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271.
272.
Mehmet Coelhan Gerda Fingerling Gabriele Christ Harun Parlar 《Environmental Sciences Europe》1998,10(2):109-122
Residue analysis of toxaphene has been difficult because of the complexity of the technical mixture consisting of a high number of compounds with very similar structure and differing chlorine content. Furthermore, the composition of toxaphene in environmental samples varies widely and is normally not related to that of the technical mixture. Therefore, quantification of single components in environmental samples was impossible. After the isolation and identification of a great number of components during the last decade, enough standards are available for the reliable quantification of toxaphene in all environmental compartments. Recently, most research has been performed on the separation of chiral components of toxaphene with a view to identifying the degradation mechanisms and distribution pathways. 相似文献
273.
Pesticide risk assessment and management in a globally changing world—report from a European interdisciplinary workshop 总被引:1,自引:1,他引:0
Marc Babut Gertie H. Arts Anna Barra Caracciolo Nadia Carluer Nicolas Domange Nikolai Friberg Véronique Gouy Merete Grung Laurent Lagadic Fabrice Martin-Laurent Nicolas Mazzella Stéphane Pesce Benoit Real Stefan Reichenberger Erwin W. M. Roex Kees Romijn Manfred Röttele Marianne Stenrød Julien Tournebize Françoise Vernier Eric Vindimian 《Environmental science and pollution research international》2013,20(11):8298-8312
274.
Céline Dupont Francesca Romana Grati Kwong Wai Choy Sylvie Jaillard Jérôme Toutain Marie-Laure Maurin Jose Antonio Martínez-Conejero Claire Beneteau Aurélie Coussement Denise Molina-Gomes Nina Horelli-Kuitunen Azzedine Aboura Anne-Claude Tabet Justine Besseau-Ayasse Bettina Bessieres-Grattagliano Giuseppe Simoni Gustavo Ayala Brigitte Benzacken François Vialard 《黑龙江环境通报》2015,35(1):35-43
275.
276.
Yener H Koç A 《Journal of environmental biology / Academy of Environmental Biology, India》2006,27(1):77-83
This study introduces the monitoring system to be established within this project, it aims to determine changes occurring within forested areas, settlement areas and other land use forms located at the peripheral area of Istanbul during consecutive decades. The first phase of the study was completed in 1998 and published, covering the period from 1984 to 1994. This study is the second phase of the first one and implemented to determine land use changes which have occurred on the same site from 1994 to 2000. Standard topographic maps with 1/25 000 scale, forest management maps with the same scale, results of the previous study, orthophoto maps of the year 2000 that were produced from aerial color photographs of the site with 1/5 000 scale, and 4-band IRS_LISS III multispectral satellite data for July 2000 were used as data. The changes in land use within the study area occurring during a six year period were studied. 相似文献
277.
Accumulation of weathered polycyclic aromatic hydrocarbons (PAHs) by plant and earthworm species 总被引:12,自引:0,他引:12
Parrish ZD White JC Isleyen M Gent MP Iannucci-Berger W Eitzer BD Kelsey JW Mattina MI 《Chemosphere》2006,64(4):609-618
Experiments were conducted to assess the bioavailability of polyclycic aromatic hydrocarbons (PAHs) in soil from a Manufactured Gas Plant site. Three plant species were cultivated for four consecutive growing cycles (28 days each) in soil contaminated with 36.3 microg/g total PAH. During the first growth period, Cucurbita pepo ssp. pepo (zucchini) tissues contained significantly greater quantities of PAHs than did Cucumis sativus (cucumber) and Cucurbita pepo ssp. ovifera (squash). During the first growth cycle, zucchini plants accumulated up to 5.47 times more total PAH than did the other plants, including up to three orders of magnitude greater levels of the six ring PAHs. Over growth cycles 2-4, PAH accumulation by zucchini decreased by 85%, whereas the uptake of the contaminants by cucumber and squash remained relatively constant. Over all four growth cycles, the removal of PAHs by zucchini was still twice that of the other species. Two earthworm species accumulated significantly different amounts of PAH from the soil; Eisenia foetida and Lumbricus terrestris contained 0.204 and 0.084 microg/g total PAH, respectively, but neither species accumulated measurable quantities 5 or 6 ring PAHs. Lastly, in abiotic desorption experiments with an aqueous phase of synthetically prepared organic acid solutions, the release of 3 and 4 ring PAHs from soil was unaffected by the treatments but the desorption of 5-6 ring constituents was increased by up to two orders of magnitude. The data show that not only is the accumulation of weathered PAHs species-specific but also that the bioavailability of individual PAH constituents is highly variable. 相似文献
278.
