炼焦过程排放挥发性有机物的排放特征和组成分布研究

为控制炼焦排放以及为预防城市大气污染提供可靠的污染源数据支持,利用不锈钢采样罐和全自动预浓缩/GC/MS系统,研究了58-Ⅱ型和JN43-80型焦炉在装煤时刻和炼焦过程(包括装煤时刻)中挥发有机物(VOCs)的排放特征及其组成分布,分析了焦化行业排放VOCs的反应活性。研究发现,在装煤时刻和炼焦过程中,58-Ⅱ型焦炉产生的总挥发性有机物(TVOCs)浓度分别为7022μg/m~3和6266μg/m~3;JN43-80型焦炉产生的TVOCs浓度分别为4185μg/m~3和3298μg/m~3。装煤时刻产生的TVOCs浓度明显高于炼焦过程产生的。炼焦过程无组织排放的VOCs包含烯烃、烷烃、芳香烃、卤代烃以及少量的醛和酮,其中乙烯、乙烷、丙烯、苯、甲苯等为主要成分。这些产生的VOCs反应活性各不相同,活性最大的是烯烃类物质,其活性占TVOCs反应活性比重为(86.2±2.1)%;其次是芳香烃类物质,其活性比重为(9.2±3.1)%;反应活性最大的5个物种分别是丙烯、乙烯、1,3-丁二烯、1-丁烯以及苯乙烯。     

Occurrence and distribution of organochlorine pesticides - lindane, p,p'-DDT, and heptachlor epoxide - in surface water of China

Persistent organochlorine pesticides pollutants (OCPs) have been reported to occur at relatively high concentrations in some Chinese waters. In order to map the distribution of organochlorine pesticides in the surface water throughout China, samples were collected from over 600 sites in seven major river basins and three main internal rivers drainage areas during 2003 and 2004. The surface water samples were analyzed for the representative organochlorine pesticides contaminants including lindane (gamma-HCH), p,p'-DDT and heptachlor epoxide. In general, the most frequently detected compound was lindane, being detected in 83.9% of samples (mean=31.3 ng/l; range <0.17-860 ng/l), and the highest concentration was present in the Yellow River basin. p,p'-DDT was detected in 63.1% of the samples collected (mean=14.6 ng/l; range <0.14-368 ng/l) with the highest concentration present in the Huaihe River basin. Heptachlor epoxide was detected in only 9.3% of water samples (range <0.11-10 ng/l). Measured concentrations for the three compounds were low and rarely exceed the environment quality standard for surface water of China. Lindane was more frequently detected at much higher concentrations in the rivers of northern China compared with those of southern China. The sites with higher concentration of lindane and p,p'-DDT mainly occurred in the Yellow River and Huaihe River basins, so the results of this investigation indicate that the organochlorine pesticide contamination of Yellow River and Huaihe River basins should be of particular concern relative to the other basins. When compared with other regions of the world, it appears that the Chinese surface water is moderately polluted by lindane and p,p'-DDT.     

Opportunities and challenges for development of urbanization in Western China

Urban and rural dual structure in Western China is obvious.The economic development of the central cities is relatively quick while that of the rural areas is lagging behind.The speeding up of urbanization contributes to the intensively uncoordinated development of urban and rural areas.Besides,the eco-fragile environment,shortage of available water resources,adverse geographic location,and relatively backward social economy restrict the development of urbanization in Western China.However,Western China also has the advantages of backwardness.This paper analyzes the present situation and development trend of urbanization in Western China.The results show that Western China has basically formed a development pattern with"industry promotes agriculture and urban leads to village".Therefore,combined with the present situation of Western China,this paper describes and analyzes the opportunities and challenges that may appear in the process of urbanization in Western China,puts forward the development pattern in which urban and rural areas can gain mutual support and co-development,and provides related recommendations.     

A Methodology Framework for Regional Land-use Change Studies based on Landsat TM images: A Case Study in Northeast China

