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Matys Grygar Tomáš Faměra Martin Hošek Michal Elznicová Jitka Rohovec Jan Matoušková Šárka Navrátil Tomáš 《Environmental science and pollution research international》2021,28(37):51183-51198
Environmental Science and Pollution Research - Willows, woody plants of genus Salix common in floodplains of temperate regions, act as plant pumps and translocate the Cd and Zn in the soil profiles... 相似文献
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Sodium azide (NaN(3)) is one of the biocides commonly used to inhibit microbial growth during sorption experiments. However, a few reports have suggested that NaN(3) can react with the analyte of interest. In this study, the interactions of NaN(3) with triazine herbicides were investigated and the effect of atrazine transformation on its sorption to soil was evaluated. The concentration of atrazine in the presence of NaN(3) decreased significantly over period of time. After 14 days, only 38% of the initial atrazine concentration (10 mg l(-1)) was detected in a solution containing 1,000 mg l(-1) NaN(3) at pH 5.5. The magnitude and the rate of atrazine transformation increased with increase in NaN(3) load and with decrease in pH. In contrast to atrazine behavior, the concentrations of prometon and ametryn did not change during the experiment. GC/MS analysis indicated that the chlorine atom of atrazine is replaced by the azide group yielding 2-azido-4-(ethylamino)-6-(isopropylamino)-s-triazine. Atrazine transformation by NaN(3) significantly affected sorption of herbicide to soil. The presence of NaN(3) affects indirectly the sorption of atrazine due to competitive effect of its derivative. Our results demonstrated that the application of NaN(3) as a biocide in sorption-desorption experiments must be carefully evaluated. This issue is vital for sorption experiments conducted over long periods of time or/and with concentration of NaN(3) higher than 100 mg l(-1). 相似文献
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The present study focuses on the effects of vegetation cover changes on the dynamic morphology of seven southeastern Mediterranean river mouths. The methodology used comprised monitoring and mapping by GIS techniques, with data derived from historic aerial photographs, which were applied in the investigation of the morphological spatial and temporal migration patterns of the mouths, and subsequent analysis of the vegetation cover changes influencing them. Vegetation cover adjacent to river mouths influences river mouth morphology through five primary mechanisms: a) bank vegetation; b) dune advancement toward the shoreline; c) changes in the beach??s micro-topography; as well as d) long-term continuous channel migration through permanent vegetation patches; and e) channel switching through permanent vegetation patches. The five mechanisms are part of a system of interactions between channel water flow and fluvial processes; coastal sediment transport and coastal processes; and the evolution of plant communities. In the interplay between these factors they all affect and are being affected by one another. In many river mouths artificial channel diversion is often needed due to uncontrolled channel migration. It is demonstrated that vegetation cover can serve as a mean of ??soft?? channel regulation. Therefore, a better understanding of the five influencing mechanisms may aid in controlling and managing river mouth migration patterns. The study contributes to the knowledge about bank vegetation as a tool of ??soft?? channel regulation and thus can contribute to the improvement of coastal zone management. 相似文献