全文获取类型
收费全文 | 113篇 |
免费 | 0篇 |
国内免费 | 15篇 |
专业分类
安全科学 | 1篇 |
废物处理 | 40篇 |
环保管理 | 2篇 |
综合类 | 26篇 |
基础理论 | 10篇 |
污染及防治 | 40篇 |
评价与监测 | 2篇 |
社会与环境 | 6篇 |
灾害及防治 | 1篇 |
出版年
2021年 | 2篇 |
2019年 | 1篇 |
2018年 | 6篇 |
2017年 | 6篇 |
2016年 | 5篇 |
2015年 | 3篇 |
2014年 | 4篇 |
2013年 | 14篇 |
2012年 | 12篇 |
2011年 | 9篇 |
2010年 | 3篇 |
2009年 | 11篇 |
2008年 | 6篇 |
2007年 | 18篇 |
2006年 | 5篇 |
2005年 | 2篇 |
2004年 | 7篇 |
2003年 | 3篇 |
2002年 | 4篇 |
2001年 | 3篇 |
2000年 | 1篇 |
1990年 | 1篇 |
1985年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有128条查询结果,搜索用时 15 毫秒
121.
Takaaki Tanak Toshiyuki Tamur Yuuichi Ishizaki Akito Kawasaki Tomokazu Kawase Masahiro Teraguchi Masayuki Taniguchi 《环境科学学报(英文版)》2009,21(6):731-735
Natural and synthetic estrogens from sewage treatment systems are suspected to influence the reproductive health of the animals in the rivers.In this article we investigated the enzymatic treatment of three estrogens (estrone,17β-estradiol,and 17α-ethynyletstradiol) by a fungal laccase which oxidize phenolic compounds with dissolved oxygen.The elimination of the estrogenic activities by enzymatic oxidation was demonstrated by medaka vitellogenin assay.In addition,we developed an enzymatic treatment system comprised of β-D-glucuronidase and the laccase for 17β-estradiol 3-(β-D-glucuronide) degradation.The two enzymes eliminated 17β-estradiol 3-(β-D-glucuronide) and the intermediate,17β-estradiol,efficiently. 相似文献
122.
A composting toilet using sawdust as a matrix has the potential to trap pathogens that might occasionally be contained in human
feces. Therefore, care should be taken when handling the sawdust. It should also be noted that pathogenic viruses tend to have stronger
tolerance than pathogenic bacteria. The fates of several species of coliphages, T4, , Q and MS2, in sawdust were investigated as
a viral model. The fates of coliphages were significantly different among them, and they changed in response to temperature and the
water content of the sawdust. As the results, T4 coliphage had the strongest tolerance and Q had the weakest one in sawdust. It was
estimated the days required to decrease virus to a safe level based on a risk assessment. According to the rates of Q and T4, 15 days
and 167 days were required respectively for a safe level of infection risk based on actually operated composting toilet condition. Thus,
it was significantly different depending on the species and sawdust conditions. 相似文献
123.
Hiroshi Takakuwa Takashi Miura Toru Matsumura Norie Hashi Michiyo Kubota Hiroshi Kutsukake Kazuhiro Muramatsu Takashi Kasamatsu Masahiro Okuda 《Environmental science and pollution research international》2018,25(17):16300-16308
It is necessary for companies supplying reclaimed oil to analyze polychlorinated biphenyls (PCBs), because there is a possibility of the presence of contaminants due to trace-level PCBs in the reclaimed oil. However, common analysis methods of PCBs are time-consuming and complicated. Fast-GC triple stage quadrupole mass spectrometer with the 13-component quantitation method is an official method for analyzing PCBs in insulating oil in Japan. This method is extremely fast and simplified. The purpose of this study involves an investigation of the aforementioned fast and simple method for potential use in the analysis of reclaimed oil. Furthermore, it was attempted to combine the method with sample preparation involving only hexane dilution. The effect of sample dilutions corresponding to 100, 300, and 500 times was evaluated for reducing the matrix effect. The matrix effect was suppressed at a dilution ratio equal to or exceeding 300 times. Calibration curves of four points, namely 0.01, 0.05, 0.1, and 0.5 ng/mL, (ignored origin) by using an internal standard method were prepared for the 13 components. The square of regression coefficient (R2) values of all calibration curves exceeded 0.997. This method was adopted for the analysis of reclaimed oil containing 0.5 μg/mL PCBs, which corresponds to the judgment criteria, and accurate quantitation (accuracy value, 94.0–102%) and good repeatability (%RSD, 3.6%) were obtained. Furthermore, the required sensitivity was maintained even when 800 samples were analyzed without a cleaning ion source and an exchanging analysis column. 相似文献
124.
