Potential of Calendula alata for phytoremediation of stable cesium and lead from solutions

Calendula alata plants were tested for their potential to remove stable cesium and lead from solutions in a 15-day period. The plants were grown hydroponically and placed in solutions containing CsCl and Pb(C?H?O?)? at different concentrations (0.6, 2 and 5 mg l?1). When plants were incubated in CsCl solutions 46.84 ± 2.12%, 41.35 ± 1.59%, and 52.06 ± 1.02% cesium was found to be remediated after 15 days. Moreover, more than 99% lead was removed from the Pb(C?H?O?)? solution in all three concentrations after 15 days during the same period. When both CsCl and Pb(C?H?O?)? were supplemented together in the solution, 9.92 ± 1.22%, 45.56 ± 3.52%, and 46.16 ± 1.48% cesium and 95.30 ± 0.72%, 96.64 ± 0.30%, and 99.02 ± 0.04% lead were removed after 15 days. The present study suggests that hydroponically grown C. alata could be used as a potential candidate plant for phytoremediation of cesium and lead from solutions; however, plants were found to be more efficient for the remediation of lead than cesium.     

Conceptual framework for evaluation of ecotourism carrying capacity for sustainable development of Karkheh protected area,Iran

The maintenance of natural and virgin ecosystems against an unnecessary influx of humans requires a modern and efficient model such as the carrying capacity model to optimize the management and development of ecotourism in these areas. The model is one of the key tools for conservation and sustainability of these areas. The present research attempts to formulate a framework for the ecotourism carrying capacity model for sustainable development of Karkheh protected area in Iran. The information was collected using a citation method as well as, interviews with experts, and visitors, and director of the region with 24 key indicators being regulated by field surveys and library studies. In this study, the network analysis process model, the Pressure-State-Response conceptual model, and Arc GIS_10.5 software were used to determine the potential for the establishment of ecotourism performance in the scale of 1: 50,000. In this research, 70 questionnaires were completed by experts in the field of environment and ecotourism to determine the relative importance of effective pressures. According to the results, the highest values belonged to physical carrying capacity (13,425,681 persons per day), ecological carrying capacity (2,482,226 persons per day), and social and culture (985,706 people per day), respectively. Based on the regional carrying capacity, the physical, ecological, and social carrying capacity index was calculated as 3356, 621, and 246 (greater than one), respectively. According to the results, the region has a high carrying capacity, which can accept visitors.     

Scenario-based urban growth allocation in a rapidly developing area: a modeling approach for sustainability analysis of an urban-coastal coupled system

Being located in an urban-coastal coupled system, the Hashtpar City is one of the most attractive areas for urban construction, tourism, agricultural activities and environmental protection in northern Iran. To resolve the issues between land developers and environmental conservation agencies, we conducted a scenario-based urban growth allocation procedure through the SLEUTH model. The scenarios consisted of ‘business as usual’, ‘managed urban growth’ and ‘environmentally sound growth’ that were introduced by modification of model parameters and exclusion layer. The resultant urban growth arrangements were compared for composition and configuration attributes of landscape patterns. According to the results, the pattern of urbanized lands under managed urban growth option demonstrated better connectivity and compactness of urban patches, while the two other scenarios generated a highly fragmented pattern. The managed urban growth can be considered as a compromised solution between other scenarios since it simultaneously takes into accounts both developers and environment protectors points’ of views. On this basis, a combination of centralized and decentralized urban land use planning is a recommended strategy for our urban-coastal environment to fulfill the purposes of a sustainable development process. The findings of the present article suggest that further expansion of the major urban core in the targeted area should be prohibited since it can lead to an urban patch with considerable physical size and noticeable ecological footprint.     

