Tank mixture additives approach to improve efficiency of bentazon against broadleaf weeds in peas

Efficiency of different tank-mixed additives with bentazon at half rate was investigated on (Malva parviflora) and other broad leaf weeds compared with bentazon at the full recommended rate without additives in peas in open field. All the tested additives enhanced the efficiency of bentazon at the half rate. Nonyl phenol and toximol S proved to be the most effective additives in comparison with the full rate treatment. The tested treatments did not show any significant effect on chlorophyll content and soil microorganisms. Bentazon residues were determined in certain treatments to investigate the effect of the tested additives on bentazon deposition. Samples were extracted using QuEChERS method and residues were determined using LC-MS/MS. Residues after 24 hours in the half rate treatment reached 4 times lower than the Maximum Residues Limit (MRL) (0.11 mg kg(-1)), compared to the full rate treatment (0.51 mg kg(-1)), that was slightly above the MRL.     

Indigenous soil bacteria with the combined potential for hydrocarbon consumption and heavy metal resistance

Introduction  

Transconjugant bacteria with combined potential for hydrocarbon utilization and heavy metal resistance were suggested by earlier investigators for bioremediation of soils co-contaminated with hydrocarbons and heavy metals. The purpose of this study was to offer evidence that such microorganisms are already part of the indigenous soil microflora.     

Optimization of integrated water quality management for agricultural efficiency and environmental conservation

The scarcity of water resources in Egypt has necessitated the use of various types of lower quality water. Agricultural drainage water is considered a strategic reserve for meeting increasing freshwater demands. In this study, a novel model series was applied to a drainage basin in the Nile Delta to optimize integrated water quality management for agriculture and the aquatic environment. The proposed model series includes a waste load allocation model, an export coefficient model, a stream water quality model, and a genetic algorithm. This model series offers an optimized solution for determining the required removal levels of total suspended solids (TSS), the chemical oxygen demand (COD) at point and non-point pollution sources, and the source flows that require treatment to meet a given water quality target. The model series was applied during the summer and winter to the El-Qalaa basin in the western delta of the Nile River. Increased pollutant removal and treated fractions at point and non-point sources reduced violations of the TSS standards from 732.6 to 238.9 mg/L in summer and from 543.1 to 380.9 mg/L in winter. Likewise, violations of the COD standards decreased from 112.4 mg/L to 0 (no violations) in summer and from 91.7 mg/L to no violations in winter. Thus, this model is recommended as a decision support tool for determining a desirable waste load allocation solution from a trade-off curve considering costs and the degree of compliance with water quality standards.     

Hydrogeochemical evaluation of calcareous eolianite aquifer with saline soil in a semiarid area

The aim of this study is to evaluate the groundwater geochemistry in Burg Elarab area as an example of a calcareous eolianite aquifer that is covered with saline soil in a semiarid climatic condition. To conduct this study, 37 groundwater samples were taped from the production wells in addition to two surface water samples from Mallahet Mariut Lake and Bahig Canal. To elucidate the origin of dissolved ions and the geochemical processes influencing this groundwater, combinations of geomorphological, pedological, hydrogeological, hydrochemical, and statistical approaches were considered. Results suggest that the groundwater flows from both sides of the plain to the central area. Soil type and salinity and the intruded brackish lake water are the main factors controlling the groundwater chemistry. Chemically, the groundwater samples were classified into three groups. Group 1 samples have higher salinity range and characterize the area close to Mallahet Mariut and are influenced by cation exchange processes. Group 2 samples have an intermediate salinity range, occupy most of the plain area, and receive water from direct infiltrations and mixing between different recharge sources. Group 3 samples have low salinity range and limited areal extent and characterize the groundwater flowing from the Mariut Tableland. Reverse ion exchange is the predominant process in the latter group. Calcite precipitation is a general phenomenon characterizing all the groundwater types in the study area.     

Performance of oil palm kernel shell gasification using a medium-scale downdraft gasifier

This article focused on the performance of oil palm kernel shell (PKS) gasification using a medium-scale downdraft gasifier with a feedstock capacity of 500 kg at a temperature range of 399–700°C and at a feed rate of 177 kg/h. This article is important for evaluating the reliability of PKS gasification for commercial power generation activities from biomass. The process performance was evaluated based on the syngas calorific value (CV), syngas flow rate, and its cold gas efficiency (CGE). The syngas flow rates and CVs were measured using a gas flow meter and a gas analyzer in real time. The data obtained were then analyzed to evaluate the performance of the process. The results showed that the CGE of the process was moderately high (51%) at 681°C, with a high syngas CV (4.45–4.89 MJ/Nm³) which was ideal for gas engine applications. The PKS gasification performance increased when the reactor temperature increased. Projections were made for the CGE and the syngas CV for the PKS gasification with increased reactor temperatures and it was found that these values could be increased up to 80% and 5.2 MJ/Nm^3, respectively at a reactor temperature of 900°C. In addition, the estimated power that could be generated was about 600 kW_e at a maximum operation of 500 kg/h of feed rate. Based on the analysis, a medium-scale PKS gasification is observed to be a promising process for power generation from biomass due to the favorable performance of the process.     