In the context of the high application potentials for on-line measurements in wastewater quality monitoring, UV spectroscopy has received recent attention. In the present work UV spectrophotometric analyses were coupled to principal component analysis (PCA) and cluster analysis (CA) to characterize samples taken from a fuel park wastewater treatment plant and to attempt preliminary contaminant identification in the treated wastewater. The score plot resulting from PCA identified two different groups of spectra, one including the influents to the biological reactor and the other the treated wastewater samples. Among the latter, weekday and weekend samples could be further distinguished. The same groups of samples were identified in a dendrogram from CA. The score plot and the dendrogram also allowed the tentative identification of employed process chemicals (lubricant and detergents) as residual contaminants in the treated effluent. 相似文献
279.
Bioaccumulation of Hg, Cu, and Zn in the Azores triple junction hydrothermal vent fields food web 总被引:2,自引:0,他引:2
In this work, mercury (Hg), copper (Cu) and zinc (Zn) concentrations and tissue distribution are determined in seven benthic invertebrates species (the key species) from the Mid Atlantic Ridge (MAR) hydrothermal vent fields. The samples were collected from three hydrothermal vent fields – Menez Gwen, 840 m; Lucky Strike, 1700 m and Rainbow, 2300 m – near the Azores Triple Junction. These fields are characterized by different depths, geological context and chemical composition of the hydrothermal fluid, particularly the metal content, which is reflected by the metal concentrations in the organisms. Indeed, our results show that organisms from Menez Gwen presented the highest Hg concentrations, while those from Lucky Strike and Rainbow were richer in Cu and Zn. The potential transfer of these metals through two trophic links are also evaluated and include (1) the mussel Bathymodiolus azoricus and the commensal worm Branchipolynoe seepensis, and (2) three different species of shrimps and the crab Segonzacia mesatlantica. No evidence of Hg biomagnification in either of the vent food chains is clearly observed but an increase in Hg accumulation from prey to predator in the crustacean food chain. The same pattern was observed for Cu and Zn, even though these metals are not known to be generally biomagnified in food chains. 相似文献
280.
Toxicity of copper excess on the lichen Dermatocarpon luridum: antioxidant enzyme activities 总被引:2,自引:0,他引:2
The aim of this study was to investigate the toxicity of copper on the aquatic lichen Dermatocarpon luridum focusing on the activities of some antioxidant enzymes. Investigations were conducted using increasing copper concentrations (0.00, 0.25, 0.50, 0.75 and 1.00 mM CuSO(4) x 5H(2)O) in synthetic freshwater that emulated the major ion compositions of its natural water biota; time course measurement was 0, 3, 6, 12, 24 and 48 h. The copper concentration in thalli increased with its increase in the medium and the duration of treatment. Copper induced lipid peroxidation, measured using the hydroperoxi-conjugated dienes (HPCD) concentration. The decrease in the protein concentrations was similar in thalli exposed to copper concentrations above 0.50 mM and the decrease was twice lower in thalli exposed to 0.25 mM copper. The activities of antioxidant enzymes measured were differently affected by copper excess. For 0.25 mM copper, the activities of SOD (superoxide dismutase) and APX (ascorbate peroxidase) were unchanged when compared with unstressed thalli whereas the CAT (catalase) activity increased and the GR (glutathione reductase) activity decreased. The activities of SOD and APX increased in thalli exposed to concentrations above 0.50mM copper. The CAT activity increased after the first 3h of experiments at these concentrations and then decreased with the duration of treatment at an activity lower than in the unstressed plant. Whereas the APX activity increased, the GR activity similarly decreased for the copper concentration tested whatever the duration of the experiment. 相似文献