Moderation effect of planning on housing development along the French Atlantic coast: findings from an event history hazard model

Laws and bylaws are regularly challenged for their effectiveness in containing urbanisation sprawl and, conversely, for the constraints they put on development projects. From a French case study, we used survival analysis to disentangle a complex mix of influences on the distribution of residential construction over a 42-year observation period at plot scale when almost everything changes simultaneously. We found that integrated laws and bylaws can slow down coastal urbanisation but do not stop it. Although land planning is becoming more effective, it still provides ample opportunity for residential development because other factors, like distance to existing infrastructure, exert a far stronger influence than the protection of coastal areas. Therefore, this article contributes to filling a knowledge gap about the founding role of public policies on land use dynamics.     

Seasonal variation in trace metals concentrations in the Ialomita River, Romania

Sampling streams for metals is an important aspect of water-quality monitoring. Using ICP-AES the concentration of some microelements in the Ialomi?a River (Romania) were determined. In order to grasp the different phases of the river regime, samples were collected from its water-sediment interface at seven locations along the river, during three campaigns: during snow melting periods in the mountain zones (April), the period of reduced flow and high water temperature (August) and the period of high precipitations (November). HNO3 was added to the samples for fixation. Cadmium and copper appear accidentally; lead was detected only in samples collected in the vicinity of roads; the MAC (maximum admitted concentration) for surface waters is exceeded for nickel and chromium in samples collected in April and respectively in April and November; zinc concentrations were usually above the MAC; molybdenum concentration was above the set reference value, especially for samples collected in April and November. Possible explanations are given for the presence of the investigated microelements along the river.     

Biodegradation of Poly(vinyl alcohol) and Bacterial Cellulose Composites by <Emphasis Type="Italic">Aspergillus niger</Emphasis>

The ability of fungal strains to attack a composite material obtained from poly(vinyl alcohol) (PVA) and bacterial cellulose (BC) is investigated. The fungal strain tested was Aspergillus niger. This fungal strain was able to change not only the polymer surface from smoother to rougher, but also to disrupt the polymer. The degradation results were confirmed by visual observations, scanning electron microscopy (SEM) analyses, X-ray diffraction analyses and FTIR spectra of the film samples. SEM micrographs confirmed the growth of fungi on the composite film surface. The degree of microbial degradation depends on culture medium and on composition of polymeric materials, especially on PVA content. The biodegradation process is accelerated by the presence of glucose in the culture medium as an easily available carbon source.     

Effectiveness of unfertilized buffer strips for reducing nitrogen loads from agricultural lowland to surface waters

Unfertilized buffer strips (BS) are widely accepted to reduce nitrogen (N) loads from agricultural land to surface water. However, the relative reduction of N load or concentration (BS effectiveness, BSE), varies with management and local conditions, especially hydrogeology. We present novel experimental evidence on BSE for 5-m-wide grass BS on intensively drained and managed plain agricultural lowland with varying hydrogeology. We selected characteristic sites for five major hydrogeological classes of the Netherlands and installed paired 5-m-wide unfertilized grass (BS) and reference (REF) treatments along the ditch. The REF was managed like the adjacent field, and BS was only harvested. Treatments were equipped with reservoirs in the ditch to collect and measure discharge and flow proportional N concentration for 3 or 4 yr. In addition, N concentration in upper groundwater was measured. We found a statistically significant BSE of 10% on the peat site. At the other sites, BSE for N was low and statistically insignificant. Low BSE was explained by denitrification between adjacent field and ditch, as well as by the site-specific hydrologic factors including low proportion of shallow groundwater flow, downward seepage, low residence time in the BS, and surface runoff away from the ditch. We emphasize that a REF treatment is needed to evaluate BSE in agriculture and recommend reservoirs if drainage patterns are unknown. Introduction of a 5-m-wide BS is ineffective for mitigating N loads from lowland agriculture to surface waters. We expect more from BS specifically designed to abate surface runoff.     