In Japan, melting-furnace fly ash (MFA) generated from ash melting and gasification/melting plants is considered an “urban
mine” due to its high metal content. This study aimed to develop a novel approach to pretreating MFA for metal recovery. Water
extraction with CO2 bubbling was investigated because MFA mainly consists of water-soluble salts containing elements such as Cl, Ca, Na, and
K. Instead of acid addition, CO2 bubbling was applied to maintain the optimal pH for minimizing the release of target metal elements and maximizing the removal
of undesirable elements during water extraction. The results revealed that CO2 bubbling effectively decreased the release of Pb, Zn, and Cd into the treatment water. This was mainly due to coprecipitation
with CaCO3, which was primarily formed by the reaction of Ca2+ from the MFA with CO3
2− from the CO2 gas. The bubbling process also helped accelerate the removal of Cl from MFA. Furthermore, the study showed that it is possible
to lower the water-to-solid ratio to 5 with only a slight reduction in water extraction effect. Finally, approximately four
times the concentration of target metals (rare metals and Cu, Pb, and Zn) was achieved by removing 90% of Cl, 70%–90% of Na
and K, and 30%–40% of Ca through water extraction with CO2 bubbling, resulting in a concentration of target metals that was nearly equal to that of ore. 相似文献
125.
A novel process for degradation of toluene in the gas-phase using heterogeneous gas-liquid photocatalytic oxidation has been developed. The degradation of toluene gas by photo-Fenton reaction in the liquid-phase has experimentally examined. The photo-Fenton reaction in the liquid-phase could improve the overall toluene absorption rate by increasing the driving force for mass transfer and as a result enhance the removal of toluene in the exhaust gas. The toluene concentrations in the inlet gas were varied in the range from 0.0968 to 8.69gm(-3) with initial hydrogen peroxide concentration of 400mgl(-1) and Fe dose of 5.0mgl(-1). It was found that toluene in the inlet gas was almost completely dissolved into water and degraded in the liquid-phase for the inlet toluene gas concentration of less than 0.42gm(-3). The dynamic process of toluene gas degradation by the photo-Fenton reaction providing information for reaction kinetics and mass transfer rate was examined. Toluene removal kinetic analysis indicated that photo-Fenton degradation was significantly affected by H(2)O(2) concentration. The experimental results were satisfactorily described by the predictions simulated using the simplified tanks-in-series model combined with toluene removal kinetic analysis. The present results showed that the proposed chemical absorption process using the photo-Fenton heterogeneous gas-liquid photocatalytic oxidation is very effective for degradation of volatile organic gases. 相似文献
126.
Chisato Mori Kazuhiko Kakuta Yoshiharu Matsuno Emiko Todaka Masahiro Watanabe Masamichi Hanazato Yukiko Kawashiro Hideki Fukata 《Environmental science and pollution research international》2014,21(10):6434-6439
Individuals’ exposure to various persistent organic pollutants (POPs), including polychlorinated biphenyls (PCBs), and its adverse health effects have been a cause of concern. We measured blood PCB concentrations from samples taken from 507 Japanese individuals ranging from infants to those over 80 years of age. The blood PCB levels increased with age for both male (Spearman’s r?=?0.69, p?<?0.001) and female (Spearman’s r?=?0.70, p?<?0.001) participants. Adult men and nulliparous women showed similar increases with age. However, the PCB levels of multiparous women were lower than those of nulliparous women in their thirties (p?=?0.005), probably because the PCBs were transferred from the mothers to their children during pregnancy and lactation. Among infants (<2 years of age), some had as high levels of accumulated PCB levels as those in adults >30 years of age. In some cases, the PCB levels were over 0.8 ng/g wet weight, similar to levels observed in adults over 50 years of age. In the future, it will be necessary to do research on the health of the children who are exposed by high concentration level of POPs. 相似文献
127.
128.
Vinay Kumar Jha Masahiro Nagae Motohide MatsudaMichihiro Miyake 《Journal of environmental management》2009
Zeolitic materials have been prepared from coal fly ash as well as from a SiO2–Al2O3 system upon NaOH fusion treatment, followed by subsequent hydrothermal processing at various NaOH concentrations and reaction times. During the preparation process, the starting material initially decomposed to an amorphous form, and the nucleation process of the zeolite began. The carbon content of the starting material influenced the formation of the zeolite by providing an active surface for nucleation. Zeolite A (Na-A) was transformed into zeolite X (Na-X) with increasing NaOH concentration and reaction time. The adsorption isotherms of the obtained Na-X based on the characteristics required to remove heavy ions such as Ni2+, Cu2+, Cd2+ and Pb2+ were examined in multi-metal systems. Thus obtained experimental data suggests that the Langmuir and Freundlich models are more accurate compared to the Dubinin–Kaganer–Radushkevich (DKR) model. However, the sorption energy obtained from the DKR model was helpful in elucidating the mechanism of the sorption process. Further, in going from a single- to multi-metal system, the degree of fitting for the Freundlich model compared with the Langmuir model was favored due to its basic assumption of a heterogeneity factor. The Extended-Langmuir model may be used in multi-metal systems, but gives a lower value for equilibrium sorption compared with the Langmuir model. 相似文献