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151.
Gonçalves FL Andrade MF Forti MC Astolfo R Ramos MA Massambani O Melfi AJ 《Environmental pollution (Barking, Essex : 1987)》2003,121(1):63-73
Numerical modeling of scavenging processes has been compared with data obtained for rainwater and aerosol chemistry at Serra do Navio, in the state of Amapá in the Brazilian Amazon region. Sulfate, nitrate and ammonium concentrations were determined in rainwater samples collected from May 1995 until June 1997. The levels of these same chemicals were also determined in aerosols for the same period and region. Scavenging processes have been evaluated on a rainfall event basis, via numerical modeling, in order to simulate the rainwater concentrations and compare them with the observed data. RAMS (Regional Atmospheric Modeling System) was used to simulate cloud structures. A model of below-cloud scavenging was evaluated, as well. The determinations made from the results of the scavenging model are the following: a) aerosol vertical profiles are quite important to rainwater concentrations; b) modeled sulfate in rainwater is a better fit to the observed data values than ammonium and nitrate; c) the obtained sulfate aerosol concentrations samples are similar to ones found in the literature, although the sulfate concentrations in rainwater are much lower than other studies in the literature; d) the in-cloud scavenging process dominates, e) our modeled results, using an input gas vertical profile extracted from the ABLE2B experimental data set, present a smaller ratio between gas and aerosol scavenging than found in other studies in the literature, other studies may have had larger rainfall times, which increase the importance of gas phase scavenging. 相似文献
152.
We report the remarkable karyotype of Dinoponera lucida, a Brazilian endemic ponerine ant. Its chromosome number is 2n=106, most of the chromosomes are acrocentric and of very small size, and the karyotype formula is 88A+18M. A chromosome pair of the AMt type is reported. This is the largest number of chromosomes reported for the Hymenoptera order until now. 相似文献
153.
Timothy L. Jacobs Miguel A. Medina Neil Kaufman David M. Wood 《Journal of the American Water Resources Association》1993,29(1):47-54
ABSTRACT: A mathematical model is developed to optimally schedule long-term stormwater infrastructure rehabilitation activities. The model is capable of considering multiple rehabilitation projects and is driven by overall cost eensiderations. Rehabilitation activities are scheduled based on perceived reliabilities and future deterioration expected within the specified planning horizon. Future growth within the stormwater drainage basin is incorporated using chance constraints that limit the likelihood that a stormwater discharge exceeds system conveyance capacity. Model structure and development are discussed, and a hypothetical example using a drainage network is presented. 相似文献
154.
155.
The possibility of transforming waste plastics into valuable hydrocarbons via catalytic cracking and reforming is attracting
increasing interest. Pyrolysis coupled with Gas Chromatographic separation and Mass Spectrometry detection (Py-GC/MS) has
been used in this work to study the product selectivity of various catalysts in the conversion of pure and residual polyethylene
samples into hydrocarbon products. Five acid solids of comparable aluminium contents but different textural and acid properties
were tested as catalysts, including three zeolites (standard ZSM-5, nanocrystalline n-ZSM-5 and Beta) and two mesostructured
solids (Al-MCM-41 and Al-SBA-15). Thermal cracking of the pure and residual polymers generated a similar range of products
to each other, with a high proportion of linear paraffins and olefins of varying lengths. The presence of zeolitic materials
resulted in complete elimination of heavy linear products, an increase in the light hydrocarbon fraction and a marked selectivity
towards the formation of single-ring aromatic species, particularly benzene, toluene and xylene. Aromatic formation was particularly
notable with the small crystal size n-ZSM-5 (aromatic selectivity up to 53.9%) and less marked in the case of standard ZSM-5
(up to 36.4%) and Beta zeolite (up to 35.0%). Mesostructured catalysts like Al-MCM-41 and Al-SBA-15 favoured the production
of light C2–C5 hydrocarbons (up to 57.9%) while the formation of aromatic products was significantly lower than with zeolitic materials.
The paper examines the extent and the causes for this product selectivity and discusses its connection with the acid and textural
properties of each catalyst. It was also observed that, under the experimental conditions employed, the products generated
were not significantly affected by the nature and origin of the polymers employed. 相似文献
156.
