In situ remediation of arsenic in contaminated soils

In situ chemical fixation represents a promising and potentially cost‐effective treatment alternative for metal‐contaminated soils. This article presents the findings of the use of iron‐bearing soil amendments to reduce the leachability and bioaccessibility of arsenic in soils impacted by stack fallout from a zinc smelter. The focus of this investigation was to reduce the lead bioaccessibility of the soils through addition with phosphorus‐bearing amendments. However, as phosphorus addition was expected to increase arsenic mobility, the fixation strategy also incorporated use of iron‐bearing amendments to offset or reverse these effects. The findings of this investigation demonstrated that inclusion of iron‐bearing chemicals in the amendment formulation reduced arsenic leachability and bioaccessibility without compromising amendment effectiveness for reducing lead bioaccessibility. These results suggest that in situ chemical fixation has the potential to be an effective strategy for treatment of the impacted soils. © 2003 Wiley Periodicals, Inc.     

Characterisation of Organic Matter and Carbon Cycling in Rehabilitated Lignite-rich Mine Soils

Open-cast lignite mining in the Lusatian mining district resulted in rehabilitated mine soils containing up to four organic matter types: (1) recent plant litter, (2) lignite deposited by mining activity, (3) carbonaceous ash particles deposited during amelioration of the lignite-containing parent substrate and (4) airborne carbonaceous particles deposited during contamination. The influence of lignite-derived carbon types on the organic matter development and their role in the soil carbon cycle was unknown. This paper presents the findings obtained during a six year project concerning the impact of lignite on soil organic matter composition and the biogeochemical functioning of the ecosystem. The organic matter development after rehabilitation was followed in a chronosequence of rehabilitated mine soils afforested in 1966, 1981 and 1987. A differentiation of the organic matter types and an evaluation of their role within the ecosystem was achieved by the use of ¹⁴C activity measurements, ¹³C CPMAS NMR spectroscopy and wet chemical analysis of plant litter compounds. The results showed that the amount and degree of decomposition of the recent organic matter derived from plant material of the 30 year old mine soil was similar to natural uncontaminated forest soil which suggests complete rehabilitation of the ecosystem. The decomposition and humification processes were not influenced by the presence of lignite. On the other hand it was shown that lignite, which was thought to be recalcitrant because of its chemical structure, was part of the carbon cycle in these soils. This demonstrates the need to elucidate further the stabilisation mechanisms of organic matter in soils.     

Troubled waters in the Middle East: the process towards the first Regional Water Declaration between Jordan, Palestinian Authority, and Israel

Water disputes in the Middle East are not a new phenomenon. For the first time, however, three parties in the region, Jordan, Israel, and the PLO for the benefit of the Palestinian Authority have concluded a "regional water agreement" within the framework of the Multilateral Peace talks. For the first time, the rationale behind the agreement is being made public by the author, who was the "neutral" facilitator of the negotiations. The article discusses some of the main elements, including issues related to water scarcity as a driving force of conflicts; application of a "track-two diplomatic" approach; some lessons learned; as well as some ethical questions related to international negotiation.     

IMPLICATIONS OF C.A.R.E. VS. SOUTHVIEW FARM ON THE U.S. LIVESTOCK AND POULTRY INDUSTRY1

ABSTRACT: On May 19, 1993, a jury in the U.S. District Court for the Western District of New York found Southview Farm and Richard H. Popp guilty of violating the Clean Water Act on five occasions. The violations were the result of storm water runoff from a site used for disposal of dairy cattle manure from an unpermitted concentrated animal feeding operation. The presiding District Court judge later dismissed the jury verdict, and subsequently a U.S. Court of Appeals for the Second Circuit reversed the dismissal. The Court of Appeals concluded that the discharges were not exempt as agricultural storm water discharges, and that the manure spreaders involved were point sources. Because the use of animal manures in crop production activities will result, unavoidably, in the discharge of some pollutants to adjacent surface waters, a rational and universally applicable basis is needed to determine when such discharges are point versus nonpoint source. Current statutes and regulations do not delineate clearly such a boundary. To address this lack of specificity, I propose that application rates be based on recommended crop nutrient needs.     

Using digital image projections to visualize forest landscape changes due to management activities and forest growth

A pedagogic problem in forestry and landscape management is to visualize future landscape effects of forest growth and current management activities in the forest. This paper presents a method for forecasting digital image projections of forest landscape dynamics. Static nonlinear regression functions estimate the digital numbers in a Landsat Thematic Mapper image. Regressors used are forest stand variables. By estimating the future forest stand data, based on intermediate treatment and growth, future satellite digital images are created. In a case study example, the future landscape of a forest block in the province of Västernorrland, Sweden, is projected to demonstrate the application of this visualization technique.     

