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351.
352.
Yi Zhang Lin Wu Chao Zou Boyu Jing Xiaoyu Li Tim Barlow Turpin Kevin Michel André Yao Liu Peipei Ren Gongdong Wang Hongjun Mao 《Environmental Modeling and Assessment》2017,22(5):445-458
This paper reports on the development and application of an urban high temporal-spatial resolution vehicle emission inventory model and decision support system based on the current situation in China and actual vehicle emission control requirements. The system incorporates a user-friendly modular architecture that integrates a vehicle emission model and a decision support platform and includes scenario analysis and visualisation capabilities. A bottom-up approach based on localised emission factors and actual on-road driving condition has been adopted to develop the system. As a case study of application and evaluation, an emission reduction effect analysis of the supposed low-emission zone (LEZ) policy in Beijing (2012) was conducted. According to the simulated results in the forms of tables, histograms and grid maps, the establishment of this LEZ had a definite effect on the emission reduction of various types of air pollutants, especially carbon monoxide and hydrocarbon. In the system, the simulation methodology for identifying environmental benefits brought by the LEZ policy could be used to assess other similar environmental policies. Through flexible modification of configuration values or input data variables, the efficacy of separate or joint policies could be quantifiably evaluated and graphically displayed. 相似文献
353.
Cocheo C Sacco P Ballesta PP Donato E Garcia S Gerboles M Gombert D McManus B Patier RF Roth C de Saeger E Wright E 《Journal of environmental monitoring : JEM》2008,10(8):941-950
The need to collect data representative of overall urban pollution is all-important in order to monitor the population exposure. High spatial resolution monitoring using diffusive samplers allows studying of the urban pollutant distribution, thus enabling deeper investigation of their generation and diffusion mechanisms. Nevertheless, such a monitoring campaign has a certain cost. In this study we point out how to find the best compromise between the number of necessary measurements and the affordable costs for monitoring campaigns. We also describe an innovative method for the proper design of a fixed urban monitoring network by means of preliminary high spatial resolution campaigns using diffusive samplers. Four European capital cities (Dublin, Madrid, Paris and Rome) were monitored six times, each time for seven days. Benzene, toluene, ethylbenzene, xylenes (BTEX) and NO(2) concentrations were measured at 146 sites in Dublin, 293 in Madrid, 339 in Paris and 290 in Rome. Multiscale grids have been drawn which ranged in mesh size from 500 m to 2 km. The statistical processing of data produced a twofold result: the creation of isoconcentration maps with geostatistical procedures, and an algorithm aimed at locating the minimum number of sampling sites where the fixed monitoring stations should be placed. Average urban levels estimated on the basis of these selected sites differ by less than 8% from those calculated on the whole populations of the sampled points. The aim of this work is to investigate how far the resolution of a monitoring campaign of urban pollution by diffusive sampling can be reduced, thus making the monitoring less expensive in terms of human and financial resources, while preserving the same quality of the results that could be achieved with a higher resolution. We found that there is no significant loss of information when the resolution of the monitoring grid for BTEX is lowered to a mesh size of 1.85 km, that is a sampling site each 3.4 km(2), and that the minimum number of sampling sites to be used is N = 0.29 A, where A is the urban surface to be monitored (in km(2)). As the spatial distribution of NO(2) is less sensitive to the distance from the emission source than that of BTEX, this relationship could be retained as a valid lower limit for the mesh grid size also for NO(2) monitoring. 相似文献
354.
Leila?Moura Tarek?Moufawad Michel?Ferreira Hervé?Bricout Sébastien?Tilloy Eric?Monflier Margarida?F.?Costa Gomes David?Landy Sophie?FourmentinEmail authorView authors OrcID profile 《Environmental Chemistry Letters》2017,15(4):747-753
Volatile organic compounds are a major source of air pollutants. Absorption is an effective solution to treat polluted air loaded with volatile organic compounds, but most actual absorbents are often toxic and non-biodegradable. Here, we tested eutectic solvent mixtures for the absorption of volatile organic compounds for the first time. The affinity of solvent mixtures for toluene, acetaldehyde and dichloromethane was determined by measuring vapour–liquid partition coefficients and liquid phase absorption capacities. Results show that the vapour–liquid partition coefficients vary, at 30 °C, from close to zero for acetaldehyde in the mixtures choline chloride:urea, choline chloride:glycerol and tetrabutylphosphonium bromide:glycerol to 0.124 for dichloromethane in the choline chloride:urea eutectic mixture. These values are similar or even superior to those published for ionic liquids and organic solvents. Solvents based on choline chloride, a food additive, and urea, can solubilize up to 500 times more volatile organic compounds compare to water. Moreover, deep eutectic solvents are easier to prepare and more biodegradable than ionic liquids, which are also toxic. Deep eutectic solvents are more biodegradable than silicone oils, which are also expensive. Furthermore, in terms of recycling, the absorption capacities of the tested solvents remained unchanged during five absorption–desorption cycles. These findings are patented. 相似文献
355.