Superoxide production by marine microalgae 总被引:5,自引:0,他引:5
Judith-Anne?MarshallEmail author Miguel?de?Salas Tatsuya?Oda Gustaaf?Hallegraeff 《Marine Biology》2005,147(2):533-540
A survey was conducted for production of the reactive oxygen species superoxide by 37 species (65 strains) of microalgae including dinoflagellates, raphidophytes, chlorophytes, prasinophytes, eustigmatophytes and prymnesiophytes. Ichthyotoxic raphidophyte species of Chattonella were found to produce the highest environmental levels of superoxide (177×104 total chemiluminescence units). However, ichthyotoxic dinoflagellates (Karenia, Alexandrium) and the prymnesiophyte Prymnesium were also found to produce significant levels of superoxide (4×104, 3×104 and 5×104 chemiluminescence units, respectively), equivalent to that of other raphidophyte species of Heterosigma and Fibrocapsa (6×104 and 2×104, respectively). A direct relationship between cell size and superoxide production was observed (r2=0.94), with larger cells producing more superoxide per cell. Chattonella produced the most superoxide per cell (expressed as cellular chemiluminescence units), followed by the dinoflagellate species Karenia, Alexandrium, Takayama and Gymnodinium. Small cells, such as the raphidophyte Heterosigma and the prymnesiophyte Prymnesium produced very little superoxide per cell (cellular chemiluminescence units), but potentially could still produce high total levels of superoxide if present at high biomass levels. Species commonly used as aquaculture bivalve feeds such as Dunaliella, Tetraselmis, Nannochloropsis and Pavlova produced negligible levels of superoxide, even at high biomass. We speculate that superoxide, while not the sole ichthyotoxic principle, may play a wider role in algal toxicity than previously considered, and propose a broad classification of microalgae based upon superoxide production.Communicated by M.S. Johnson, Crawley 相似文献
157.
A project to characterize the radionuclide and chemical components in natural spring waters in the vicinity of Saratoga Springs, New York (USA) has been completed. As a result of the measured radionuclide and chemical content, eight springs were labeled as mineral waters, whereas three springs contained very low concentrations of these components. The mineral waters were highly enriched in alkaline and alkaline-earth elements, as well as chloride ions. Three isotopes of radium ((224)Ra, (226)Ra, (228)Ra) were detected in the mineral waters and reached concentrations of 1, 20, and 2 Bq/L, respectively. Overall, the (226)Ra isotope constituted about 80% of the total radioactivity measured in the water samples. Dissolved uranium concentrations in the mineral waters were very low (mean approximately 50 mBq/L). 相似文献
158.
Casares ML Ulierte N Matarán A Ramos A Zamorano M 《Waste management (New York, N.Y.)》2005,25(10):1075-1082
ASEGRA is an industrial area in Granada (Spain) with important waste management problems. In order to properly manage and control waste production in industry, one must know the quantity, type, and composition of industrial wastes, as well as the management practices of the companies involved. In our study, questionnaires were used to collect data regarding methods of waste management used in 170 of the 230 businesses in the area of study. The majority of these companies in ASEGRA are small or medium-size, and belong to the service sector, transport, and distribution. This was naturally a conditioning factor in both the type and management of the wastes generated. It was observed that paper and cardboard, plastic, wood, and metals were the most common types of waste, mainly generated from packaging (49% of the total volume), as well as material used in containers and for wrapping products. Serious problems were observed in the management of these wastes. In most cases they were disposed of by dumping, and very rarely did businesses resort to reuse, recycling or valorization. Smaller companies encountered greater difficulties when it came to effective waste management. The most frequent solution for the disposal of wastes in the area was dumping. 相似文献
159.
Jorge A.?ArgáezEmail author J.?Andrés Christen Miguel?Nakamura Jorge?Soberón 《Environmental and Ecological Statistics》2005,12(1):27-44
We introduce a methodology to infer zones of high potential for the habitat of a species, useful for management of biodiversity, conservation, biogeography, ecology, or sustainable use. Inference is based on a set of sites where the presence of the species has been reported. Each site is associated with covariate values, measured on discrete scales. We compute the predictive probability that the species is present at each node of a regular grid. Possible spatial bias for sites of presence is accounted for. Since the resulting posterior distribution does not have a closed form, a Markov chain Monte Carlo (MCMC) algorithm is implemented. However, we also describe an approximation to the posterior distribution, which avoids MCMC. Relevant features of the approach are that specific notions of data acquisition such as sampling intensity and detectability are accounted for, and that available a priori information regarding areas of distribution of the species is incorporated in a clear-cut way. These concepts, arising in the presence-only context, are not addressed in alternative methods. We also consider an uncertainty map, which measures the variability for the predictive probability at each node on the grid. A simulation study is carried out to test and compare our approach with other standard methods. Two case studies are also presented. 相似文献
160.