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191.
Diana Reckien Klaus Eisenack Matthias K. B. Lüdeke 《Environmental Modeling and Assessment》2011,16(5):465-477
A new modelling approach to urban sprawl dynamics is introduced which allows representing qualitative knowledge on relations
between moving actor populations and properties of locations. The results of this Qualitative Attractiveness Migration (QuAM)
Model are scenario-like sets of possible future developments of the urban system, much in contrast to quantitative forecasts
gained by traditional modelling approaches. QuAM models allow for the interaction between internal dynamics and external influences.
The application of the new approach is exemplified by the case of urban sprawl in Leipzig since 1990. It was possible to reproduce
the observed qualitative development and to calculate future scenarios. The scenario runs project a new wave of middle class
driven residential sprawl and suggest implications for sprawl reducing policy interventions. 相似文献
192.
Transition to sustainability is a search for ways to improve the social capacity to guide interactions between nature and society toward a more sustainable future and, thus, a process of social learning in its broadest sense. Accordingly, it is not only learning that is at issue but education and educational science, of which the latter is about exploring the preconditions of and opportunities for learning and education—whether individual or social, in formal or informal settings. Analyzing how educational science deals with the challenge of sustainability leads to two complementary approaches: the ‘outside-in’ approach sees the idea of sustainability influencing educational practice and the way the relationship of learning and teaching is reviewed, theoretically as well as within the social context. In an ‘inside-out’ approach, an overview is given of how educational science can contribute to the field of sustainability science. An examination of the literature on education and sustainability shows that, while sustainability features prominently in one form or another across all sectors, only little work can be found dealing with the contributions of educational science within sustainability science. However, as sustainability is a concept that not only influences educational practices but also invites disciplinary contributions to foster inter- and transdisciplinary research within the sustainability discourse, the question remains as to how and to what extent educational science in particular can contribute to sustainability science in terms of an ‘inside-out’ approach. In this paper, we reconstruct the emergence of education for sustainable development as a distinctive field of educational science and introduce and discuss three areas of sustainability research and throw into relief the unique contribution that educational science can make to individual action and behavior change, to organizational change and social learning, and, finally, to inter- and transdisciplinary collaboration. 相似文献
193.
Zhiyuan Zhong Stefan Schneiderbauer Pieter J. Dijkstra Matthias Westerhausen Jan Feijen 《Journal of Polymers and the Environment》2001,9(1):31-38
The ring-opening polymerization of l-lactide with calcium alkoxides generated in-situ from bis(tetrahydrofuran)calcium bis[bis(trimethylsilyl)amide] and 2-propanol are presented. The polymerization in THF at room temperature proceeds rapidly and in a living manner, giving poly(l-lactide)s of controlled molecular weight, low polydispersity, and tailored end-functionalities. Kinetic studies show the absence of an induction period and a pseudo-first order rate constant of 6.41 L mol–1 min–1, which is significantly higher than for related Y5(-O)(O
i
Pr)13– or aluminum alkoxide-initiated polymerizations. The initiation involves a two-step process: (1) alcoholysis of bis(tetrahydrofuran)calcium bis[bis(trimethylsilyl)amide] to give the corresponding calcium alkoxide and (2) ring-opening of l-lactide via acyl-oxygen cleavage and insertion into the calcium-alkoxide bond. In the presence of excess alcohol, fast and reversible exchange between free alcohol molecules and coordinated alkoxide ligands takes place. This allows tuning of the poly(l-lactide) molecular weight over a wide range. 相似文献
194.
Changes in material use, energy use and emissions profiles of industry are the result of complex interrelationships among a multitude of technological and economic drivers. To better understand and guide such changes requires that attention is paid to the time-varying consequences that technology and economic influences have on an industry's choice of inputs and its associated (desired and undesired) outputs. This paper lays out an approach to improving our understanding of the dynamics of large industrial systems. The approach combines engineering and econometric analysis with a detailed representation of an industry's capital stock structure. A transparent dynamic computer modeling approach is chosen to integrate information from these analyses in ways that foster participation of stakeholders from industry and government agencies in all stages of the modeling process-from problem definition and determination of system boundaries to generation of scenarios and interpretation of results. Three case studies of industrial energy use in the USA are presented-one each for the iron and steel, pulp and paper, and ethylene industry. Dynamic models of these industries are described and then used to investigate alternative carbon emissions and investment-led policies. A comparison of results clearly points towards two key issues: the need for industry specific policy approaches in order to effectively influence industrial energy use, fuel mix and carbon emissions, and the need for longer time horizons than have typically been chosen for the analysis of industrial responses to climate change policies. 相似文献
195.
