Ecotoxicological risk assessment for sediments of Çavuşlu stream in Giresun,Turkey: association between garbage disposal facility and metallic accumulation

Environmental Science and Pollution Research - The objective of this paper was to stress the possible potential toxic element (PTE) accumulation in the surface sediments of the Çavu?lu...     

5-fluorouracil and curcumin with pectin coating as a treatment regimen for titanium dioxide with dimethylhydrazine-induced colon cancer model

Environmental Science and Pollution Research - Colorectal cancer was inducted in Wister rats using titanium dioxide nanoparticles (TiO2NPs) and dimethylhydrazine (DMH) and treatment using...     

Fabrication of ZnO–SnO2 nanocomposite and its photocatalytic activity for enhanced degradation of Biebrich scarlet

Environmental Science and Pollution Research - The n–n-type ZnO–SnO2 nanocomposite was fabricated using malic acid following a simple one-pot co-precipitation method. The fabricated...     

Soil erosion hazard evaluation—An integrated use of remote sensing,GIS and statistical approaches with biophysical parameters towards management strategies

Soil erosion hazard maps can be an essential tool in erosion prone areas as they explain and display the distribution of hazards and areas likely to be affected to different magnitudes. Therefore, it is very useful to planners and policy makers initiating remedial measures and for prioritizing areas. In this study, a numerical model was developed for soil erosion hazard assessment, in which Z-score analysis was combined with a geographical information system (GIS) to compute a synthetic soil erosion hazard index (SEHI). For this model, nine factors which have notable impact on soil erosion were selected. To generate the selected factors remote sensing, analytical hierarchy process (AHP) and GIS techniques along with spatial models were applied. To standardize all of the factors and establish the factor weights, the AHP method was adopted. For Z-score analysis with selected standardized factors, the Integrated Land and Water Information System (ILWIS) software was used and nine individual layers with Z-scores were prepared. Afterwards, the layers were integrated with their factor weights by means of a weighted linear combination to derive a SEHI value for each pixel. To classify the discrete SEHI map to represent a meaningful regionalization of soil erosion hazard, the equal distance cluster principle was used and graded into four levels of hazard; very high, high, moderate and low. The results depicted that in general, a moderate hazardous condition of soil erosion was found in the study area and the proposed approach was also able to identify the areas under high and very high hazards that require urgent intervention on a priority basis. Based on this study, comprehensive erosion hazard management strategies were anticipated for the efficient management of present and future erosion disaster in the area.     

Hybrid sensor for metal grade measurement of a falling stream of solid waste particles

A hybrid sensor system for accurate detection of the metal grade of a stream of falling solid waste particles is investigated and experimentally verified. The system holds an infrared and an electromagnetic unit around a central tube and counts all the particles and only the metal particles, respectively. The count ratio together with the measured average particle mass ratio (k) of non-metal and metal particles is sufficient for calculation of grade. The performance of the system is accurately verified using synthetic mixtures of sand and metal particles. Towards an application a case study is performed using municipal solid waste incineration bottom ash in size fractions 1-6mm, which presents a major challenge for nonferrous metal recovery. The particle count ratio was inherently accurate for particle feed rates up to 13 per second. The average value and spread of k for bottom ash was determined as 0.49 ± 0.07 and used to calculate grade within 2.4% from the manually analysed grade. At higher feed rates the sensors start missing particles which fall simultaneously through the central tube, but the hybrid system still counted highly repeatable. This allowed for implementation of a count correction ratio to eliminate the stationary error. In combination with averaging in measurement intervals for suppression of stochastic variations the hybrid system regained its accuracy for particle feed rates up to 143 per second. This performance and its special design, intended to render it insensitive to external interference and noise when applied in an eddy current separator, make the hybrid sensor suitable for applications such as quality control and sensor controlled separation.     

阶梯形鱼道中的滚动流研究

最近,小型倾斜河流中的阶梯形鱼道建筑以它的简易与实用而变得日益重要。在这种鱼道中出现的滚动流将产生波涌,并继续向下传播,而且它的周期性滚动可能会严重危害鱼道,因此,我们着手研究了它的严重性以便设计者在设计鱼道时能考虑这些因素。由实验证实滚动流源于阶梯形鱼道的上游。滚动流在稳定流与半平滑流间转变,它在一定时间间隔内不断地从稳定流变成半平滑流,又从半平滑流变成稳定流。它的流量值随着阶梯形水道的几何形状变形而呈现上下限。流量值和时间间隔均随着水池长度的增加而增加。     

