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311.
The identification of degradation products generated upon photolysis of estrone (E1), a natural estrogenic hormone, under simulated UV irradiation conditions was addressed by the use of LC-Q-TOF mass spectrometry. The structures of the main degradation products were elucidated, demonstrating how the use of model molecules 5,6,7,8-tetrahydro-2-naphtol (THN), 2-methylcyclopentanone (MCP), labeled molecule estrone D(4) (E1-D(4)), the investigation of the fragmentation pathways of the parent E1, the concurrent use of CID and exact mass measurements permit the characterization of structural modifications induced by photodegradation processes. In the present study, we identified nine major by-products of which seven photoproducts correspond to E1H(+) modified in positions other than the C-2, C-4 and C-16 of E1. Most of them showed one to three additional hydroxylations preferentially located on the aromatic ring of the parent E1, which confirms that these products may present environmental risk. Applications to real water samples have been conducted to extend the validity of the present study to environmental samples. 相似文献
312.
Cocheo C Sacco P Ballesta PP Donato E Garcia S Gerboles M Gombert D McManus B Patier RF Roth C de Saeger E Wright E 《Journal of environmental monitoring : JEM》2008,10(8):941-950
The need to collect data representative of overall urban pollution is all-important in order to monitor the population exposure. High spatial resolution monitoring using diffusive samplers allows studying of the urban pollutant distribution, thus enabling deeper investigation of their generation and diffusion mechanisms. Nevertheless, such a monitoring campaign has a certain cost. In this study we point out how to find the best compromise between the number of necessary measurements and the affordable costs for monitoring campaigns. We also describe an innovative method for the proper design of a fixed urban monitoring network by means of preliminary high spatial resolution campaigns using diffusive samplers. Four European capital cities (Dublin, Madrid, Paris and Rome) were monitored six times, each time for seven days. Benzene, toluene, ethylbenzene, xylenes (BTEX) and NO(2) concentrations were measured at 146 sites in Dublin, 293 in Madrid, 339 in Paris and 290 in Rome. Multiscale grids have been drawn which ranged in mesh size from 500 m to 2 km. The statistical processing of data produced a twofold result: the creation of isoconcentration maps with geostatistical procedures, and an algorithm aimed at locating the minimum number of sampling sites where the fixed monitoring stations should be placed. Average urban levels estimated on the basis of these selected sites differ by less than 8% from those calculated on the whole populations of the sampled points. The aim of this work is to investigate how far the resolution of a monitoring campaign of urban pollution by diffusive sampling can be reduced, thus making the monitoring less expensive in terms of human and financial resources, while preserving the same quality of the results that could be achieved with a higher resolution. We found that there is no significant loss of information when the resolution of the monitoring grid for BTEX is lowered to a mesh size of 1.85 km, that is a sampling site each 3.4 km(2), and that the minimum number of sampling sites to be used is N = 0.29 A, where A is the urban surface to be monitored (in km(2)). As the spatial distribution of NO(2) is less sensitive to the distance from the emission source than that of BTEX, this relationship could be retained as a valid lower limit for the mesh grid size also for NO(2) monitoring. 相似文献
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315.
Mailloux M Martel R Gabriel U Lefebvre R Thiboutot S Ampleman G 《Journal of environmental quality》2008,37(4):1468-1476
The Arnhem Anti-Tank Range (Canadian Forces Base [CFB] Valcartier, Canada, in operation since the 1970s) has been characterized, including the drilling, installation, and characterization of 25 wells and a ground-penetrating radar survey. The observed particular features of this site include highly variable flow velocities (from < 3 to 1200 m/yr) and transient flow regime in the regional aquifer below the contaminant source zone of the impact area, sharp flow direction shifts, discontinuous stratigraphy and a local perched aquifer. A transient ground water flow model permitted us to understand how the complex hydrogeological setting shapes contaminant transport in the regional aquifer. The model explains the highly variable energetic material (EM) concentrations measured in the plume with peaks associated to spring and to a lesser extent to fall recharge events. As a conclusion from this work, the authors suggest that the characterization of contaminant sources on slopes should extend over all seasons to be sure to detect potential transient flow conditions and variable contaminant concentrations. 相似文献
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317.
