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571.
Hua Zhang Zhiliang Zhu Noboru Yoshikawa 《Frontiers of Environmental Science & Engineering in China》2011,5(2):205-211
Microwave processing was used to stabilize copper ions in soil samples. Its effects on the stabilization efficiency were studied
as a function of additive, microwave power, process time, and reaction atmosphere. The stabilization efficiency of the microwave
process was evaluated based on the results of the toxicity characteristic leaching procedure (TCLP) test. The results showed
that the optimal experimental condition contained a 700W microwave power, 20 min process time and 3 iron wires as the additive,
and that the highest stabilization efficiency level was more than 70%. In addition, the different reaction atmospheres showed
no apparent effect on the stabilization efficiency of copper in the artificially contaminated soil. According to the result
of the Tessier sequential extraction, the partial species of copper in the contaminated soil was deduced to transform from
unstable species to stable states after the microwave process. 相似文献
572.
Baohua Tang Lingyan Zhu Qixing Zhou 《Frontiers of Environmental Science & Engineering in China》2011,5(1):99-110
The joint toxicity of Penta-BDE (Pe-BDE) and heavy metals including cadmium and copper on Daphnia magna (D. magna) was evaluated on the basis of determining the 48 h survival, antioxidative enzyme responses, and lipid peroxidation. The
response was classified as additive, greater than additive, or less than additive by comparing the measured “toxic units,
TU” with one. Based on the survival of D. magna, less-than-additive interactions were found in most of mixtures treatments. This may be attributed to the different toxicity
mechanism between Pe-BDE and metals. Cu and Cd played a greater role in toxicity than what Pe-BDE did. As for the superoxide
dismutase (SOD) and catalase (CAT) activity, most response was less than additive. For the glutathione S-transferases (GST) activity, most of the greater-thanadditive responses were found in the Cu plus Pe-BDE treatments, but
the additive responses occurred in Cd plus Pe-BDE treatments and binary metal treatments. For lipid peroxide levels, which
were measured as malondialdehyde (MDA) levels, less-than-additive response occurred in the 50% Cd plus 50% Cu and ternary
mixture treatments. Results suggested that Pe-BDE, Cd, and Cu could induce different patterns of antioxidant enzyme responses,
such as antioxidant/prooxidant responses, depending on their capability to produce reactive oxygen species and antioxidant
enzymes to detoxify them. 相似文献
573.
Yanhui Zhan Jianwei Lin Yanling Qiu Naiyun Gao Zhiliang Zhu 《Frontiers of Environmental Science & Engineering in China》2011,5(1):65-75
Surfactant-modified natural zeolites (SMNZ) with different coverage types were prepared by loading hexadecyltrimethyl ammonium
bromide (HTAB) onto the surface of a natural zeolite. The adsorption behavior of humic acid (HA) on SMNZ was investigated.
Results indicate that the adsorbent SMNZ exhibited a higher affinity toward HA than the natural zeolite. HA removal efficiency
by SMNZ increased with HTAB loading. Coexisting Ca2+ in solution favored HA adsorption onto SMNZ. Adsorption capacity decreased with an increasing solution pH. For typical SMNZ
with bilayer HTAB coverage, HA adsorption process is well described by a pseudo-second-order kinetic model. The experimental
isotherm data fitted well with the Langmuir model. Calculated maximum HA adsorption capacities for SMNZ with bilayer HTAB
coverage at pH 5.5 and 7.5 were 63 and 41 mg·g−1, respectively. E2/E3 (absorbance at 250 nm to that at 365 nm) and E4/E6 (absorbance at 465 nm to that at 665 nm) ratios of
the residual HA in solution were lower than that of the original HA solution. This indicates that the HA fractions with high
polar functional groups, low molecular weight (MW), and aromaticity had a stronger tendency for adsorption onto SMNZ with
bilayer HTAB coverage. Results show that HTAB-modified natural zeolite is a promising adsorbent for removal of HA from aqueous
solution. 相似文献
574.
针对环境样品采用钼酸铵分光光度法测定的总磷中,影响显色的二个因素进行了分析,对加入显色刺后的混合过程对显色结果的影响,以及环境条件的温度对显色的影响进行了研究,对总磷测定时准确度及精密度的提高有着重要的参考价值,是对钼酸铵法测定总磷方法的完善。 相似文献
575.
576.
本文提出了以固定混合器作为促进混合效果装置的快速混合法,并以E.Coli作为指示微生物、液氯作为消毒剂进行了研究。结果表明,均匀快速而剧烈的初始混合作用,可大大改善灭菌效果。在短至5秒的接触时间内即可达到99.99%以上的灭活效率。投氯量和接触时间对E.Coli灭活率的影响随混合程度的提高而减弱。与传统法相比,灭活率可提高100倍以上,投氯量可下降4—8倍,接触时间可大大缩短。 相似文献
577.
本文详细研究了在硫酸介质中,邻苯氨基苯甲酸与NO_3~-和NO_2~-离子显色体系的光度性质与形成条件。结果表明,显色产物的最大吸收λ_(?)位于560—565nm。在此波长下,表观摩尔吸光系数分别为:ε′NO_3~-=1.07×10~5和ε′NO_2~-=1.77×10~5。符合Beer定律的浓度范围为:0.03—0.15 μg/ml(NO_2~--N)和0.05—0.20 μg/ml(NO_3~--N)。据此,拟定了分光光度联合训定NO_3~--N和NO_2~--N的新方法,应用于地表水的测定,得到了满意的结果。 相似文献
578.
聚对苯二甲酸乙二醇酯废料的回收方法 总被引:6,自引:0,他引:6
介绍了聚对苯二甲酸乙二醇酯传统的化学回收方法:甲醇醇解法、水解法和醣酵解法;简述了聚酯新的回收工艺:伊斯曼乙二醇水解工艺、超临界水水解工艺和Reco-PET工艺,及有关国家聚酯回收的工业化实践,并对聚酯回收的前景及影响聚酯回收的因素进行了分析。 相似文献
579.
580.