Effect of Pretreatment with UV Radiation on Physical and Mechanical Properties of Photocured Jute Yarn with 1,6-Hexanediol Diacrylate (HDDA)

Jute yarns were grafted with a single impregnating monomer 1,6-hexanediol diacrylate (HDDA) in order to improve the physicomechanical properties. Jute yarns soaked for different soaking times (3, 5, 10, and 30 minutes) in HDDA+MeOH solutions at different proportions (1–10% HDDA in MeOH [v/v] along with photoinitiator Darocur-1664 [3%]) were cured under UV lamp at different UV radiation intensities (two, four, six, and eight passes). Concentration of monomer, soaking time, and intensity of UV radiation were optimized with extent of mechanical properties such as tensile strength, elongation at break, and modulus. Enhanced tensile strength (67%), modulus (108%), and polymer loading (11%) were achieved with 5% HDDA concentration, 5-minute soaking time, fourth pass of UV radiation. To further improve the mechanical properties, the jute yarns were pretreated with UV radiation (5, 10, 15, 30, and 50 passes) and treated with optimized monomer concentration (5%). UV-pretreated samples showed the enhanced properties. The tensile strength and modulus increase up to 84% and 132%, respectively, than that of virgin jute yarn. An experiment involving water absorption capacity shows that water uptake by treated samples was much lower than that of the untreated samples. During the weathering test, treated yarns exhibited less loss of mechanical properties than untreated yarns.     

Removal of thiobencarb in aqueous solution by zero valent iron

A cost-effective method with zero valent iron (ZVI) powder was developed for the purification of thiobencarb (TB)-contaminated water. The removal treatment was performed in the batch system. A sample solution of 10 ml containing 10 microg ml(-1) of TB could be almost completely treated by 100mg of ZVI at 25 degrees C for 12h of treatment time. Since the formation of chloride ion in the aqueous solution during the treatment of TB was observed, the removal of TB with ZVI may contain two processes: reduction (degradation) and adsorption. Because the present treatment for TB is simple, easy handling and cheap, the developed technology with ZVI can contribute to the treatment of agricultural wastewaters.     

Comparative evaluation of a bioluminescent bacterial assay in terrestrial ecotoxicity testing

Despite the widespread and successful use of luminescence-based bioassays in water testing, their applications to soils and sediments is less proven. In part this is because such bioassays have mainly been carried out in an aqueous-based medium and, as such, favour contaminants that are readily water-soluble. In this study, aqueous solutions and soils contaminated with heavy metals (HM), polar organic contaminants and hydrophobic organic contaminants (HOCs) were tested using a range of luminescence-based bioassays (Vibrio fischeri, Escherichia coli HB101 pUCD607 and Pseudomonas fluorescens 10586r pUCD607). For the first two chemical groups, the assays were highly reproducible when optimised extraction procedures were employed but for HOCs the bioassay response was poor. Quantitative structure-activity relationships (QSARs) obtained from aqueous solutions had a linear response although correlation for the chemicals tested using bacterial bioassays was significantly less sensitive than that of sublethal tests for Tetrahymena pyriformis. Bacterial and Dendrobaena veneta bioassay responses to extracts from HM amended soils showed that a clear relationship between trophic levels could be obtained. There is no doubt that the wide range of bioluminescent-based bioassays offers complementary applications to traditional testing techniques but there is a significant need to justify and optimise the extraction protocol prior to application.     

Spatial variability of arsenic concentration in soils and plants, and its relationship with iron, manganese and phosphorus

Spatial distribution of arsenic (As) concentrations of irrigation water, soil and plant (rice) in a shallow tube-well (STW) command area (8 ha), and their relationship with Fe, Mn and P were studied. Arsenic concentrations of water in the 110 m long irrigation channel clearly decreased with distance from the STW point, the range being 68-136 μg L⁻¹. Such decreasing trend was also noticed with Fe and P concentrations, but the trend for Mn concentrations was not remarkable. Concerning soil As, the concentration showed a decreasing tendency with distance from the pump. The NH₄-oxalate extractable As contributed 36% of total As and this amount of As was associated with poorly crystalline Fe-oxides. Furthermore only 22% of total As was phosphate extractable so that most of the As was tightly retained by soil constituents and was not readily exchangeable by phosphate. Soil As (both total and extractable As) was significantly and positively correlated with rice grain As (0.296 ± 0.063 μg g⁻¹, n = 56). Next to drinking water, rice could be a potential source of As exposure of the people living in the As affected areas of Bangladesh.