全文获取类型
收费全文 | 1845篇 |
免费 | 104篇 |
国内免费 | 610篇 |
专业分类
安全科学 | 133篇 |
废物处理 | 112篇 |
环保管理 | 137篇 |
综合类 | 1069篇 |
基础理论 | 300篇 |
污染及防治 | 585篇 |
评价与监测 | 96篇 |
社会与环境 | 64篇 |
灾害及防治 | 63篇 |
出版年
2024年 | 5篇 |
2023年 | 52篇 |
2022年 | 136篇 |
2021年 | 105篇 |
2020年 | 81篇 |
2019年 | 82篇 |
2018年 | 77篇 |
2017年 | 90篇 |
2016年 | 115篇 |
2015年 | 119篇 |
2014年 | 123篇 |
2013年 | 178篇 |
2012年 | 145篇 |
2011年 | 153篇 |
2010年 | 114篇 |
2009年 | 107篇 |
2008年 | 102篇 |
2007年 | 111篇 |
2006年 | 75篇 |
2005年 | 56篇 |
2004年 | 36篇 |
2003年 | 56篇 |
2002年 | 64篇 |
2001年 | 43篇 |
2000年 | 48篇 |
1999年 | 46篇 |
1998年 | 39篇 |
1997年 | 37篇 |
1996年 | 40篇 |
1995年 | 25篇 |
1994年 | 12篇 |
1993年 | 25篇 |
1992年 | 14篇 |
1991年 | 9篇 |
1990年 | 10篇 |
1989年 | 3篇 |
1988年 | 10篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1984年 | 3篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1958年 | 1篇 |
1956年 | 2篇 |
排序方式: 共有2559条查询结果,搜索用时 15 毫秒
91.
Phosphorus is a vital nutrient for algal growth, thus, a better understanding of phosphorus availability is essential to mitigate harmful algal blooms in lakes. Wind waves are a ubiquitous characteristic of lake ecosystems. However, its effects on the cycling of organic phosphorus and its usage by phytoplankton remain poorly elucidated in shallow eutrophic lakes. A mesocosm experiment was carried out to investigate the responses of alkaline phosphatase activity fractions to wind waves in large, shallow, eutrophic Lake Taihu. Results showed that wind-driven waves induced the release of alkaline phosphatase and phosphorus from the sediment, and dramatically enhanced phytoplanktonic alkaline phosphatase activity. However, compared to the calm conditions, bacterial and dissolved alkaline phosphatase activity decreased in wind-wave conditions. Consistently, the gene copies of Microcystis phoX increased but bacterial phoX decreased under wind-wave conditions. The ecological effects of these waves on phosphorus and phytoplankton likely accelerated the biogeochemical cycling of phosphorus and promoted phytoplankton production in Lake Taihu. This study provides an improved current understanding of phosphorus availability and the phosphorus strategies of plankton in shallow, eutrophic lakes. 相似文献
92.
Imhoff PT Reinhart DR Englund M Guérin R Gawande N Han B Jonnalagadda S Townsend TG Yazdani R 《Waste management (New York, N.Y.)》2007,27(6):729-745
In recent years several types of sensors and measurement techniques have been developed for measuring the moisture content, water saturation, or the volumetric water content of landfilled wastes. In this work, we review several of the most promising techniques. The basic principles behind each technique are discussed and field applications of the techniques are presented, including cost estimates. For several sensors, previously unpublished data are given. Neutron probes, electrical resistivity (impedance) sensors, time domain reflectometry (TDR) sensors, and the partitioning gas tracer technique (PGTT) were field tested with results compared to gravimetric measurements or estimates of the volumetric water content or moisture content. Neutron probes were not able to accurately measure the volumetric water content, but could track changes in moisture conditions. Electrical resistivity and TDR sensors tended to provide biased estimates, with instrument-determined moisture contents larger than independent estimates. While the PGTT resulted in relatively accurate measurements, electrical resistivity and TDR sensors provide more rapid results and are better suited for tracking infiltration fronts. Fiber optic sensors and electrical resistivity tomography hold promise for measuring water distributions in situ, particularly during infiltration events, but have not been tested with independent measurements to quantify their accuracy. Additional work is recommended to advance the development of some of these instruments and to acquire an improved understanding of liquid movement in landfills by application of the most promising techniques in the field. 相似文献
93.
This investigation conducted a full-scale survey the drinking water distribution system in Kaohsiung city, Taiwan. The aim
was to investigate whether the distribution system was capable of maintaining high water quality from the water treatment
facilities through to the end user. The results showed that the distribution system can maintain high water quality, except
for suitable chlorine residuals. The authors plotted chlorine residual contour maps to identify areas with low chlorine residuals,
helping them prioritize sections that must be flushed or renewal. The contour maps also provide sufficient and clear information
for locating booster chlorination stations. Contour maps enable water facilities to identify how water quality decays in the
distribution systems and the locations of such decay. Water quality decay can be caused by properties of pipeline materials,
hydraulic conditions, and/or biofilm thickness. However, understanding the exact reasons is unnecessary because the contour
maps provide sufficient information for trouble-shooting the distribution systems. 相似文献
94.