Polylactide (PLA)—Halloysite Nanocomposites: Production, Morphology and Key-Properties

To evaluate the potential of halloysite nanotubes (HNT) as nanofiller for polylactide (PLA), various nanocomposites have been successfully produced by melt-blending the polyester matrix with HNT (HNT(QM)). HNT were also surface treated by silanization reaction with 3-(Trimethoxysilyl) propyl methacrylate (TMSPM). The morphology, thermal, tensile and impact strength properties of the nanocomposites containing 3?C12?% HNT were evaluated and compared to those of pristine (unfilled) PLA. The nanocomposites were characterized by higher rigidity (with Young??s modulus increasing with HNT loading), higher tensile strength (about 70?MPa at 6?% HNT(QM)), whereas the elongation at break and impact strength did not decrease. As demonstrated under dynamic solicitation (DMA), melt-blending PLA with HNT led to enhancement of storage modulus (E??) and offers the possibility to use PLA in applications requiring higher temperatures of utilization. However, with few exceptions, TGA and DSC measurements did not reveal important changes of thermal parameters. The surface silanization treatment proved to improve the quality of the nanofiller dispersion even at higher loading. As a result, good thermal stability associated to high tensile strength, and noticeable increases in impact properties were recorded. Furthermore, enhanced nucleating ability and crystallization kinetics of the PLA matrix were revealed as specific characteristics.     

Perception of drinking water in the Quebec City region (Canada): the influence of water quality and consumer location in the distribution system

The purpose of every water utility is to provide consumers with drinking water that is aesthetically acceptable and presents no risk to public health. Several studies have been carried out to analyze people's perception and attitude about the drinking water coming from their water distribution systems. The goal of the present study is to investigate the influence of water quality and the geographic location of consumers within a distribution system on consumer perception of tap water. The study is based on the data obtained from two surveys carried out in municipalities of the Quebec City area (Canada). Three perception variables were used to study consumer perception: general satisfaction, taste satisfaction and risk perception. Data analysis based on logistic regression indicates that water quality variations and geographic location in the distribution system have a significant impact on the consumer perception. This impact appears to be strongly associated with residual chlorine levels. The study also confirms the importance of socio-economic characteristics of consumers on their perception of drinking water quality.     

Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)/Organomodified Montmorillonite Nanocomposites for Potential Food Packaging Applications

Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) is a versatile, biobased and biodegradable copolymer from the family of polyhydroxyalkanoates. This study aims to further ameliorate its properties in order to enhance its applicability for food packaging purposes through preparation of organomodified montmorillonite clay (OMMT) nanocomposites. Nanocomposites based on pure PHBHHx as well as commercial PHBHHx granulate, after a previous dry-mixing with OMMT in concentrations of 1, 3, 5 and 10 wt%, were prepared using melt blending and compression molding. Investigation of the samples showed well dispersed nanofiller and highly intercalated nanocomposites, resulting in a continuous decrease in gas permeability, lowering O₂, CO₂ and water vapor permeability with about 5–7 % and approximately 40 % at OMMT concentration of 1 and 10 wt%, respectively. Besides gas permeability, other properties were affected as well. Thermal stability of the samples increased gradually up to 5 wt% nanofiller, but was reduced at 10 wt%. In order to investigate the effects of OMMT and molecular weights on PHBHHx crystallization, nanocomposites were also produced by solvent-casting and compared to those obtained by melt-blending. Crystallization was retarded, because of severe lowering of molecular weight due to processing-induced chain scission, catalyzed by OMMT moisture. However, this reduction was counteracted for a large part by using commercial PHBHHx granulate, which has shown better crystallization properties. The samples were rendered increasingly more brittle, displaying higher Young’s modulus and severely reduced elongation at break. From this study it appeared that, upon viewing all affected properties as a whole, the sample based on commercial PHBHHx and containing 3 wt% OMMT shows most promise for possible applications, however further research must be performed in order to exploit their fullest potential.     

Modelling the distribution of domestic ducks in Monsoon Asia

Domestic ducks are considered to be an important reservoir of highly pathogenic avian influenza (HPAI), as shown by a number of geospatial studies in which they have been identified as a significant risk factor associated with disease presence. Despite their importance in HPAI epidemiology, their large-scale distribution in monsoon Asia is poorly understood. In this study, we created a spatial database of domestic duck census data in Asia and used it to train statistical distribution models for domestic duck distributions at a spatial resolution of 1 km. The method was based on a modelling framework used by the Food and Agriculture Organisation to produce the Gridded Livestock of the World (GLW) database, and relies on stratified regression models between domestic duck densities and a set of agro-ecological explanatory variables. We evaluated different ways of stratifying the analysis and of combining the prediction to optimize the goodness of fit of the predictions. We found that domestic duck density could be predicted with reasonable accuracy (mean RMSE and correlation coefficient between log-transformed observed and predicted densities being 0.58 and 0.80, respectively), using a stratification based on livestock production systems. We tested the use of artificially degraded data on duck distributions in Thailand and Vietnam as training data, and compared the modelled outputs with the original high-resolution data. This showed, for these two countries at least, that these approaches could be used to accurately disaggregate provincial level (administrative level 1) statistical data to provide high resolution model distributions.