聚二甲基二烯丙基氯化铵与聚合硫酸铁复合絮凝剂的制备及应用研究

在一定温度下 ,将聚二甲基二烯丙基氯化铵 (PDMDAAC)溶解在聚合硫酸铁 (PFS)中 ,制成稳定的均相复合溶液。采用FT IR和X 射线衍射对其固体结构进行了分析。考察了液体复合絮凝剂的稳定性和固体复合絮凝剂的吸湿溶解性能 ,及其对生活污水的处理效果。结果表明 :在 6 0℃以下制备的液体复合絮凝剂具有良好的稳定性 ,固体复合絮凝剂具有良好的溶解性和比PFS更强的吸湿性 ;复合絮凝剂不是由PDMDAAC与PFS简单的机械混和 ,而是互相融合的复合体系 ;具有比PFS更优的去污性能和与PFS类似的较宽的最佳投药范围和 pH适用范围。对浊度和COD分别为 10 5 2和 187 5mg/L ,pH值为 7 5 9的生活污水 ,复合絮凝剂中Fe3 + 和PDMDAAC最佳用量分别为 5 4 .15和 4 2 7mg/L ,对COD的去除率为 77 14 % ,比PFS在用量为 81 2 2mg/L时的最佳效果高 12 %。     

城市生活污水厌氧生物处理发展现状

回顾了国内外污水厌氧生物处理工艺的发展情况,着重分析了中国城市污水的特点以及厌氧生物处理工艺在城市生活污水处理中的应用情况。     

短程硝化的实现、维持与过程控制的研究现状

短程生物脱氮技术目前倍受人们的关注,国内外学者对短程硝化提出了多种实现及维持的控制途径,但仍存在着一些问题。由于活性污泥法中DO,ORP,pH的变化规律从不同角度不同程度地反映了生物脱氮反应的进程,所以用它们作为控制参数就可以对生物脱氮反应进行过程控制。在分析中,通过对国内外短程硝化控制途径的研究现状与发展趋势的分析和总结,针对目前在实现短程硝化及维持短程硝化各种途径中存在的问题,提出了通过在线检测DO,pH,ORP来实现与维持短程硝化的新思路。     

H2O2处理酸性大红GR染料废水的研究

通过对废水pH值、H2O2用量、催化剂用量、反应时间、反应温度等工艺条件的考察,确定了H2O2催化氧化处理酸性大红染料废水的最佳工艺条件pH 4、H2O2用量6 mL/L、催化剂用量3 g/L、反应时间100 min、反应温度70℃.在该条件下,COD和色度的去除率分别为76.7%和99.4%;通过反应前后的紫外-可见光光谱分析表明,H2O2催化氧化处理酸性大红GR染料废水有比较好的效果,为该工艺处理酸性大红GR染料废水提供了科学依据.     

高速飞机弹射救生时的气流吹袭及其防护

飞行员在高速弹离飞机时,会受到气流的吹袭。如何防护高速弹射时受到的气流吹袭,是各国航空救生业一直致力解决的问题。本文介绍了高速气流吹袭的危害性和对人体的影响,以及可以采取的一些防护措施,供科研人员参考。     

A review of regulations and guidelines related to winter manure application

Winter manure application elevates nutrient losses and impairment of water quality as compared to manure applications in other seasons. In conjunction with reviewing global distribution of animal densities, we reviewed worldwide mandatory regulations and voluntary guidelines on efforts to reduce off-site nutrient losses associated with winter manure applications. Most of the developed countries implement regulations or guidelines to restrict winter manure application, which range from a regulative ban to guidelines based upon weather and field management conditions. In contrast, developing countries lack such official directives, despite an increasing animal production industry and concern over water quality. An analysis of five case studies reveals that directives are derived from a common rationale to reduce off-site manure nutrient losses, but they are also affected by local socio-economic and biophysical considerations. Successful programs combine site-specific management strategies along with expansion of manure storage to offer farmers greater flexibility in winter manure management.     

The fractionation and geochemical characteristics of rare earth elements measured in ambient size-resolved PM in an integrated iron and steelmaking industry zone

Environmental Science and Pollution Research - Improved understanding of the fractionation and geochemical characteristic of rare earth elements (REEs) from steel plant emissions is important due...     

响应面法优化石油降解菌性能的研究

从延长油田石油污染土壤中筛选出4株能以原油为唯一碳源生长的细菌单菌株,鉴定其优势菌株YC-2为枯草芽孢杆菌;利用响应面法进行实验设计,选定培养温度、pH值、氮磷比以及盐度为影响因素,对原油含量为0.5%的培养基进行YC-2菌株降解工艺优化,得到了原油降解率与4种因素之间的非线性回归方程,确定了降解原油的最优工艺条件:培养温度28℃;pH值6.5,氮磷比5.2:1,盐度0.45%。在最优条件下,预测降解率为53.9%,实验验证值为52.5%,结果显示,建立的模型具有较高的精度。     

印染污泥连续过滤压榨过程

研究了连续进料情况下,过滤压力、压榨起始点和压榨压力对印染污泥过滤效果的影响。研究发现,提高过滤压力可以改善过滤效率,缩短过滤时间,但滤饼含水率并无明显影响。过滤压力0.6 MPa下过滤2.3 h后滤液量达到2 900 g,此时过滤进入压密阶段。结果表明,若适当提前压榨,可在滤饼含水率变化不大的情况下显著缩短过滤时间,且该污泥在滤液量为2 750 g时开始压榨,滤饼含水率仅提高约1%,而过滤时间缩短为原来的87%(2 h)。进一步研究压榨压力对污泥脱水的影响,发现提高压榨压力也可以提高滤液流速,降低滤饼含水率,但因为在高压下更容易发生絮体破裂成细微粒子等现象,使过滤介质堵塞或滤饼中的一些孔变成盲孔,所以过高的压力不仅不能起到提高压榨效率的作用,反而会使滤饼含水率有所上升,且该污泥的最佳压榨压力为2.5 MPa。     

Immobilization of fungal laccase onto a nonionic surfactant-modified clay material: application to PAH degradation

Nonionic surfactant-modified clay is a useful absorbent material that effectively removes hydrophobic organic compounds from soil/groundwater. We developed a novel material by applying an immobilized fungal laccase onto nonionic surfactant-modified clay. Low-water-solubility polycyclic aromatic hydrocarbons (PAHs) (naphthalene/phenanthrene) were degraded in the presence of this bioactive material. PAH degradation by free laccase was higher than degradation by immobilized laccase when the surfactant concentration was allowed to form micelles. PAH degradation by immobilized laccase on TX-100-modified clay was higher than on Brij35-modified clay. Strong laccase degradation of PAH can be maintained by adding surfactant monomers or micelles. The physical adsorption of nonionic surfactants onto clay plays an important role in PAH degradation by laccase, which can be explained by the structure and molecular interactions of the surfactant with the clay and enzyme. A system where laccase is immobilized onto TX-100-monomer-modified clay is a good candidate bioactive material for in situ PAHs bioremediation.