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151.
Journal of Polymers and the Environment - This research is an effort towards the synthesis of a novel Guar Gum (GG) based flocculant by grafting it with Itaconic Acid (IA) using microwave... 相似文献
152.
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154.
The kinetics of ferrate(VI) (FeVIO4
2−, Fe(VI)) oxidation of an antiphlogistic drug, ibuprofen (IBP), as a function of pH (7.75–9.10) and temperature (25–45°C) were investigated to see the applicability of Fe(VI) in removing this drug from water. The rates decrease with an increase in pH and the rates are related to protonation of ferrate(VI). The rates increase with an increase in temperature. The E
a of the reaction at pH 9.10 was calculated as 65.4±6.4 kJ mol−1. The rate constant of the HFeO4
− with ibuprofen is lower than with the sulphur drug, sulfamethoxazole. The use of Fe(VI) to remove ibuprofen is briefly discussed. 相似文献
155.
Carol J. Miller Manoj Mishra 《Journal of the American Water Resources Association》1989,25(3):551-556
ABSTRACT: The existence and importance of macro-pores to the containment efficiency of cover clay liners at waste landfills is documented. Macro-pores exist as voids, or cracks, and act to increase the volume and rate of leakage through cover liners. Existing numerical models used to simulate flow through clay liners are shown to neglect the macro-pore aspect of the problem. Current theories of macro-pore flow developed from related areas of research are presented, and applications to the landfill liner problem are considered. 相似文献
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158.
In the present study, catalytic wet oxidation (CWO) was investigated for the destruction of organic pollutants in the thermally pretreated effluent from a pulp and paper mill under moderate temperature and pressure conditions. The thermal pretreatment studies were conducted at atmospheric pressure and 368K using copper sulfate as a catalyst. The thermal pretreatment reduced COD by about 61%. The filtrate of the thermal pretreatment step was used at pH 8.0 for CWO at 383-443K temperature and a total pressure of 0.85MPa for 4h. Catalysts used for the reaction include copper sulfate, 5% CuO/95% activated carbon, 60% CuO/40% MnO(2), and 60% CuO/40% CeO(2). Maximum COD reduction was found to be 89% during CWO step using 5% CuO/95% activated carbon with a catalyst loading of 8gl(-1) at 443K and 0.85MPa total pressure. Overall COD reduction for the pretreatment and the CWO was found to be 96%. Besides this, 60% CuO/40% CeO(2) catalyst also exhibited the similar activity as that of obtained with 5% CuO/95% activated carbon catalyst at 423K temperature and 0.85MPa total pressure. The pH of the solution during the experimental runs decreases initially due to the formation of carboxylic acid and then increases due to the decomposition of acids. 相似文献
159.
Gupta DK Tripathi RD Rai UN Mishra S Srivastava S Dwivedi S Maathuis FJ 《Environmental monitoring and assessment》2007,134(1-3):479-487
Growth and metal accumulation were investigated in two Cicer arietinum L. varieties (var. CSG-8962 and var. C-235) when grown in various combinations of fly ash (FA) amended with garden soil (GS),
press mud (PM) or saw dust (SD). In addition, the levels of photosynthetic pigments, nitrate reductase (NR) activity, cysteine,
non-protein thiols (NP-SH), and ascorbic acid were studied. FA amended with GS or PM led to a 5–10 times increase in biomass
compared to FA control and was most pronounced in the less metal tolerant variety CSG-8962. Amendment of FA with either GS
or PM only moderately increased the contents of some essential metals whereas the non-essential Cd and Cr remained similar
or decreased slightly compared to FA control. FA combined with either GS or PM increased the amount of photosynthetic pigments
and was largely absent when SD was added to FA. Improved nitrogen availability led to increased nitrate reductase (NR) activity
with all amendments but less so with SD. Metal stress indicating parameters were generally reduced (cysteine and non-protein
thiols) or unchanged (ascorbic acid). In conclusion, of the tested ameliorants both GS and PM greatly improved growth of C. arietinum making FA a suitable component of plant growth substrates. 相似文献
160.
Trace metals and organometals in selected marine species and preliminary risk assessment to human beings in Thane Creek area, Mumbai 总被引:3,自引:0,他引:3
Mishra S Bhalke S Saradhi IV Suseela B Tripathi RM Pandit GG Puranik VD 《Chemosphere》2007,69(6):972-978
Trace metals and organometals were estimated in different types of marine organisms (fish, bivalve, crab and prawn) collected from the Trans-Thane Creek area, Mumbai. Thane Creek area is considered as most polluted area due to industrial discharges. Potential risks associated with consumption of marine organisms collected from this particular area to human beings were assessed. Concentrations of ten trace elements (As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb and Zn) in the edible part of marine organisms were analysed by atomic absorption spectrometer and differential pulse anodic stripping voltametric technique. Methyl mercury and tributyl tin were estimated using gas chromatograph-mass spectrometer in combination with solid phase micro extraction (SPME). An assessment of the risk on human beings due to consumption of marine organism was undertaken using toxic reference benchmark, namely the reference dose (RfD). The hazard index (HI), sum of hazard quotients calculated for all the pollutant showed that the risks from consumption of fish and marine organisms as a whole were generally low and are within safe limits. 相似文献