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71.
72.
Businelli M Calandra R Pagliai M Businelli D Gigliotti G Grasselli O Said-Pullicino D Leccese A 《Journal of environmental quality》2007,36(1):254-261
This research deals with the transformation of an anthropomorphous landfill covering composed of a fill soil mixed with mechanically separated municipal waste compost. The study site was a municipal landfill near Perugia, Italy. Throughout the years, waste disposal in the landfill was performed by burial in horizontal layers, each one representing a yearly disposal. The external front of the landfill thus represented the yearly disposal over a 10-yr period starting in 1993. Temporal changes in the anthropomorphous soil over this period were studied by examining and describing soil profiles, and by collecting and analyzing soil samples from the 1993, 1994, 1997, and 2001 disposals. The samples were subjected to a series of physical, chemical, and biochemical analyses. The results obtained suggest that over a 10-yr period the top layer gained a pedological structure (subangular blocky and/or crumb) giving rise to an A horizon. Improved soil structure was confirmed by an increase in macroporosity, particularly for pores larger than 50 microm, measured by image analysis of soil thin sections. Total extractable carbon showed an increase in the content of humic substances, evidenced by parameters of humification. Enzymatic activities in the A and C1 horizons were also indicative of soil evolution and may serve as a valid indicator for monitoring the evolution of anthropogenic soils containing municipal waste compost. 相似文献
73.
INTRODUCTION: This article describes the validation of an instrument designed to conduct an Occupational Health and Safety (OHS) self-diagnosis using workers observations of tangible facts and actions in the workplace. The instrument puts the emphasis on observable factors that make it possible to act proactively before accidents actually occur. METHOD: Three companies were recruited from the printing sector in Québec based on their OHS performance (low, medium, and high), their interest in the project, and their availability. The master sample was composed of 269 people. Partial least squares (PLS) and vanishing tetrad analyses were used to study the behavior of the formative scales developed. RESULTS: The results indicate that partial revision of the instrument will be necessary to reach a fully satisfying level of validity. With regards to the statistical approach adopted, the use of a macro called CTA-SAS 2.0 developed by Bollen and Ting [Bollen, K.A., & Ting, K.-F. (1993). Confirmatory tetrad analysis. In P.V. Marsden (Ed.), Social methodology.Vol.23 (pp.147-176). Cambridge, MA: Blackwell, 23] has proven to be effective in providing a suitable statistical treatment of the latent formative variables on which our instrument's development is based. CONCLUSION: The results suggest that the instrument appears to be relatively robust and appropriate to diagnose OHS leading measures. IMPACT ON INDUSTRY: In the long run, this instrument will make it possible for companies to draw a more refined picture of OHS evolution, even in the absence of occupational injuries. 相似文献
74.
Heavy metal detoxification in eukaryotic microalgae 总被引:9,自引:0,他引:9
75.
Gödeke S Richnow HH Weiss H Fischer A Vogt C Borsdorf H Schirmer M 《Journal of contaminant hydrology》2006,87(3-4):211-236
At the Centre for Environmental Research Leipzig-Halle (UFZ) research site in Zeitz, Germany, benzene contaminates the lower of two aquifers with concentrations of up to 20 mg/l. Since the benzene plume has a minimum length of approximately 1 km, enhanced natural attenuation measures are being considered as a remediation strategy. This study describes the performance and evaluation of a multi-species reactive tracer test using the tracers fluorescein and bromide as conservative tracers and toluene as reactive tracer. Sampling was performed over a period of six months using a detailed network of multilevel sampling wells. Toluene was only slightly retarded in comparison to bromide, whereas fluorescein was retarded considerably stronger. Therefore, it was not possible to use fluorescein as an in situ tracer for the determination of groundwater velocities. The ionic nature of fluorescein is assumed to be the major reason for its retardation. The results show that the infiltration conditions were suitable to produce a wide spreading of the tracer front along the full thickness of the aquifer. Thus, a large aquifer volume can be treated in future enhanced bioremediation measures. The total quantity of infiltrated toluene (24 l) was degraded under sulfate-reducing conditions over a flow path of 50 m. Benzylsuccinate was identified as a metabolite of toluene degradation under sulfate-reducing conditions at this site. The modelling results show that toluene degradation was described more accurately using Monod kinetics than first-order kinetics. Since toluene was only slightly retarded in comparison to bromide, sorption and desorption processes were considered to be negligible. 相似文献
76.
77.
In situ bioremediation of a hydrocarbon polluted site with cyclodextrin as a coadjuvant to increase bioavailability 总被引:1,自引:0,他引:1
Bioavailability is one main factor that influences the extent of biodegradation of hydrocarbons. They are very poorly soluble in water and easily adsorbed to clay or humus fractions, so they pass very slowly to the aqueous phase where they are metabolised by microorganisms. Cyclodextrins are natural compounds that form soluble inclusion complexes with hydrophobic molecules and increase degradation rate of hydrocarbons in vitro. In the perspective of an in situ application, we previously checked that -cyclodextrin does not increase eluviation of hydrocarbons through the soil and consequently does not increase the risk of groundwater pollution. The results of an in situ application of -cyclodextrin for bioremediation of a hydrocarbon polluted site are presented. We stated that the combination of bioaugmentation and enhanced bioavailability due to -cyclodextrin was effective for a full degradation. 相似文献
78.
Felipe Hernndez‐Luis Mercedes Lemus Domingo Grandoso Mario V. Vzquez Carmen D. Arbelo 《补救:环境净化治理成本、技术与工艺杂志》2005,16(1):107-116
In the Summer 2004 issue of Remediation, the authors presented a study of the influence of buffering behavior in contaminated Andisol soil. This article, Part II, expands on this research by presenting the results of laboratory tests conducted to study the movement of heavy metals in contaminated Andisol soil during the first stage of an electrochemical remediation process. The analysis was performed on the soil after treatment and also on the washing solutions collected during the first four hours. In order to analyze the effectiveness of fast and simple techniques for monitoring the electroremediation process, computer‐aided modeling of speciation in the soil solution was performed in connection with the remediation treatment. The results show that the metals moved mainly as positive species in the soil and later occurred as insoluble forms relative to the pH value in the washing solution from the cathode chamber. © 2005 Wiley Periodicals, Inc. 相似文献
79.
80.
Mario Pérez-Rincón Julieth Vargas-Morales Zulma Crespo-Marín 《Sustainability Science》2018,13(3):635-648
In the global map of environmental injustices (http://www.ejatlas.com), the Andean countries (AC) report many ecological distribution conflicts. Our hypothesis is that the patterns of such conflicts are explained by the structural shifts of the economies and the concomitant changes in their metabolic profiles. Since the 1990s, these countries went through a strong reprimarization process, which changed their social metabolism as well as intensified environmental pressures and conflicts. In monetary terms, in the AC group of countries (Colombia, Ecuador, Peru and Bolivia), the primary sector increased its importance both in exports as well as in GDP. In the metabolic dynamics, the Domestic Extraction of materials (measured in tons) increased by a factor of 3.4 after jumping from 336 to 1145 MT between 1970 and 2012. This was driven by the fossil fuel and mining sectors. This reality was reflected in the environmental conflicts. Mining, fossil fuels, biomass and hydropower plants are the most conflictive sectors. The research in this article relies on a study of material flow analysis for the four AC carried out by the authors as well as 244 environmental conflicts reported in the EJAtlas until August 2016. The shifts in the metabolic–economic patterns help explain the dynamics and characteristics of the environmental conflicts in the AC. Such conflicts produce social mobilizations, which if successful, might help move society towards sustainability and environmental equity. 相似文献