Toward a green economy: The nexus between economic and environmental factors in MENA countries,ARDL bounds approach

With the transition of the global economy toward a green economy, it is important to analyze the elements that can either support or impede this transformation. Therefore, in this study, we aimed to evaluate the potential of the green economy in the Middle East and North Africa (MENA) countries by analyzing the correlation between economic and environmental factors. The objective of this study is to explore the potential of the green economy in MENA countries by analyzing key factors such as access to clean fuel, GDP, and CO₂ emissions. The study aims to distinguish between long- and short-term effects, assess the presence of a long-run relationship or co-integration between the parameter estimates, and evaluate the progress of MENA countries toward a green economy based on the impact of economic, and environmental factors. Using quarterly and seasonally adjusted data from 2000 to 2018, the auto-regressive distributed lag (ARDL) technique was employed to examine the co-integration of the factors in the long and short terms. Multiple cointegration techniques were also used to determine the feasibility of a green economy by analyzing the relationship between access to clean fuel for technology and cooking, GDP, and CO₂ emissions. The study's findings indicate a clear long- and short-term relationship between the analyzed factors, as confirmed by the error correction model (ECM) which suggests that the variables are cointegrated and potentially relevant. Additionally, the result of the autoregressive distributed lag bound test shows that the green economy variables, GDP, CO₂ emissions, and access to clean fuel, are cointegrated in the long-term.     

Production of natural and recycled aggregates: the environmental impacts of energy consumption and CO<Subscript>2</Subscript> emissions

Natural aggregates (NA) are crushed and processed in crushing plants after the extraction stage in quarries. In the present study, the aggregates are divided into three scenarios, depending on the production methods. The first scenario considers the production of NA, the second scenario deals with the production of recycled aggregates (RA) with respect to construction and demolition waste, and the third scenario, which is a hybrid scenario, handles the combination of NA and RA by assuming a 50% mixing percentage. In this research, we assess the environmental impacts on the production of aggregates via each scenario, using life cycle assessment; in addition, energy consumption and CO₂ emissions are considered as the environmental variables. We conclude that Iran’s current policy with an annual energy consumption of 1.48 million tons of oil equivalent (toe) can have a footprint of 2.88 million tons of CO₂ eq emissions per year (the first scenario). Achieving 30 and 36% reduction in annual energy consumption and CO₂ emissions, respectively, by the third scenario compared to the first scenario indicates the destructive effect of the first scenario from the environmental outlook.     

Adsorption study of 14C-paraquat in two Malaysian agricultural soils

The adsorption equilibrium time and effects of pH and concentration of ¹⁴C-labeled paraquat (1,1^??-dimethyl-4,4^??-bipyridylium dichloride) in two types of Malaysian soil were investigated. The soils used in the study were clay loam and clay soils from rice fields. Equilibrium studies of paraquat in a soil and pesticide solution were conducted. Adsorption equilibrium time was achieved within 2 h for both soil types. The amount of ¹⁴C-labeled paraquat adsorbed onto glass surfaces increased with increasing shaking time and remained constant after 10 h. It was found that paraquat adsorbed by the two soils was very similar: 51.73 (clay loam) and 51.59 ?? g g^???1 (clay) at 1 ?? g/ml. The adsorption of paraquat onto both types of soil was higher at high pH, and adsorption decreased with decreasing pH. At pH 11, the amounts of ¹⁴C-labeled paraquat adsorbed onto the clay loam and clay soil samples were 4.08 and 4.05 ?? g g^???1, respectively, whereas at pH 2, the amounts adsorbed were 3.72 and 3.57 ?? g g^???1, respectively. Results also suggested that paraquat sorption by soil is concentration dependent.     

Development of Cellulose Aerogel as a New Material for the Reduction of Harmful Substances in Cigarette Smoke

The current study proposes a novel and improved cigarette filtration design comprising cellulose nanofibers (CNFs) and powdered activated carbons (PACs) with different dry matter contents. The proposed filter samples were primarily analyzed to verify their applicability as cigarette filters via measurements and standard tests, such as SEM, BET, DSC, and airflow permeability analysis. The results were compared with the cellulose acetate (CA) sample used as a conventional cigarette filter. The preliminary results indicated noticeable improvement compared to the reference CA. Also, the cigarettes were tested using a smoking machine, and the filtered smoke was analyzed using GC–MS to evaluate the filters' performance in reducing the harmful substances present in the smoke. The results showed that the filters made of CNF and PAC significantly decreased the toxic substances compared with the reference but did not affect the nicotine substantially and therefore will not negatively impact the trance level of smokers.

     

Introduction of Ionic Liquids as Highly Efficient Plasticizers and Flame Retardants of Cellulose Triacetate Films

Journal of Polymers and the Environment - As a promising biodegradable polymer, cellulose triacetate (CTA) was synthesized and plasticized with ionic liquids to produce flexible biocomposite films...