Henner?HollertEmail author Ingo?Haag Matthias?Dürr Bernhard?Wetterauer Roman?Holtey-Weber Ulrich?Kern Bernhard?Westrich Harald?F?rber Lothar?Erdinger Thomas?Braunbeck 《Environmental Sciences Europe》2003,15(1):5-12
Particle-bound pollutants accumulate in river-bottom sediments, a process which results in a significant decrease in the ecotoxicological availability of toxicants for the majority of aquatic organisms. Under normal hydrologic conditions, the release of contaminants from bottom sediments is usually of minor importance. In contrast, flood events may remobilize highly contaminated sediments via in-stream erosion. The objective of this study was to develop a combined ecotoxicological and hydraulic approach to elucidate the ecotoxicological implications associated with the risk of erosion of contaminated sediments. This integrated strategy was applied to the lock-regulated Neckar river in Southern Germany. Both the bottom-sediment cores and suspended matter from two intensive flood events were investigated. Sediment samples below an erosional unconformity showed a sharp increase in the ecotoxicological load. Moreover, it was found that major flood events (HQ5 and higher) could possibly erode even very old, well-consolidated and highlycontaminated sediments. The suspended matter of the high discharge events investigated (return periods of 15 to 20 years) exerted significantly higher cytotoxicity and mutagenicity than a moderate flood with a 1-year return period. These findings support the conclusion that the observed ecotoxicological effects during major floods may at least in part be due to the in-stream erosion of highly contaminated bottom sediments. 相似文献
196.
Matthias Koschorreck René Frömmichen Peter Herzsprung Jörg Tittel Katrin Wendt-Potthoff 《Water, Air, & Soil Pollution: Focus》2002,2(3):97-109
The addition of straw in combination with Carbokalk, a by-product from the sugar-industry, was successfully used to stimulate microbial alkalinity generation in an acidic mining lake. To get detailed information about functions of straw, anenclosure experiment was carried out. Straw bundles were placedat the sediment surface of an acidic mining lake (ML 111) and thephysiochemical conditions and the microbiology of the sediment-water contact zone were studied. Straw was degraded by anaerobic microorganisms and dissolved organic carbon (DOC) leached from straw bundles. Pigmented flagellates responded to the DOC supply in the water column anda considerable amount of algal carbon was transported to the sediment. Straw addition led to microbial reduction of iron andsulfate in the sediment. Sulfate reduction was observed at a pHof 5.5. The pH, however, was not high enough to precipitate H2S completely. Thus, some H2S diffused into the watercolumn, where it was reoxidized. Straw did not create orstabilize an anoxic water body above the sediment. Microbial sulfate reduction and pyrite formation only took place in the sediment,whereas iron reduction also took place in the straw. Straw, however, altered the flow conditions above the sediment surfaceand prevented complete mixing of the profundal water. Straw didnot serve as a substratum for a reactive biofilm. We conclude that the most important function of straw for mining lake remediation is to be a long-term nutrient source for microbialalkalinity generation in the sediment. 相似文献
197.
Assessment of Bacterial Degradation of Aromatic Hydrocarbons in the Environment by Analysis of Stable Carbon Isotope Fractionation 总被引:4,自引:0,他引:4
Rainer U. Meckenstock Barbara Morasch Matthias Kästner Andrea Vieth Hans Hermann Richnow 《Water, Air, & Soil Pollution: Focus》2002,2(3):141-152
13C/12C stable carbon isotope fractionation was used to assess biodegradation in contaminated aquifers with toluene as a model compound. Different strains of anaerobic bacteria (Thauera aromatica, Geobacter metallireducens, and the sulfate-reducing strain TRM1) showed consistent 13C/12C carbon isotope fractionation with fractionation factors between C = 1.0017 and 1.0018. In contrast, three cultures of aerobic organisms, using different mono- and dioxygenase enzyme systems to initiate toluene degradation, showed variable isotope fractionation factors of C = 1.0027 (Pseudomonasputida strain mt-2), C = 1.0011 (Ralstonia picketii), andC = 1.0004 (Pseudomonas putida strain F1). The great variability of isotope fractionation between different aerobic bacterial strains suggests that interpretation of isotope data in oxic habitats can only be qualitative. A soil column was run as a model system for contaminated aquifers with toluene as the carbon source and sulfate as the electron acceptor and samples were taken at different ports along the column. Microbial toluene degradation was calculated based on the 13C/12C isotope fractionation factors of the batch culture experiments together with the observed 13C/12C isotope shifts of the residual toluene fractions. The calculated percentage of biodegradation, B, correlated well with the decreasing toluene concentrations at the sampling ports and indicated the increasing extent of biodegradation along the column. The theoretical toluene concentrations as calculated based on the isotope values matched the measured concentrations at the different sampling ports indicating that the Rayleigh equation can be used to calculate biodegradation in quasi closed systems based on measured isotope shifts. A similar attempt was performed to assess toluene degradation in a contaminated, anoxic aquifer. A transect of groundwater wells was monitored along the main direction of the groundwater flow and revealed decreasing concentrations accompanied with an increase in the 13C/12C stable carbon isotope ratio of the residual toluene. Calculation of the extent of biodegradation based on the isotope values and laboratory derived isotope fractionation factors showed that the residual toluene was degraded to more than 99% by microbial activity. Calculation of the theoretical residual toluene concentrations based on the measured isotope values described the strongly decreasing concentrations along the plume. Other aromatic hydrocarbons like benzene and naphthalene which were analysed in the same course also showed decreasing concentrations along the groundwater flow path accompanied by increasing 13C values indicating biodegradation. 相似文献
198.