Abstract

Land-use change is an important aspect of global environment change. It is, in a sense, the direct result of human activities influencing our physical environment. This paper analyzed the land- use change in Northeast China during 1985–2000 based on Landsat TM images. It divides Northeast China into five land-use zones based on the dynamic degree model of land-use: woodland/grassland-arable land conversion zone, dry land-paddy field conversion zone; urban expansion zone, interlocked zone of farming and pasturing and reclamation and abandon zone. The findings include the obvious increase of cropland area, paddy field and dry land increased by 75 and 276 thousand hm² respectively; urban areas expanded rapidly, areas of town and rural residence increased by 76.8 thousand hm²; areas of forests and grassland decreased sharply with the amounts of 1399 and 1521 thousand hm² respectively; areas of water body and unused land increased by 148 and 514 thousand hm² respectively. This paper also discusses the driving forces in each land-use dynamic zone and finds that some key biophysical factors affect conspicuously the conversion of different land-use types. The relation between land-use conversion and DEM, accumulated temperature (≤10°C) and precipitation was analyzed and represented. The land-use changes In Northeast China resulted from the changing macro social and economic factors and local physical elements. Rapid population growth and management changes can explain the shaping of woodland/grassland-cropland conversion zone. The conversion from dry land to paddy field in the dry land-paddy field conversion zone, apart from the change of physical elements promoting the expansion of paddy field, results from two reasons: one is that the implementation of market economy in China has given farmers the right to decide what and how they plant their crops, the other factor is originated partially from the change of the dietary habit along with the social and economic development. The conversion from paddy field to dry land is caused primarily by the shortfall of irrigation water, which in turn is caused by poor water allocation managed by local governments. The shaping of the reclamation and abandon zone is partially due to the lack of environment protection consciousness among pioneer settlers. The reason for the conversion from grassland to cropland is the relatively higher profits of farming than that of pasturing in the interlocked zone of farming and pasturing. In Northeast China, the rapid expansion of built-up areas results from two factors: the existence of a small number of towns and the huge potential for expansion of the existing towns and cities. The urban land expanded mainly in areas with a gentle topographic relief and low population density.     

中国西部城镇化可持续发展路径的探讨

基于对中国西部地区城镇化进程的调研,本文探讨了西部地区城镇化可持续发展的路径,结合西部地区的现状与西部地区城镇发展的历史趋势,分析了中国西部地区城镇化发展的需求,阐析了其城镇化进程中的环境压力与阻力,提出了促进中国西部城镇化可持续发展的政策建议.目前,西部地区整体城镇化水平滞后,各省(区)间的城镇化发展水平极不均衡.而社会经济发展水平对于城镇化具有很大的促进作用,故未来相当一段时间内,西部地区社会经济发展是其区域城镇化进程的主要动力,同时西部地区尚处于城镇化与工业化发展的正相关期,工业化水平的提升对西部地区城镇化进程的推动作用不容小觑.城镇化进程的不断加快和工业化的快速推进过程中,西部地区本就脆弱的生态环境存在进一步遭受损失与破坏的威胁.这些将会导致西部地区生态环境状况的恶化转而成为其城市化的严重制约,给当地经济可持续发展造成一定程度的影响.据此,文中提出建议,未来西部城镇化建设过程中,应推行“二元”城镇化发展战略,增强中心城镇的辐射带动作用,培育中小城市和特色鲜明的小城镇;进一步完善西部城镇基础设施水平,以各级政府支持管理为先导和主导,尝试采用“公私营合作”(PPP)融资模式,重点推进交通及通讯设施建设;构建长期稳定的绿色城镇发展战略,推进城市绿色文化、建设绿色城市,筹措西部地区绿色城镇发展基金、发展城市绿色产业;立足功能分区并结合城镇化战略格局优化城镇化发展,依托国家主体功能区划优化城镇化发展格局,结合“两横三纵”城镇化战略格局推进城市群建设.     

Spatial-temporal analysis of wetland landscape pattern under the influence of artificial dykes in the Yellow River delta

The influence of anthropogenic activities,especially artificial dykes,on the coastal wetland landscape is now considered as a serious problem to the coastal ecosystem.It is important and necessary to analyze changes of coastal landscape pattern under the influence of artificial dykes for the protection and management of coastal wetland.Our study aimed to reveal the quantitative characteristics of the coastal wetland landscape and its spatial-temporal dynamics under the influence of artificial dykes in the Yellow River delta(YRD).It was analyzed by the methods of the statistical analysis of landscape structure,five selected landscape indices and the changes of spatial centroids of three typical wetland types,including reed marshes,tidal fiats and aquaculture-salt fields.The results showed that:(1)Reduction of wetland area,especially the degradation of natural wetlands,had been the principal problem since the dykes were constructed in the YRD.The dykes created conditions for the development of artificial wetlands.However,the new born artificial wetlands were still less than the vanished natural wetlands.(2)Compared with the open area,the building of artificial dykes significantly speeded up the changes of landscape patterns and the aggravation of the landscape fragmentation in the closed area.(3)The changes of area-weighted centroids of three typical wetland landscapes were greatly affected by dykes,and the movement of the centroid of the aquaculture-salt field was very sensitive to the dykes constructed in the corresponding period.     

