Overcoming the blame game to learn from major accidents: A systemic analysis of an Anhydrous Ammonia leakage accident

This article aims to demonstrate the need for changing the methods with which accidents are analyzed, if we truly wish to use what we uncover from them to learn and enrich our knowledge base of organizational management. The goal is to relinquish the broadly adopted and rather simplistic paradigm that accepts the search for human error and unsafe acts performed by workers, and produces “guilt diagnostics”. Instead, we use a systemic accident analysis methodology, based on the sociotechnical principle of understanding the real operating conditions in which accidents take place. In order to demonstrate the benefits of the theoretical framework, we compare the analyses of an Anhydrous Ammonia gas leakage accident in a fish processing plant using the traditional accident analysis model based on unsafe acts and the proposed systemic approach. The results favor the latter since it tends to be more reliable and offering useful recommendations to safety management processes, thus helping to prevent accidents, especially in complex systems.     

PCDD/F mass balance in the flue gas cleaning units of a MSW incineration plant

With the main purpose of evaluating PCDD/F presence and the corresponding mass balance over the emissions control system, an extensive study was performed on a municipal solid waste full scale incinerator equipped with a best available technology flue gas treatment line. Present paper reports the main results obtained, with particular reference to the PCDD/F concentration profiles and mass balances derived for every process unit of the flue gas control system. Total release evaluated for the plant is also outlined compared with data on PCDD/F content of raw waste and with reference values included in most recent guidelines.     

Economic benefits from food recovery at the retail stage: An application to Italian food chains

The food supply chain is affected by losses of products near to their expiry date or damaged by improper transportation or production defects. Such products are usually poorly attractive for the consumer in the target market even if they maintain their nutritional properties. On the other hand undernourished people face every day the problem of fulfilling their nutritional needs usually relying on non-profit organizations. In this field the food recovery enabling economic benefits for donors is nowadays seen as a coherent way to manage food products unsalable in the target market for various causes and thus destined to be discarded and disposed to landfill thus representing only a cost. Despite its obvious affordability the food recovery is today not always practiced because the economic benefits that could be achieved are barely known. The paper aims at presenting a deterministic mathematical model for the optimization of the supply chain composed by retailers and potential recipients that practice the food recovery, taking into account the benefits recognized to donors and the management costs of the food recovery. The model determines the optimal time to withdraw the products from the shelves as well as the quantities to be donated to the non-profit organizations and those to be sent to the livestock market maximizing the retailer profit. The results show that the optimal conditions ensuring the affordability of the food recovery strategy including the tax reliefs and cost saving for the retailers outperforms the profit achievable in absence of such a system.     

Social business as a sustainable business model: making capitalism anti-fragile

In the last two centuries, developed nations have had an unprecedented generation of wealth showing a strong economic progress. Unfortunately, such economic development has not been witnessed in all countries and it does not represent the holistic face of the social progress. The main reason stands in the ideological limitations of capitalism itself, often ignoring local communities and environment while focusing exclusively on profit maximization, market share, dividends and bonuses. This failure it is also because of the division between two basic entities: nonprofit and for profit sectors. The segregation created between the economic values and social values, has created a system where the two different entities have failed to capture and integrate the multi-dimensional nature of the human being to satisfy social needs. Because of this increasing tension, the society needs to find a common ground solution, where the social and economic benefits of these two entities are merged together to generate an anti-fragile system. This research is an attempt to determine if the social business (SB) is capable to solve the problems arose from the free market idealogy, nonprofit philosophy, and the consequent social and economic inefficiency. Thus, the boundaries between the private, public and nonprofit sectors need to be changed. In addition, it is aimed to show that SB can solve social, economic, and environmental problems by using the entrepreneurial engine and the profit instrument, proving at the end to be by default a sustainable business model that respects the triple bottom line approach. The investigation method is based on literature review and theory development from three different fields: economics, development studies, and nonprofit management.     

