Stable isotopic evidence for trophic groupings and bio-regionalization of predators and their prey in oceanic waters off eastern Australia

Muscle tissue was collected for stable isotope analysis (SIA) from the main fish predators and their fish and cephalopod prey from oceanic waters off eastern Australia between 2004 and 2006. SIA of δ¹⁵N and δ¹³C revealed that the species examined could be divided into three main trophic groups. A “top predator” group consisted mainly of large billfish (Xiphias gladius and Tetrapturus audax), yellowfin (Thunnus albacares), bigeye (T. obesus) and southern bluefin (T. maccoyii) tunas and sharks; with mako (Isurus oxyrinchus) the highest. Below this tier was a second group composed of mid-trophic level fishes including albacore tuna (Thunnus alalunga), lancet fish (Alepisaurus ferox), mahi mahi (Coryphaena hippuris) and ommastrephid squid. Underlying both groups was a grouping of small fishes including myctophids, small scombrids and nomeids as well as surface fishes including macrorhamphosids. These groupings were based largely on mean animal size which showed a positive linear relation to δ¹⁵N (r ² = 0.58). Some species showed significant ontogenetic variation in either δ¹⁵N (swordfish, lancet fish, yellowfin and albacore tuna) or δ¹³C (mako shark). We also noted a consistent latitudinal change in δ¹⁵N and δ¹³C at ~28°S for the top predator species, particularly albacore and yellowfin tuna. The differences were consistent with a change from oligotrophic Coral Sea to nutrient rich Tasman Sea waters. These differences suggest that predatory fishes may have extended residence time in distinct regions off eastern Australia.     

Reactive transport of 85Sr in a chernobyl sand column: static and dynamic experiments and modeling

The effects of nonlinear sorption and competition with major cations present in the soil solution on radioactive strontium transport in an eolian sand were examined. Three laboratory techniques were used to identify and quantify the chemical and hydrodynamic processes involved in strontium transport: batch experiments, stirred flow-through reactor experiments and saturated laboratory columns. The major goal was to compare the results obtained under static and dynamic conditions and to describe in a deterministic manner the predominant processes involved in radioactive strontium transport in such systems. Experiments under dynamic conditions, namely flow-through reactor and column experiments, were in very good agreement even though the solid/liquid ratio was very different. The experimental data obtained from the flow-through reactor study pointed to a nonlinear, instantaneous and reversible sorption process. Miscible displacement experiments were conducted to demonstrate the competition between stable and radioactive strontium and to quantify its effect on the 85Sr retardation factor. The results were modeled using the PHREEQC computer code. A suitable cation-exchange model was used to describe the solute/soil reaction. The model successfully described the results of the entire set of miscible displacement experiments using the same set of parameter values for the reaction calculations. The column study revealed that the stable Sr aqueous concentration was the most sensitive variable of the model, and that the initial state of the sand/solution system had also to be controlled to explain and describe the measured retardation factor of radioactive strontium. From these observations, propositions can be made to explain the discrepancies observed between some data obtained from static (batches) and dynamic (reactor and column) experiments. Desorbed antecedent species (stable Sr) are removed from the column or reactor in the flow system but continue to compete for sorption sites in the batch system. Batch experiments are simple and fast, and provide a very useful means of multiplying data. However, interpretation becomes difficult when different species compete for sorption sites in the soil/solution system. A combination of batches, flow-through reactor and column experiments, coupled with hydrogeochemical modeling, would seem to offer a very powerful tool for identifying and quantifying the predominant processes on a cubic decimeter scale (dm3) and for providing a range of radioactive strontium retardation factor as a function of the geochemistry of the soil/solution system.     

Reclamation of phytotoxic tailing

The reclamation of tailing that is toxic to vegetation (phytotoxic) was the subject of laboratory and field research. Using trona tailing as an example of phytotoxic waste, research identified three areas that may be critical to reclamation:

establishment and maintenance of a capillary barrier to prevent upward migration of plant toxicants into the plant-rooting zone;

water drainage or evaporation to prevent or control water accumulation within the tailing;

soil requirements for revegetation.

A pilot reclamation program was developed in which a 20-cm layer of coarse gravel formed a capillary barrier between phytotoxic tailing and overlying material. To maintain the integrity of the capillary barrier, a 20-cm layer of fine gravel was applied to the coarse gravel surface; soil was then applied to the fine gravel surface. A zone of shallow soil was used to allow water, which collected during the late winter, to evaporate from the tailing during the dry summer. Soil depth requirements were assessed by measuring the response of shrubs and grasses to increasing soil depth.     

Realizing an effectiveness revolution in environmental management

The environmental movement of the 20(th) century has evolved into a large, diverse and well-financed global community that is increasingly required to prove its worth. Though the environmental sector collects and uses data to determine the status of ecological and social systems, the effectiveness of the programs and policies it uses to affect this status remains largely untested. As governments and donor institutions insist on greater transparency, accountability and evidence of what works and what does not, much is being learned from other fields (e.g. health services, education, international development) and increasingly sophisticated approaches are emerging to manage effectiveness. For example, program evaluation, adaptive management, and systematic review provide frameworks and methods to collect and use information to measure and improve performance. However, the critical data and collaborations necessary for an effectiveness revolution are marginalized by technical, cultural and political obstacles. Learning from other fields, the environmental sector must exploit key leverage points, such as flows of information and self-organization, to overcome impediments and create incentives to initiate and realize an era of effectiveness in environmental management.     