Pesticides in surface water,sediment, and rainfall of the northeastern Pantanal basin,Brazil 总被引:2,自引:0,他引:2
Laabs V Amelung W Pinto AA Wantzen M da Silva CJ Zech W 《Journal of environmental quality》2002,31(5):1636-1648
Within the last 25 years an intensive agriculture has developed in the highland regions of Mato Grosso state (Brazil), which involves frequent pesticide use in highly mechanized cash-crop cultures. To provide information on pesticide distribution and dynamics in the northeastern Pantanal basin (located in southern Mato Grosso), we monitored 29 pesticides and 3 metabolites in surface water, sediment, and rainwater of the study area during the main application season. In environmental samples, 19 pesticides and 3 metabolites were detected in measurable quantities, resulting in at least one pesticide detection in 68% of surface water samples (n = 139), 62% of sediment samples (n = 26), and 87% of rainwater samples (n = 91). Surface water samples were most frequently contaminated by endosulfan compounds (alpha-, beta-, -sulfate), ametryn, metolachlor, and metribuzin, although in low (< 0.1 microgram L-1) concentrations. Sediment samples exhibited concentrations up to 4.5 micrograms kg-1 of p,p'-DDT, p,p'-DDE, endosulfan-sulfate, beta-endosulfan, and ametryn. In contrast, rainwater was polluted with substantial amounts of endosulfan, alachlor, metolachlor, trifluralin, monocrotofos, and profenofos (maximum concentrations = 0.3 to 2.3 micrograms L-1) in the highlands. Lowland rainwater samples taken 75 km from the next application area contained 5- to 10-fold lower mean pesticide concentration than in the highlands. Cumulative deposition rates of the pesticide sum within the study period ranged from 423 micrograms m-2 in the highlands to 14 micrograms m-2 in the lowlands. The atmospheric input of pesticides to ecosystems seemed to be of higher relevance in the tropical study area than known from temperate regions. 相似文献
199.
Soils of the large sewage farm area south of Berlin are contaminated with heavy metals such as Cd, Cr, Cu, Hg, Ni, Pb, Zn. Based on earlier studies the total amount and the bioavailable proportions of heavy metals in soil samples were analysed. In some samples very high levels of total heavy metal concentrations were detected. For Pb, Cd, Cu and Hg the maximum values were 1360, 29.7, 817 and 40.8 mg/kg soil dry matter, respectively. The biovailable fractions of heavy metals which were found primarily in the acetate and EDTA fractions and to a lesser degree in the water extract account for about 50 % (Pb, Ni), 70 % (Cd) or 90% (Zn) of their total amount and may therefore pose a considerable environmental risk. 相似文献
200.
Concentrations of a wide range of trace elements: arsenic, cadmium, cobalt, chromium, hafnium, nickel, thorium, uranium, zinc and the rare earth elements, cerium, europium, samarium, terbium and ytterbium were determined by instrumental neutron activation analysis in the brown alga,Fucus vesiculosus from Eckwarder Hörne, North Sea and from Rügen, Baltic Sea. Another brown alga,Sargassum filipendula from Sri Lanka, Indian ocean (representing an unpolluted control station) was similarly investigated. Cobalt, chromium and nickel concentrations were highest inF. vesiculosus from the North Sea while zinc was highest in samples from the Baltic Sea, reflecting high levels of these elements in coastal waters of the North and the Baltic sea. Cadmium, cobalt, nickel and zinc levels were lowest inS. filipendula from Sri Lanka, probably demonstrating lower levels of those elements in coastal waters. Concentration levels of hafnium, thorium, uranium, and the rare earth elements were highest inS. filipendula. Two years later in 1994,S. filipendula along withUlva sp. (green alga) was resampled from the same sampling site, and in addition to the above elements, six other trace elements (Ag, Ba, Br, Rb, Se and Sr) were determined.Sargassium filipendula showed a particular affinity for Ag, As, Br and Sr. For the other elements, marginal concentration differences were observed betweenS. filipendula andUlva sp., probably reflecting the regional background levels. Substantially higher concentrations of Hf, Th, U, and the rare earths were found again in the 1994Sargassum andUlva samples, reflecting the effect of a substrate rich in rare earth elements. The brown algae used in this study may be used to monitor trace elements in coastal waters. 相似文献