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91.
The hairy root culture of black nightshade (Solanum nigrum) SNC-9O was exposed to 2,2′-dichlorobiphenyl (PCB 4) and 2,6-dichlorobiphenyl (PCB 10) to follow the metabolites produced. The analytical standards of 4-hydroxy-2,2′-dichlorobiphenyl, 5′-hydroxy-2,2′-dichlorobiphenyl, 4-hydroxy-2,6-dichlorobiphenyl, 2-hydroxy-2′,6′-dichlorobiphenyl, 3-hydroxy-2′,6′-dichlorobiphenyl and 4-hydroxy-2′,6′-dichlorobiphenyl have been synthesized. Hydroxy-metabolites of both PCB 4 and PCB 10 were present in the biomass. These appeared mainly as conjugates rather than as free hydroxy-PCBs, both maintained in plant cells. The concentrations of non-conjugated hydroxy-PCBs ranged between 0.9 and 35.2 μg kg−1 of biomass fresh weight and the concentration of the conjugated ones ranged between 2.0 and 113.0 μg kg−1 depending on the position of hydroxyl. The para- position of biphenyl (4 or 4′) seems to be preferred for hydroxylation. Methoxy-PCBs and hydroxy-methoxy-PCBs have also been identified in plant cells. Hydroxyl in the meta-position (3, 3′, 5 or 5′) appears to be preferred for methylation in hydroxy-PCBs. Hydroxy-methoxy-PCBs have occurred in the conjugated form as well. 相似文献
92.
A Quantitative Review of Urban Ecosystem Service Assessments: Concepts,Models, and Implementation 总被引:3,自引:0,他引:3
Dagmar Haase Neele Larondelle Erik Andersson Martina Artmann Sara Borgström Jürgen Breuste Erik Gomez-Baggethun Åsa Gren Zoé Hamstead Rieke Hansen Nadja Kabisch Peleg Kremer Johannes Langemeyer Emily Lorance Rall Timon McPhearson Stephan Pauleit Salman Qureshi Nina Schwarz Annette Voigt Daniel Wurster Thomas Elmqvist 《Ambio》2014,43(4):413-433
Although a number of comprehensive reviews have examined global ecosystem services (ES), few have focused on studies that assess urban ecosystem services (UES). Given that more than half of the world’s population lives in cities, understanding the dualism of the provision of and need for UES is of critical importance. Which UES are the focus of research, and what types of urban land use are examined? Are models or decision support systems used to assess the provision of UES? Are trade-offs considered? Do studies of UES engage stakeholders? To address these questions, we analyzed 217 papers derived from an ISI Web of Knowledge search using a set of standardized criteria. The results indicate that most UES studies have been undertaken in Europe, North America, and China, at city scale. Assessment methods involve bio-physical models, Geographical Information Systems, and valuation, but few study findings have been implemented as land use policy.
Electronic supplementary material
The online version of this article (doi:10.1007/s13280-014-0504-0) contains supplementary material, which is available to authorized users. 相似文献93.
Snezhana Doncheva Michael Moustakas Kalina Ananieva Martina Chavdarova Emiliya Gesheva Rumyana Vassilevska Plamen Mateev 《Environmental science and pollution research international》2013,20(2):823-833
The aim of the present work was to study the response of two sunflower genotypes (cultivated sunflower Helianthus annuus cv. 1114 and newly developed genotype H. annuus?×?Helianthus argophyllus) to Pb medium-term stress and the role of exogenously applied EDTA in alleviating Pb toxicity in hydroponics. Plant growth, morpho-anatomical characteristics of the leaf tissues, electrolyte leakage, total antioxidant activity, free radical scavenging capacity, total flavonoid content, and superoxide dismutase isoenzyme profile were studied by conventional methods. Differential responses of both genotypes to Pb supplied in the nutrient solution were recorded. Pb treatment induced a decrease in the relative growth rate, disturbance of plasma membrane integrity, and changes in the morpho-anatomical characteristics of the leaf tissues and in the antioxidant capacity, which were more pronounced in the cultivated sunflower H. annuus cv. 1114. The new genotype demonstrated higher tolerance to Pb when compared with the cultivar. This was mainly due to increased photosynthetically active area, maintenance of plasma membrane integrity, permanently high total antioxidant activity, and free radical scavenging capacity as well as total flavonoid content. The addition of EDTA into the nutrient solution led to limitation of the negative impact of Pb ions on the above parameters in both genotypes. This could be related to the reduced content of Pb in the roots, stems, and leaves, suggesting that the presence of EDTA limited the uptake of Pb. The comparative analysis of the responses to Pb treatment showed that the deleterious effect of Pb was more pronounced in the cultivated sunflower H. annuus cv. 1114. The new genotype H. annuus?×?H. argophyllus was more productive and demonstrated higher tolerance to Pb medium-term stress, which could indicate that it may possess certain mechanisms to tolerate high Pb concentrations. This character could be inherited from the wild parent used in the interspecific hybridization. The ability of EDTA to prevent Pb absorption by the plants could underly the mechanism of limiting of the negative impact of Pb ions. Hence, EDTA cannot be used to enhance Pb absorption from nutrient solution by sunflower plants for phytoremediation purposes. 相似文献
94.
