全文获取类型
收费全文 | 1079篇 |
免费 | 130篇 |
国内免费 | 616篇 |
专业分类
安全科学 | 110篇 |
废物处理 | 43篇 |
环保管理 | 89篇 |
综合类 | 958篇 |
基础理论 | 169篇 |
污染及防治 | 264篇 |
评价与监测 | 66篇 |
社会与环境 | 74篇 |
灾害及防治 | 52篇 |
出版年
2024年 | 10篇 |
2023年 | 45篇 |
2022年 | 79篇 |
2021年 | 94篇 |
2020年 | 69篇 |
2019年 | 82篇 |
2018年 | 84篇 |
2017年 | 74篇 |
2016年 | 66篇 |
2015年 | 76篇 |
2014年 | 87篇 |
2013年 | 114篇 |
2012年 | 96篇 |
2011年 | 94篇 |
2010年 | 80篇 |
2009年 | 87篇 |
2008年 | 88篇 |
2007年 | 84篇 |
2006年 | 71篇 |
2005年 | 42篇 |
2004年 | 45篇 |
2003年 | 39篇 |
2002年 | 39篇 |
2001年 | 46篇 |
2000年 | 31篇 |
1999年 | 27篇 |
1998年 | 9篇 |
1997年 | 18篇 |
1996年 | 9篇 |
1995年 | 10篇 |
1994年 | 10篇 |
1993年 | 5篇 |
1992年 | 7篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
排序方式: 共有1825条查询结果,搜索用时 218 毫秒
61.
Xiangyun Zhong Shiyong Wu Yang Liu Zhenning Zhao Yaru Zhang Jinfeng Bai Jun Xu Bai Xi 《环境科学学报(英文版)》2013
The evolvement of morphology and structure of the coal with different metamorphic degrees during coking process in the vertical furnace was investigated by infrared Image detector. Moreover, the temperature distribution in the radial direction and the crack formation were also studied in heating process. The results show that the amount of crack and the shrinkage level of char decrease with the coal rank rising. In addition, the initial temperature of crack formation for char increases with the coal rank rising. 相似文献
62.
63.
氧气热处理的TiO2纳米管阵列光电催化降解亚甲基蓝的研究 总被引:1,自引:0,他引:1
采用原位阳极氧化法在Ti基底上制备了高度有序的TiO2纳米管阵列薄膜,SEM图像表明TiO2纳米管定向排列整齐,分布均匀,其管径范围在70~100 nm.XRD结果证明,阳极氧化法制备的TiO2纳米管为无定型晶型,经退火后为具有良好光催化活性的锐钛矿型.以亚甲基蓝(methylene blue)为目标物研究了TiO2纳米管光电催化性能及影响因素,结果表明,以0.1 mol/L NaCl为电解质,在氧气热处理气氛下,外加偏压为0.5 V、pH=3.25、光照强度为1 000μW/cm2、纳米管薄膜表面积为2 cm×2 cm且MB初始浓度为10 mg/L的条件下,TiO2纳米管阵列薄膜光电催化降解MB的降解效率可达99.56%.电化学阻抗谱分析显示,光电催化降解过程的速控步骤均为表面反应步骤,外加偏压减小了界面电荷转移阻抗,提高了光生载流子的分离效率. 相似文献
64.
淀山湖浮游藻类群落的早期增长 总被引:3,自引:3,他引:0
对2004~2009年淀山湖浮游藻类群落生物量[以叶绿素a(Chla)表示]随时间的变化进行了数学模拟.模拟结果表明,Logistic增长模型能够很好地描述淀山湖浮游藻类群落春季和夏季的早期增长.一般说来,淀山湖春季以硅藻和绿藻为主的浮游藻类群落于2月下旬进入指数级增长,到3月上旬浮游藻类密度已经达到始盛点的2倍,浮游... 相似文献
65.
阿替洛尔在硝酸根溶液中的光降解研究 总被引:1,自引:0,他引:1
以氙灯为模拟太阳光光源,研究了β阻滞剂阿替洛尔(ATL)在硝酸根溶液中的光解,探讨了硝酸根离子浓度、溶液pH值、碳酸氢根离子浓度和腐殖质浓度对ATL光解的影响.结果表明,ATL在不同浓度硝酸根溶液中的光解反应符合准一级动力学规律,增大硝酸根离子浓度促进了ATL的光降解率,当硝酸根离子浓度由0增至5 mmol.L-1时其速率常数由0.002 26min-1增至0.009 4 min-1;酸性或碱性溶液有利于ATL在硝酸根溶液中的光解,碳酸氢根离子浓度对光解无明显影响,而加入Suwannee富里酸(SRFA)对光解产生抑制作用.采用异丙醇作为羟基自由基分子探针检测到.OH存在于ATL光解过程中.采用SPE-LC-MS方法鉴定了ATL在硝酸根溶液中的主要光解产物,并提出了可能的光解途径. 相似文献
66.
