of arsenic in soil from brownfield sites in Beijing (China): statistical characterization of the background populations and implications for site assessment studies

A probabilistic analysis was performed on soil arsenic concentration data from 4 brownfield sites at Beijing (Chaoyang and Haidian Districts), involved in environmental assessment studies. The available data sets were processed to provide a statistical characterization of the background populations and differentiate “anomalous data” from the natural range of variation of arsenic concentrations in soil. The site-specific background distributions and the existing wide-scale background values defined for the Beijing area were compared, discussing related implications for the definition of metal contamination soil screening levels (SSLs) in site assessment studies. The statistical analysis of As data sets discriminated site-specific background populations, encompassing 88% to 94% of the sample data, from outliers values, associated with either subsoil natural enrichments or possible anthropogenic releases. Upper Baseline Concentration (UBC) limits (+ 2σ level), including most of the site-specific metal background variability, were derived based on the statistical characterization of the background populations. Sites in the Chaoyang South District area had UBC values in the range 10.4–12.6 mg·kg^-1. These ranges provide meaningful SSL values to be adopted for As in local site assessment studies. Using the wide-scale background value for the Beijing area would have erroneously classified most of the areas in the subject sites as potentially contaminated.     

Estimation of Similarity in the Qualitative Composition of Humic Substance in Marine Sediments By Means of an Uv-Spectroscopic Library

In this paper a method for the study of the qualitative similarity of extractable humic substance (EHS) in marine sediments based on the realisation of UV spectral library of EHS is described. the spectral library was built including the digitised spectra of humic substance extracted from several marine sediments (46 samples) and two samples of standard materials (lignin sulphonate and humic substance) in a Statistica data file. the data matrix was elaborated by means of different multivariate statistic techniques such as Cluster Analysis (CA), Principal Components Analysis (PCA) and the univariate technique Spectral Correlation Analysis (SCA). This approach allows us to show the contribution of different organic compounds (aromatic, lipid and acid) to the composition of EHS and moreover it evidences also the structural characteristics of EHS in terms of similarities in the qualitative composition of samples such as presence of terrestrial and/or vegetal contributions. the UV library is an objective tool to study the qualitative composition of EHS and it represents a complementary approach to the most common methods based on the application of spectroscopic (IR, ¹³CNMR), potentiometric and chromatographic techniques.     

Nutrient balance in the ecosystem of the North Western Adriatic Sea

The effects of biological processes on dissolved inorganic nutrients, dissolved organic nitrogen (DON) and phosphorus (DOP) are considered in the north western Adriatic Sea. The budgets of these nutrients, which represent the sum of production and consumption processes in comparison to advection, are discussed with regard to dissolved inorganic nitrogen ( 15 N labelled) uptake, which basically indicates the biological demand of this fraction of nitrogen by phytoplankton community. The presented data show that, although important, the continental input of dissolved inorganic nitrogen (DIN), mainly nitrate, is utilised and recycled within the coastal marine environment (budget of m 15 r µmol-N·dm m 3 ). In fact, during four cruises (June, 1996; February, 1997; June, 1997; February, 1998), phytoplankton production was mainly driven by regenerated nutrients ( f h 0.4). Regarding dissolved inorganic phosphorus (DIP), the negative budgets observed in most cases (down to m 0.4 r µmol-P·dm m 3 ) confirm, above all, its scarce availability in this basin. Recycling processes rather than continental inputs regulate the availability of this nutrient. In addition, the comparison between DIN and DIP budgets indicates that, in this ecosystem, dissolved inorganic phosphorus is recycled faster than nitrogen through the living particulate and dissolved organic pools. As a consequence of biological activities, a strong production of dissolved organic nitrogen (DON) can occur in summer (up to +22 r µmol-N·dm m 3 ) while DOP shows a more independent behaviour both with respect to its accumulation in the environment and to the observed nitrogen variations.