When estimating human health risks from exposure to TCDD using toxicokinetic and toxicodynamic models, it is important to understand how model choice and assumptions necessary for modeling add to the uncertainty of risk estimates. Several toxicokinetic models have been proposed for the risk assessment of dioxins, in particular the elimination kinetics in humans has been a matter of constant debate. For a long time, a simple linear elimination kinetics has been common choice. Thus, it was used for the statistical analysis of the largest occupationally exposed cohort, the German Boehringer cohort. We challenge this assumption by considering, amongst others, a nonlinear modified Michaelis-Menten-type elimination kinetics, the so-called Carrier kinetics. Using the area under the lipid TCDD concentration time curve as dose metrics, we model the time to cancer-related death using the Cox proportional hazards model as toxicodynamic model. This risk assessment set-up was simulated in order to quantify uncertainty of both the dose (TCDD body burden) and the risk estimates, depending on the use of the kinetic model, variations of carcinogenic effect of TCDD and variations of latency period (lag time). If past exposure is estimated assuming a linear elimination kinetics although a Carrier kinetics actually holds, then high exposures in reality will be underestimated through statistical analysis and low exposures will be overestimated, respectively. This bias will carry over on the estimated individual concentration-time curves and the therefrom derived TCDD dose metric values. Using biased dose values when estimating a dose-response relationship will finally lead to biased risk estimates. The extent of bias and the decrease of precision are quantified in selected scenarios through this simulation approach. Our findings are in concordance with recent results in the field of dioxin risk assessment. They also reinforce the general demand for the scheduled uncertainty assessments in risk analyses. 相似文献
95.
Misík M Micieta K Solenská M Misíková K Pisarcíková H Knasmüller S 《Environmental pollution (Barking, Essex : 1987)》2007,145(2):459-466
Aim of the study was to monitor changes of genotoxic activity of urban air caused by an incinerator and a petrochemical plant in Tradescantia micronucleus (Trad-MCN) and pollen fertility assays with wild plants (Chelidonium majus, Clematis vitalba, Cichorium intybus, Linaria vulgaris, Robinia pseudoacacia). While in the first sampling period (1997-2000) significantly (on average 80%) more MN were found at the polluted site in comparison to controls from a rural area, no significant effects were observed during a later period (between 2003 and 2005). A similar pattern was observed in the pollen abortion assays in which the most pronounced effects were found in chicory and false acacia. The differences of the results obtained in the two periods can be explained by a substantial reduction of air pollution by use of new technologies. In particular the decrease of SO(2) emissions may account for the effects seen in the present study. 相似文献
96.
Monitoring, assessment and modelling using water quality data in the Saale River Basin, Germany 总被引:1,自引:0,他引:1
Bongartz K Steele TD Baborowski M Lindenschmidt KE 《Environmental monitoring and assessment》2007,135(1-3):227-240
The European Water Framework Directive (WFD) is the overall driver for this environmental study and currently requires the
identification of patterns and sources of pollution (monitoring) to support objective ecological sound decision making and
specific measures to enhance river water quality (modelling). The purpose of this paper is to demonstrate in a case study
the interrelationship between (1) hydrologic and water quality monitoring data for river basin characterization and (2) modelling
applications to assess resources management alternatives. The study deals with monitoring assessment and modelling of river
water quality data of the main stem Saale River and its principal tributaries. For a period of 6 years the data, which was
sampled by Environmental Agencies of the German states of Thuringia, Saxony and Saxony-Anhalt, was investigated to assess
sources and indicators of pollution. In addition to the assessment a modelling exercise of the routing of different pollutants
was carried out in the lower part of the test basin. The modelling is a tool to facilitate the evaluation of alternative measures
to reduce contaminant loadings and improve ecological status of a water body as required by WFD. The transport of suspended
solids, salts and heavy metals was modelled along a selected Saale reach under strong anthropogenic influence in terms of
contaminants and river morphology between the city of Halle and the confluence with the Elbe River. The simulations were carried
out with the model WASP5 which is a dynamic flood-routing and water quality model package developed by the US Environmental
Protection Agency. 相似文献
97.
Rapinski Michel Payette Fanny Sonnentag Oliver Herrmann Thora Martina Royer Marie-Jeanne S. Cuerrier Alain Siegwart Collier Laura Hermanutz Luise Guanish George 《Regional Environmental Change》2018,18(1):189-203
Regional Environmental Change - For Inuit and Naskapi living in the eastern Canadian Subarctic, local meteorological and environmental conditions (e.g., snow and ice cover extent, thickness, and... 相似文献
98.
99.
100.
Anna Doffini Claudio Forcato Chiara Mangano Debora Lattuada Roberta Aversa Chiara Maranta Emilia D. Giovannone Genny Buson Chiara Bolognesi Rebecca Maiocchi Martina Dori Liyana Jamal Raidah B. Ahmad George S. H. Yeo Tai Wai Yeo Silvia Saragozza Rosamaria Silipigni Marta Serafini Andrea Biondi Sofia Perego Patrizia Vergani Enrico Ferrazzi Paola Ricciardi-Castagnoli Thomas J. Musci Francesca Romana Grati 《黑龙江环境通报》2023,43(1):14-27