Developing Mechanism of Rubber-tea-chicken Agro-forestry Model in Tropical Area of China

Abstract

As a typical tropical agro-forestry ecosystem in Wenchang, Hainan Province, China, rational mechanisms of the rubber-tea-chicken eco-agricultural model were studied with the Solow technological level index, stability indicator, harmonizing coefficient, grey correlation coefficient and production dominance. This study focused on rational hierarchical structure, the limiting factors and optimal strategies of the model development based on model structure, resource conditions and external market demands. Results showed that rational mechanism of the rubber-tea-chicken ecosystem model mainly included technological contributions, leverage function of dominance component (livestock husbandry), stability of the model structure and harmony of its components, the model dominant product’s market demand and government’s supporting policies. The contributions of fund, technology, information and talent resources played an important role in improving sustainability and productivity of the agro-forestry model.     

Biofuel development, food security and the use of marginal land in China

With concerns of energy shortages, China, like the United States, European Union, and other countries, is promoting the development of biofuels. However, China also faces high future demand for food and feed, and so its bioenergy program must try to strike a balance between food and fuel. The goals of this paper are to provide an overview of China's current bioethanol program, identify the potential for using marginal lands for feedstock production, and measure the likely impacts of China's bioethanol development on the nation's future food self-sufficiency. Our results indicate that the potential to use marginal land for bioethanol feedstock production is limited. Applying a modeling approach based on highly disaggregated data by region, our analysis shows that the target of 10 million t of bioethanol by 2020 seems to be a prudent target, causing no major disturbances in China's food security. But the expansion of bioethanol may increase environmental pressures due to the higher levels of fertilizer use. This study shows also that if China were able to cultivate 45% of its required bioethanol feedstock on new marginal land, it would further limit negative effects of the bioethanol program on the domestic and international economy, but at the expense of having to apply another 750 thousand t of fertilizer.     

Solubilization of mixed polycyclic aromatic hydrocarbons through a rhamnolipid biosurfactant

The solubilization of phenanthrene (PHE) and pyrene (PYR) by rhamnolipid biosurfactant was systematically investigated. The solubilities of both polycyclic aromatic hydrocarbons (PAHs) were increased linearly with the biosurfactant concentration at above critical micelle concentration. A competitive effect was observed between PHE and PYR. The solubility of PHE in a mixed system was lower than that in a single PAH system, whereas the solubility of PYR in a mixed system was enhanced. This is because the hydrophobicity of PYR is higher than that of PHE, so PYR is favored in the competitive solubilization. The combined effect of biosurfactant and dissolved organic matter (DOM) on PAH solubilization was also examined. Two kinds of DOM (derived from soil and from compost) were used. There was an obvious enhancement of solubility for PHE and PYR in systems with concurrence of DOM and biosurfacrant compared with systems with only DOM or biosurfactant; however, the enhancement in the mixed system was less than their additive. This could be explained as the formation of a DOM-biosurfactant complex. In addition, the solubility enhancement of PAHs in a compost-DOM system was higher than that in a soil-DOM system. This could be explained as functional group differences of two DOM types.     

Modeling the Impacts of Cetacean-Focused Tourism in Taiwan: Observations from Cetacean Watching Boats: 2002–2005

Cetacean-focused tourism in Taiwan has grown rapidly since 1997. This development, measured in terms of both number of tour boats and visitors, has resulted in many resource management challenges stemming from the absence of regulation and scientific data. To fill this void in empirical evidence, we used 464 sighting records from 2002 to 2005 to model the impact of cetacean-focused tourism. Cox proportional hazard analysis indicated cetacean avoidance responses to cetacean watching boats were strongly associated with pod size, mother–calf pairs, and cetacean-vessel distances. Mother–calf pairs abandoned their avoidance tactic by 55% compared to noncalf groups when tour boats approached. Second, the hazard ratio of abundance was 0.996, suggesting that the odds of encountering avoidance responses by the cetaceans decreased by 42% for every 100-member increase in the cetacean pod size. Last, distances maintained by boats from the cetaceans was positively related to avoidance responses (i.e., less avoidance behavior with closer interaction). Based on our findings, we have the following recommendations: (a) limit vessels from approaching mothers with calves, (b) limit vessels from approaching small groups of cetaceans, (c) reduced avoidance behavior to boat traffic may be a red flag for potential long-term disturbance, and (d) apply the “precautionary principle” based on the best scientific information available in cetacean-based tourism in Taiwan. These recommendations will help contribute to the sustainable development of cetacean-focused tourism in Taiwan.