Between 1850 and 1970, rivers throughout Sweden were channelized to facilitate timber floating. Floatway structures were installed
to streamline banks and disconnect flow to secondary channels, resulting in simplified channel morphologies and more homogenous
flow regimes. In recent years, local authorities have begun to restore channelized rivers. In this study, we examined the
effects of restoration on riparian plant communities at previously disconnected secondary channels of the Pite River. We detected
no increase in riparian diversity at restored sites relative to unrestored (i.e., disconnected) sites, but we did observe
significant differences in species composition of both vascular plant and bryophyte communities. Disconnected sites featured
greater zonation, with mesic-hydric floodplain species represented in plots closest to the stream and mesic-xeric upland species
represented in plots farthest from the stream. In contrast, restored sites were most strongly represented by upland species
at all distances relative to the stream. These patterns likely result from the increased water levels in reconnected channels
where, prior to restoration, upland plants had expanded toward the stream. Nonetheless, the restored fluvial regime has not
brought about the development of characteristic flood-adapted plant communities, probably due to the short time interval (ca.
5 years) since restoration. Previous studies have demonstrated relatively quick responses to similar restoration in single-channel
tributaries, but secondary channels may respond differently due to the more buffered hydrologic regimes typically seen in
anabranching systems. These findings illustrate how restoration outcomes can vary according to hydrologic, climatic and ecological
factors, reinforcing the need for site-specific restoration strategies. 相似文献
356.
Kris Verheyen Margot Vanhellemont Harald Auge Lander Baeten Christopher Baraloto Nadia Barsoum Simon Bilodeau-Gauthier Helge Bruelheide Bastien Castagneyrol Douglas Godbold Josephine Haase Andy Hector Hervé Jactel Julia Koricheva Michel Loreau Simone Mereu Christian Messier Bart Muys Philippe Nolet Alain Paquette John Parker Mike Perring Quentin Ponette Catherine Potvin Peter Reich Andy Smith Martin Weih Michael Scherer-Lorenzen 《Ambio》2016,45(1):29-41
357.
358.
Matthieu Dussauze Lionel Camus Stéphane Le Floch Karine Pichavant-Rafini Perrine Geraudie Nathalie Coquillé Aline Amérand Philippe Lemaire Michael Theron 《Environmental science and pollution research international》2014,21(24):13779-13788
In this study, impact of dispersed oil on cardiac mitochondrial function was assessed in a key species of Arctic marine ecosystem, the polar cod Boreogadus saida. Mature polar cod were exposed during 48 h to dispersed oil (mechanically and chemically) and dispersants alone. The increase observed in ethoxyresorufin-O-deethylase activity and polycyclic aromatic hydrocarbon metabolites in bile indicated no difference in contamination level between fish exposed to chemical or mechanical dispersion of oil. Oil induced alterations of O2 consumption of permeabilised cardiac fibres showing inhibitions of complexes I and IV of the respiratory chain. Oil did not induce any modification of mitochondrial proton leak. Dispersants did not induce alteration of mitochondrial activity and did not increase oil toxicity. These data suggest that oil exposure may limit the fitness of polar cod and consequently could lead to major disruption in the energy flow of polar ecosystem. 相似文献
359.
The identification of degradation products generated upon photolysis of estrone (E1), a natural estrogenic hormone, under simulated UV irradiation conditions was addressed by the use of LC-Q-TOF mass spectrometry. The structures of the main degradation products were elucidated, demonstrating how the use of model molecules 5,6,7,8-tetrahydro-2-naphtol (THN), 2-methylcyclopentanone (MCP), labeled molecule estrone D(4) (E1-D(4)), the investigation of the fragmentation pathways of the parent E1, the concurrent use of CID and exact mass measurements permit the characterization of structural modifications induced by photodegradation processes. In the present study, we identified nine major by-products of which seven photoproducts correspond to E1H(+) modified in positions other than the C-2, C-4 and C-16 of E1. Most of them showed one to three additional hydroxylations preferentially located on the aromatic ring of the parent E1, which confirms that these products may present environmental risk. Applications to real water samples have been conducted to extend the validity of the present study to environmental samples. 相似文献
360.
Céline Liaud Michel Brucher Claude Schummer Clara Coscollà Hélène Wolff Jean-Jacques Schwartz 《Journal of environmental science and health. Part. B》2016,51(10):703-714
Atmospheric samples have been collected between 14 March and 12 September 2012 on a 2-week basis (15 days of sampling and exchange of traps each 7 days) in Strasbourg (east of France) for the analysis of 43 pesticides. Samples (particle and gas phases) were separately extracted using Accelerated Solvent Extraction (ASE) and pre-concentrated by Solid Phase Micro-Extraction (SPME) before analysis by gas chromatography coupled to tandem mass spectrometry (GC-MS/MS). Four SPME consecutive injections at distinct temperatures were made in order to increase the sensitivity of detection for the all monitored pesticides. Currently used detected pesticides can be grouped in four classes; those used in maize crops (acetochlor, benoxacor, dicamba, s-metolachlor, pendimethalin, and bromoxynil), in cereal crops (benoxacor, chlorothalonil, fenpropimorph, and propiconazole), in vineyards (tebuconazole), and as herbicides for orchards, meadows of green spaces (2,4-MCPA, trichlopyr). This is in accordance with the diversity of crops found in the Alsace region and trends observed are in accordance with the period of application of these pesticides. Variations observed permit also to demonstrate that the long time sampling duration used in this study is efficient to visualize temporal variations of airborne pesticides concentrations. Then, long time high-volume sampling could be a simple method permitting atmospheric survey of atmospheric contamination without any long analysis time and consequently low cost. 相似文献