Mobilization and Toxicity Potential of Aluminum from Alum Floc Deposits in Kensico Reservoir,New York

There is detailed literature on the mobilization of aluminum (Al) from soil to surface waters as a result of elevated acidic deposition to base‐poor forest watersheds. There is considerably less information on the mobilization and effects of Al from the application of alum that is used in some water supplies to control turbidity during high‐flow events. We report on the results of field measurements, laboratory sediment release experiments, and chemical equilibrium calculations conducted to evaluate the potential for the mobilization of Al from alum floc deposits in sediments of Kensico Reservoir, New York. Under ambient water quality conditions, mobilization of sediment Al is not a noteworthy concern at Kensico Reservoir. However, under experimental conditions of low pH, low acid neutralizing capacity (ANC), and low temperature, the inorganic fraction of monomeric Al can be mobilized from Kensico sediments to concentrations that would likely impair the health of aquatic organisms (>2 μmol/l). Elevated concentrations of monomeric Al were observed only when ANC decreased below 50 μeq/l, which is outside the range of values observed in Kensico during the 1997‐2007 interval (120‐460 μeq/l). Concentrations of complexing ligands are relatively low in Kensico waters (i.e., fluoride, naturally occurring organic solutes) and do not appear to substantially contribute to potential Al mobilization. For other water supplies with low ANC, the potential for sediment release of Al may exist.     

Affordable CO2 negative emission through hydrogen from biomass,ocean liming,and CO2 storage

Mitigation and Adaptation Strategies for Global Change - A new process to remove carbon dioxide (CO2) from the atmosphere, by combining commercial industrial technologies with ocean liming and CO2...     

Generating better energy indicators: Addressing the existence of multiple scales and multiple dimensions

High energy prices and the growing concern for “Peak Oil” have put energy analysis, once again, on the front burner. However, before speculating about possible roadmaps regarding our energy future, it would be wise to develop better quantitative analyses. This paper flags the existence of systemic epistemological flaws in the current use of aggregate energy indicators and presents an alternative approach capable of dealing with the issue of multiple dimensions and multiple scales. Starting from a critical appraisal of the aggregate indicator “Economic Energy Intensity” it shows that economic and biophysical variables are often correlated and that their value is determined by characteristics which can only observed across different levels and scales. Complex metabolic systems (systems that use energy to maintain and reproduce themselves) are operating simultaneously at different scales. This implies that changes in the characteristics of parts, defined at the local scale, and changes in the characteristics of the whole, defined at the large scale can only be obtained after establishing a scaling mechanism in the analysis. In order to deal with the issue of scale in energy accounting, we propose to make a distinction between three different categories: (i) primary energy sources (PES) - establishing a link between energy quantities and the associated requirement of biophysical gradients, at the large scale, on the interface black-box/context; (ii) energy carriers (EC) - defining the set of energy inputs required by technical devices for expressing useful functions, at the local scale, within the parts operating inside the black-box; (iii) end uses (EU) the set of functions to be expressed by society across hierarchical levels for reproducing itself. Finally, the paper presents examples of quantitative results obtained using an innovative method of analysis - Multi-Scale Integrated Analysis of Societal and Ecosystem Metabolism (MuSIASEM). We conclude that by using this new accounting method it is possible to generate a better understanding of external and internal constraints determining the desirability and viability of the metabolic pattern of societies.     

TENORM employed as inert material for house building: a model for evaluating the radon activity enhancement

Environmental Science and Pollution Research - Radon exhalation from soil and ores is among the most dangerous risks for the public health care. The impact becomes even more powerful when...     

Periodic Migration and Lowland Forest Refugia in a "Sedentary" Neotropical Bird, Wetmore's Bush-Tanager

Although the concept of tropical birds as sedentary is pervasive, evidence suggests many are not. Our grasp of movement status in tropical birds is decidedly poor, but the successful long-term conservation of these birds depends on such information. Sedentariness will likely doom much tropical avian diversity, but increased vagility is a two-edged sword: beneficial in promoting immigration, but detrimental in that more than one habitat may be required. Birds requiring more than one habitat may be unable to locate a particular type as landscape modifications increase. Our long-term data set from the Sierra de Los Tuxtlas in southern Veracruz, México, reveals infrequent, large-scale movements in a local highland endemic. Wetmore's Bush-Tanager ( Chlorospingus ophthalmicus wetmorei) seems occasionally dependent upon lowland forests (now greatly diminished) as a refugium from temporarily unsuitable highlands. Our data and observations lead us to three conclusions: 1) assumptions of sedentariness in tropical birds should be made with extreme caution; 2) normal, but periodic phenomena may be easily overlooked, even in relatively long-term studies; and 3) missing such phenomena jeopardizes the success of any conservation plan because over the long term a population may be dependent upon refugia only occasionally occupied.