67.
若尔盖高原湿地藻类多样性研究 总被引:1,自引:1,他引:0
分别于夏、冬两季采集若尔盖高原湿地水样,利用传统培养及显微镜检的方法和现代分子生物学方法对其藻类多样性进行了研究.结果表明,夏季水样至少培养出4种绿藻,分别为普通小球藻(Chlorella vulgaris Beij.)、浮球藻(Planktosphaeriagelatinosa G.M.Smith)、繁茂栅列藻(Scenedesmus abundans Kirchner)和柱状栅列藻(Scenedesmus bijuga Turp.),均属于绿球藻(Chlorococcales),其中普通小球藻为优势藻种,并被分离纯化.显微镜检结果表明冬季水样中主要的藻类种群为硅藻,此结果符合在低温季节天然水体中常以硅藻为主的常理.蓝藻16S rRNA基因克隆文库中的主要类群为硅藻(Bacillaripiophyta,35.3%),其次为蓝藻,包括色球藻(Chroococcales,5.9%)、念珠藻(Nostocales,11.8%)、颤藻(Oscillatoriales,11.8%)和一些未知种属的蓝藻类群(Unclassified Cyanobacteria,35.3%),还发现一些与低温环境微生物相关的类群,如颤藻目细纤菌属(Leptolyngbya). 相似文献
68.
69.
Yanhui Li Bing Xi Quansheng Zhao Fuqiang Liu Pan Zhang Qiuju Du Dechang Wang Da Li Zonghua Wang Yanzhi Xia 《环境科学学报(英文版)》2011,23(3):404-411
Kaolin has been widely used as an adsorbent to remove heavy metal ions from aqueous solutions. However, the lower heavy metal
adsorption capacity of kaolin limits its practical application. A novel environmental friendly material, calcium alginate immobilized
kaolin (kaolin/CA), was prepared using a sol-gel method. The e ects of contact time, pH, adsorbent dose, and temperature on Cu2+
adsorption by kaolin/CA were investigated. The Langmuir isotherm was used to describe the experimental adsorption, the maximum
Cu2+ adsorption capacity of the kaolin/CA reached up to 53.63 mg/g. The thermodynamic studies showed that the adsorption reaction
was a spontaneous and endothermic process. 相似文献
70.
Removal of polycyclic aromatic hydrocarbons (PAHs), e.g., naphthalene, acenaphthene, phenanthrene and pyrene, from aqueous solution by raw and modified plant residues was investigated to develop low cost biosorbents for organic pollutant abatement. Bamboo wood, pine wood, pine needles and pine bark were selected as plant residues, and acid hydrolysis was used as an easily modification method. The raw and modified biosorbents were characterized by elemental analysis, Fourier transform infrared spectroscopy and scanning electron microscopy. The sorption isotherms of PAHs to raw biosorbents were apparently linear, and were dominated by a partitioning process. In comparison, the isotherms of the hydrolyzed biosorbents displayed nonlinearity, which was controlled by partitioning and the specific interaction mechanism. The sorpfion kinetic curves of PAHs to the raw and modified plant residues fit well with the pseudo second-order kinetics model. The sorption rates were faster for the raw biosorbents than the corresponding hydrolyzed biosorbents, which was attributed to the latter having more condensed domains (i.e., exposed aromatic core). By the consumption of the amorphous cellulose component under acid hydrolysis, the sorption capability of the hydrolyzed biosorbents was notably enhanced, i.e., 6-18 fold for phenanthrene, 6-8 fold for naphthalene and pyrene and 5-8 fold for acenaphthene. The sorpfion coefficients (Kd) were negatively correlated with the polarity index [(O+N)/C], and positively correlated with the aromaticity of the biosorbents. For a given biosorbent, a positive linear correlation between logKoc and logKow for different PAHs was observed. Interestingly, the linear plots of logKoc-logKow were parallel for different biosorbents. These observations suggest that the raw and modified plant residues have great potential as biosorbents to remove PAHs from wastewater. 相似文献