Suitability of ignition source “exploding wire” for determination of dust explosion characteristics in the 20-L-sphere

Several safety characteristics of dusts are determined in the 20-L-sphere (also known as SIWEK Chamber) according to international standards. Dust cloud ignition is carried out using pyrotechnical igniters. Due to various disadvantages of such igniters the need for alternative ignition sources arises again and again. An alternative could be an ignition source which is known as “exploding wire” or “fuse wire”. The paper presents test results of a comparative study between both ignition sources for the determination of the safety characteristics “Maximum Explosion Pressure” and “Maximum Rate of Explosion Pressure Rise” of five selected dusts in the 20-L-sphere. In addition to that the ignition mechanisms of both ignition sources were analyzed by high speed camera recordings and the ignition energy was determined with electric and calorimetric recordings. The paper shows results of measurements of the ignition energy of both ignition sources as well as sequences of the flame propagation.     

Sustainable local land use policy: rhetoric and reality

Abstract

This study examined trends in population redistribution and residential land use changes in northeast Scotland during 1988 to 2003. We utilised a geographical information system (GIS) tool to bring together data from interrelated sources and to analyse population settlement and land use changes at detailed spatial scale. This analysis revealed that substantial land conversion had taken place in the region; particularly conversion of agricultural lands to built-up and residential areas. It also drew attention to policy conflicts, discrepancies between policy rhetoric and policy implementations. More specifically, it was shown that substantial farm land conversion had taken place in suburban areas and rural Aberdeenshire with little change in the size of derelict land in Aberdeen City. The reason given for this was that it was costly to rehabilitate and reuse derelict lands and this conflicted with the objective of providing affordable housing in the City region. The implication of this study is that if the declared policy objectives of integrated and sustainable land use and transport policies are to be achieved, then local authorities may need to cooperate to minimise conflicts between economic and environmental objectives.     

Relationships between water quality, habitat quality, and macroinvertebrate assemblages in Illinois streams

The influence of specific stressors, such as nutrient enrichment and physical habitat degradation, on biotic integrity requires further attention in Midwestern streams. We sampled 53 streams throughout Illinois and examined relationships between macroinvertebrate community structure and numerous physicochemical parameters. Streams were clustered into four major groups based on taxa dissimilarity. Habitat quality and dissolved nutrients were responsible for separating the major groups in a nonmetric multidimensional scaling ordination. Furthermore, the alignment of environmental factors in the ordination suggested there was a habitat quality-nutrient concentration gradient such that streams with high-quality habitats usually had low concentrations of nutrients. Discrimination by community measures further validated the major stream groups and indicated that forested streams had generally higher biological integrity than agricultural streams, which in turn had greater integrity than urban streams. Our results demonstrate that physical habitat degradation and nutrient pollution are important and often confounded determinants of biotic integrity in Illinois streams. In addition, we suggest that management of Midwestern streams could benefit from further implementation of multivariate data exploration and stream classification techniques.     

Validation of three new methods for determination of metal emissions using a modified Environmental Protection Agency Method 301

Three new methods applicable to the determination of hazardous metal concentrations in stationary source emissions were developed and evaluated for use in U.S. Environmental Protection Agency (EPA) compliance applications. Two of the three independent methods, a continuous emissions monitor-based method (Xact) and an X-ray-based filter method (XFM), are used to measure metal emissions. The third method involves a quantitative aerosol generator (QAG), which produces a reference aerosol used to evaluate the measurement methods. A modification of EPA Method 301 was used to validate the three methods for As, Cd, Cr, Pb, and Hg, representing three hazardous waste combustor Maximum Achievable Control Technology (MACT) metal categories (low volatile, semivolatile, and volatile). The modified procedure tested the methods using more stringent criteria than EPA Method 301; these criteria included accuracy, precision, and linearity. The aerosol generation method was evaluated in the laboratory by comparing actual with theoretical aerosol concentrations. The measurement methods were evaluated at a hazardous waste combustor (HWC) by comparing measured with reference aerosol concentrations. The QAG, Xact, and XFM met the modified Method 301 validation criteria. All three of the methods demonstrated precisions and accuracies on the order of 5%. In addition, correlation coefficients for each method were on the order of 0.99, confirming the methods' linear response and high precision over a wide range of concentrations. The measurement methods should be applicable to emissions from a wide range of sources, and the reference aerosol generator should be applicable to additional analytes. EPA recently approved an alternative monitoring petition for an HWC at Eli Lilly's Tippecanoe site in Lafayette, IN, in which the Xact is used for demonstrating compliance with the HWC MACT metal emissions (low volatile, semivolatile, and volatile). The QAG reference aerosol generator was approved as a method for providing a quantitative reference aerosol, which is required for certification and continuing quality assurance of the Xact.     

重型机动车实际排放特性与影响因素的实测研究

利用美国Sensors公司生产的SEMTECHD车载排放测试仪在上海随机选择了7辆重型柴油车开展实际道路的排放测试,该实验累积测试道路长度为186km,共取得29090个逐秒的有效工况点数据,其中城市主干道12979个,次干道12368个,快速干道3743个.给出了车辆在不同道路上的工况点分布,分析了速度、加速度对燃油消耗、尾气排放的影响.测试结果表明,在选定的城市道路上,车流的平均怠速工况比为17%,加速工况比23.6%,等速工况比为31.0%,减速工况比为28.5%.被测车辆的CO、THC、NOx平均排放因子分别为(4.41±2.46)g·km-1、(1.77±1.17)g·km-1和(6.96±1.93)g·km-1,车辆排放状况因车速、加速度等因素而不同.测试结果基本反映了目前上海道路的交通状况和柴油卡车的排放现状,同时也说明过低的车速和频繁加减速是加重机动车污染的重要原因.