Deposition and Fate of Lead in a Forested Catchment, Lesni Potok, Central Czech Republic

The deposition of trace elements and their fate in a forest ecosystemhas been monitored at the experimental site, Lesni Potok catchment (LP), with granite bedrock. The catchment is located 30 km ESE from Prague. Annual bulk Pb-deposition flux F_Pb was 3.41 kg km^-2 a^-1 in 1994 and gradually decreased to 0.49 kg km^-2 a^-1 in 2001. The decrease is comparable with those observed in Germany and in the U.S.A. in the 1970s and 1980s. The total sales ban of leaded gasoline in the Czech Republic since January 2001 was accompanied by a pronounced decrease of F_Pb in a single year. The residual Pb-deposition flux is assigned to both the long-range transport of fine-grained vehicular lead aerosol (with a long residence time in the atmosphere) and to theemissions from power plant boilers burning lignite mined in the Czech northwest coal basin. The F_Pb of lead correlates stronglywith those of As, Cd, Cu, Zn and Be, the typical metals in coal fly ash, at two monitored sites. Topsoil horizons contain elevated concentrations of Pb (53–67 mg kg^-1), which are of anthropogenicorigin. Soils in the riparian areas contain increased concentrations of Pb when compared to soils on the hillslope areas. Significant amounts of Pb were found on a stream substrate and Fe-precipitate sampled from the stream. Low concentrations of Pb in bark and bole wood suggest that the uptake of Pb by vegetation is negligible. The very small surface water outputs (average of 0.002 kg km^-2 a^-1) compared to inputs (average of 1.890 kg km^-2 a^-1) from the LP catchment indicate an ongoing accumulation of Pb in a forested landscape.     

Review of in situ remediation technologies for lead,zinc, and cadmium in soil

This article presents a review of in situ technologies for the remediation of soils contaminated with lead, zinc, and/or cadmium. The objective of this review is to assess the developmental status of the available in situ technologies and provide a general summary of typical applications and limitations of these technologies. The literature review identified seven in situ remediation technologies—solidification/stabilization, vitrification, electrokinetic remediation, soil flushing, phytoextraction, phytostabilization, and chemical stabilization. These technologies were considered for their ability to meet a specific set of remediation objectives under a range of conditions. Each of these technologies has both strengths and weaknesses for addressing particular remedial situations discussed in the article for each of the technologies. A general summary of which technologies are most applicable to common remedial scenarios is also provided. © 2004 Wiley Periodicals, Inc.     

Building a place-responsive society through inclusive local projects and networks

This paper presents the story of a project undertaken by researchers who are active participants in the national Australian debate over place and belonging. It arose from the desire to ground this debate, which brings issues of ecological sustainability, reconciliation and multiculturalism together, in more localised action aimed at building a 'place-responsive society'. The project was carried out as a case study in a region that combines part of the Sydney metropolitan area and the separate 'city' of the Blue Mountains, and involved a consultative committee and then a regional forum of conservationists, environmental educators and community workers. The researchers explored existing place-oriented initiatives in the region and developed practical projects for the future, most notably a proposal for 'totemic species' work within schools involving local Aboriginal people. The research demonstrated, more than anything else, that indigenous Australian approaches to 'place awareness' and nature conservation remain highly relevant in contemporary Australia. It also showed that bioregional awareness and the notion of place responsiveness can add value to more traditional approaches to nature conservation and environmental education. There are opportunities to galvanise local action that can integrate community and environmental work and revitalise professional practice in both areas, but the effort involves working constantly with difference and conflict.     

The Ethical Contract as a Tool in Organic Animal Husbandry

This article explores what an ethicfor organic animal husbandry might look like,departing from the assumption that organicfarming is substantially based in ecocentricethics. We argue that farm animals arenecessary functional partners in sustainableagroecosystems. This opens up additional waysto argue for their moral standing. We suggestan ethical contract to be used as acomplementary to the ecocentric framework. Weexpound the content of the contract and end bysuggesting how to apply this contract inpractice. The contract enjoins us to share thewealth created in the agroecosystem (by ourjoint contributions) by enjoining us to carefor the welfare and needs of the individualanimal, and to protect them from exploitation(just as human co-workers should not beexploited). The contract makes promoting goodanimal welfare a necessary condition forbenefiting farm animals. Animals for their partare guaranteed coverage under the contract solong as they continue to contribute to thesystem with products and services.