Yi Zhang Lin Wu Chao Zou Boyu Jing Xiaoyu Li Tim Barlow Turpin Kevin Michel André Yao Liu Peipei Ren Gongdong Wang Hongjun Mao 《Environmental Modeling and Assessment》2017,22(5):445-458
This paper reports on the development and application of an urban high temporal-spatial resolution vehicle emission inventory model and decision support system based on the current situation in China and actual vehicle emission control requirements. The system incorporates a user-friendly modular architecture that integrates a vehicle emission model and a decision support platform and includes scenario analysis and visualisation capabilities. A bottom-up approach based on localised emission factors and actual on-road driving condition has been adopted to develop the system. As a case study of application and evaluation, an emission reduction effect analysis of the supposed low-emission zone (LEZ) policy in Beijing (2012) was conducted. According to the simulated results in the forms of tables, histograms and grid maps, the establishment of this LEZ had a definite effect on the emission reduction of various types of air pollutants, especially carbon monoxide and hydrocarbon. In the system, the simulation methodology for identifying environmental benefits brought by the LEZ policy could be used to assess other similar environmental policies. Through flexible modification of configuration values or input data variables, the efficacy of separate or joint policies could be quantifiably evaluated and graphically displayed. 相似文献
318.
Metian M Warnau M Teyssié JL Bustamante P 《Journal of environmental radioactivity》2011,102(6):543-550
In order to understand the bioaccumulation of 241Am and 134Cs in scallops living in sediments, the uptake and depuration kinetics of these two elements were investigated in the king scallop Pecten maximus exposed via seawater, food, or sediment under laboratory conditions. Generally, 241Am accumulation was higher and its retention was stronger than 134Cs. This was especially obvious when considering whole animals exposed through seawater with whole-body concentration factors (CF7d) of 62 vs. 1, absorption efficiencies (A0l) of 78 vs. 45 for seawater and biological half-lives (Tb½l) of 892 d vs. 22 d for 241Am and 134Cs, respectively. In contrast, following a single feeding with radiolabelled phytoplankton, the assimilation efficiency (AE) and Tb½l of 134Cs were higher than those of 241Am (AE: 28% vs. 20%; Tb½l: 14 d vs. 9 d). Among scallop tissues, the shells always contained the higher proportion of the total body burden of 241Am whatever the exposure pathway. In contrast, the whole soft parts presented the major fraction of whole-body burden of 134Cs, which was generally associated with muscular tissues. Our results showed that the two radionuclides have contrasting behaviors in scallops, in relation to their physico-chemical properties. 相似文献
319.
This paper attempts to analyse the role of building energy efficiency (BEE) in China in addressing climate change mitigation. It provides an analysis of the current situation and future prospects for the adoption of BEE technologies in Chinese cities. It outlines the economic and institutional barriers to large-scale deployment of the sustainable, low-carbon, and even carbon-free construction techniques. Based on a comprehensive overview of energy demand characteristics and development trends driven by economic and demographic growth, different policy tools for cost-effective CO2 emission reduction in the Chinese construction sector are described. We propose a comprehensive approach combining building design and construction, and the urban planning and building material industries, in order to drastically improve BEE during this period of rapid urban development. A coherent institutional framework needs to be established to ensure the implementation of efficiency policies. Regulatory and incentive options should be integrated into the policy portfolios of BEE to minimise the efficiency gap and to realise sizeable carbon emissions cuts in the next decades. We analyse in detail several policies and instruments, and formulate relevant policy proposals fostering low-carbon construction technology in China. Specifically, Our analysis shows that improving building energy efficiency can generate considerable carbon emissions reduction credits with competitive price under the CDM framework. 相似文献
320.
The aim of this study was to determine the effects of a 60-day head-down tilt long-term bed rest (HDT) on stress and recovery in sixteen healthy female volunteers. Participants were randomly assigned to either an exercise group (Exe) that followed a training program combining resistive and aerobic exercises, or to a no-exercise control group (Ctl). Psychological states were assessed using the Rest-Q, a validated questionnaire based on stress–recovery responses. A longitudinal analysis revealed significant changes in the general and specific-stress scales for all participants throughout the experiment with a critical stage from supine to standing posture leading to a significant decrease in physical recovery. During HDT, Exe reported higher scores on stress subscales, as well as lower recovery scores compared to the Ctl. During the post-HDT ambulatory recovery period, the exercisers still reported higher scores than the non-exercisers on the Lack of energy stress-related scale, along with lower scores in general well-being and personal accomplishment. The present findings show that simulated weightlessness such as HDT may induce psychological stress and lead to subsequent alterations in perceived recovery. Exercise did not reduce HDT impaired effects on stress and recovery states. Several suggestions, including psychological preparation, are proposed to support the beneficial effects of exercise on psychological factors. 相似文献