Research and application of method of oxygen isotope of inorganic phosphate in Beijing agricultural soils 总被引:1,自引:0,他引:1
Liyan Tian Qingjun Guo Yongguan Zhu Huijun He Yunchao Lang Jian Hu Han Zhang Rongfei Wei Xiaokun Han Marc Peters Junxing Yang 《Environmental science and pollution research international》2016,23(23):23406-23414
Phosphorus (P) in agricultural ecosystems is an essential and limited element for plants and microorganisms. However, environmental problems caused by P accumulation as well as by P loss have become more and more serious. Oxygen isotopes of phosphate can trace the sources, migration, and transformation of P in agricultural soils. In order to use the isotopes of phosphate oxygen, appropriate extraction and purification methods for inorganic phosphate from soils are necessary. Here, we combined two different methods to analyze the oxygen isotopic composition of inorganic phosphate (δ18OP) from chemical fertilizers and different fractions (Milli-Q water, 0.5 mol L?1 NaHCO3 (pH = 8.5), 0.1 mol L?1 NaOH and 1 mol L?1 HCl) of agricultural soils from the Beijing area. The δ18OP results of the water extracts and NaHCO3 extracts in most samples were close to the calculated equilibrium value. These phenomena can be explained by rapid P cycling in soils and the influence of chemical fertilizers. The δ18OP value of the water extracts and NaHCO3 extracts in some soil samples below the equilibrium value may be caused by the hydrolysis of organic P fractions mediated by extracellular enzymes. The δ18OP values of the NaOH extracts were above the calculated equilibrium value reflecting the balance state between microbial uptake of phosphate and the release of intracellular phosphate back to the soil. The HCl extracts with the lowest δ18OP values and highest phosphate concentrations indicated that the HCl fraction was affected by microbial activity. Hence, these δ18Op values likely reflected the oxygen isotopic values of the parent materials. The results suggested that phosphate oxygen isotope analyses could be an effective tool in order to trace phosphate sources, transformation processes, and its utilization by microorganisms in agricultural soils. 相似文献
95.
Combination of biochar amendment and phytoremediation for hydrocarbon removal in petroleum-contaminated soil 总被引:1,自引:0,他引:1
Tao Han Zhipeng Zhao Mark Bartlam Yingying Wang 《Environmental science and pollution research international》2016,23(21):21219-21228
Remediation of soils contaminated with petroleum is a challenging task. Four different bioremediation strategies, including natural attenuation, biochar amendment, phytoremediation with ryegrass, and a combination of biochar and ryegrass, were investigated with greenhouse pot experiments over a 90-day period. The results showed that planting ryegrass in soil can significantly improve the removal rate of total petroleum hydrocarbons (TPHs) and the number of microorganisms. Within TPHs, the removal rate of total n-alkanes (45.83 %) was higher than that of polycyclic aromatic hydrocarbons (30.34 %). The amendment of biochar did not result in significant improvement of TPH removal. In contrast, it showed a clear negative impact on the growth of ryegrass and the removal of TPHs by ryegrass. The removal rate of TPHs was significantly lower after the amendment of biochar. The results indicated that planting ryegrass is an effective remediation strategy, while the amendment of biochar may not be suitable for the phytoremediation of soil contaminated with petroleum hydrocarbons. 相似文献
96.
采用共混热解法制备系列Ce-Sn-W-Ox复合氧化物,用于NH3选择性催化还原NO。通过正交实验优化CeSn-W-Ox配方,采用环境扫描电镜(ESEM)、X-射线衍射仪(XRD)等表征分析催化剂的微观形貌和固相结构,确立Ce-Sn-WOx最佳配比及结构形貌。结果表明,以粒度为5~8 mm的堇青石瓷片担载分散Ce-Sn-W-Ox,进行NH3-SCR脱除NO,当Ce/Sn/W元素摩尔比为1∶0.8∶0.6时,Ce Sn0.8W0.6Ox/堇青石NH3-SCR脱除NO效果最好。当空速为7 200 h-1,催化剂在252~426℃内脱除NO效率均大于94%。重点考察了反应空速(GHSV)、水蒸气(H2O)、SO2等对Ce Sn0.8W0.6Ox/堇青石NH3-SCR脱除NO活性的影响。研究表明,空速低于10 000 h-1时,催化剂脱硝活性受空速影响小;单独通入5%H2O对催化剂脱硝活性基本没有影响;单独通入429 mg/m3SO2导致催化剂活性略有降低;同时通入429 mg/m3SO2和5%H2O,催化剂脱硝活性下降至85.33%,除去SO2和H2O后,催化剂活性又能明显回升。 相似文献
97.
98.
Xie Qiaoling Wang Dandan Han Zhichao Tao Huchun Liu Sitong 《Journal of Material Cycles and Waste Management》2023,25(1):62-73
Journal of Material Cycles and Waste Management - A ball milling pretreatment with additives for fly ash and the combined use of reagents as flotation collectors in fly ash flotation were... 相似文献
99.
100.
为响应国家节能减排和循环经济的理念,本文提出一种新的园区污水处理方式-以污治污:利用企业A废水中的碱性物质与消耗企业B废水中的氢离子,再向废水中投加石灰石去除多余的氢离子,投加液碱去除废水中的铜离子和锌离子。优化后的废水处理方式可减少盐酸、石灰石的使用量,从源头上减少了资源的浪费和排入外环境的污染物,对社会发展和生态环境均具有明显的正效益。 相似文献