Effects of Cd2+ on K+, Ca2+ and N uptake in two halophytes Sesuvium portulacastrum and Mesembryanthemum crystallinum: consequences on growth

One of the limits of Cd2+-phytoextraction is the high toxicity of this metal to plants. Growth restriction, chlorosis and necrosis are usually accompanied with a large disturbance of the uptake of essential elements. This work aims to study the effects of cadmium (Cd2+) on potassium (K+), calcium (Ca2+) and nitrogen (N) acquisition, and their consequences on growth in two halophytes species: Sesuvium portulacastrum and Mesembryanthemum crystallinum. Seedlings were grown for 30 days in split-root conditions. One half of the root system was immersed in complete nutrient solution (Basal medium (B)) supplemented with 100 microM Cd2+, and the other half was immersed in a Cd2+-free medium, containing all nutrients (B/Cd plants) or deprived of potassium ((B-K)/Cd) or calcium ((B-Ca)/Cd) or nitrogen ((B-N)/Cd). Using this approach, we demonstrated that K+ and Ca2+ uptake was impaired in roots exposed to Cd2+. Concerning N, we noticed no indication of uptake inhibition by Cd2+. However, restriction of K+ uptake by roots was compensated by an increase in the K+-use efficiency, so that growth was not inhibited. Calcium uptake was strongly limited by Cd2. This inhibition was accompanied by a reduction in growth of ((B-Ca)/Cd) plants. Thus, we conclude that Cd2+ limits growth of both halophytes through restriction imposed on Ca2+ uptake. We suggest that the increase of Ca2+ availability in soils could improve the growth of both species in the presence of Cd2+. This would be essential for improving their utility for extraction of this metal by from salty contaminated soils.     

Assessing the transformation kinetics of 2- and 4-nitrophenol in the atmospheric aqueous phase. Implications for the distribution of both nitroisomers in the atmosphere

Different transformation processes for nitrophenols in the atmospheric aqueous phase were considered to assess their relative importance, and their ability to account for the higher occurrence of 4-nitrophenol (4NP) compared to 2-nitrophenol (2NP) in the atmosphere. The importance of the different processes was in the order ^?OH > ^?NO₃ > direct photolysis > nitration to 2,4-dinitrophenol. 2NP is more reactive than 4NP with the hydroxyl radical, but the difference is low. Accordingly, such a process could account for the higher atmospheric occurrence of 4NP only if the observed atmospheric nitrophenols were what was left of an almost complete degradation by ^?OH. This would imply the unlikely scenario that the known nitrophenol sources to the atmosphere were only a limited fraction of the actual ones. A more likely, tentative possibility would be connected with the higher occurrence of 4NP on particles. If the reactivity order of nitrophenols in the atmospheric compartments was water droplets > gas phase > particles, particulate matter could act as a reservoir of 4NP. 2NP would undergo degradation in gas phase or solution at a higher rate than 4NP on particles, which could decrease the atmospheric levels of 2NP below those of 4NP.     

Potential for internal loading by phosphorus based on sequential extraction of surficial sediment in a shallow Egyptian Lake

The fractionation of phosphorus (P) in shallow Lake Maryout surficial sediments was investigated in order to understand its potential availability in relation to the eutrophication status of this lake. The rank order of P fractions was NaOH-P > HCl-P > NH₄Cl-P > BD-P. The metal oxide-bound P (NaOH-P) averaged 43% in this hypereutrophic lake and would be potentially available under low oxygen conditions. The highly available, loosely sorbed P (NH₄Cl-P) represented 20% of the sedimentary inorganic P on average, while the reductant P (BD-P) averaged 15% and is also considered highly available under low oxygen conditions. The less available calcium-bound P (HCl-P) represented 22% of sedimentary inorganic P. Lake Maryout exhibits high potential for release of P from sediment in forms available to algae, which is undesirable for eutrophication control. The range of potentially available P in tested sediments was 1,541 to 3,990 mg/kg (ppm), a very high quantity capable of supporting algal blooms independent of external loading.     

Organic matter content of sediments in continental shelf area of southeast coast of India

Total organic matter (TOM) content of sediment samples collected from various depths of continental shelf region of the southeast coast of India varied from 0.19% to 7.73%. Higher TOM content and lower median particle diameter could be attributed to the influence of higher riverine flow. Higher values were observed at 100?m depth and above (average 5.29%) and lower values in shallower depths below 100?m (average 3.07%). In the Principal Coordinate Analysis (PCO), the first two axes explained about 83.1% of the total variability. The direction of the vector representing total organic matter was towards 150?m depth. In the Canonical Analysis of Principal Coordinates (CAP) done to confirm the above pattern, the canonical correlation value obtained for the first axis was high (0.9999). The same for the second axis was 0.9995. The direction of the axis representing TOM in this analysis was towards the 100?m depth truly reflecting higher TOM level recorded here (average TOM at 100?m depth—5.81% and at 150?m depth—5.33%). The percentage of samples allocated to the correct group in CAP was 91.67% (33 out of the 36 samples). As the allocation success of samples is substantially greater around 92%, the CAP is explaining greater percentage of variability of TOM than PCO and was found to be quite useful for studies of this nature.     

Acute toxicities of cadmium and permethrin on the pre-spawning and post-spawning phases of Hexaplex trunculus from Bizerta Lagoon, Tunisia

Marine gastropods, exposed to anthropogenic pollution, accumulate high chemical concentrations in their tissues, especially in the digestive glands. An evaluation of the impacts of cadmium (Cd) and permethrin (Perm), coupled with reproductive events (pre-spawning and post-spawning phase) throughout the year, was attempted by measuring catalase (CAT), a biomarker of defence, on Hexaplex trunculus experimentally exposed for 48 or 96 h. Specimens of gastropods were sampled from Bizerta Lagoon (Tunisia). The results show that CAT activity increased in gastropods exposed to the three cadmium concentrations (C1 Cd, 100 μg L(-1); C2 Cd, 200 μg L(-1); and C3 Cd, 300 μg L(-1)) and to the three permethrin doses (C1 Perm, 100 μg L(-1); C2 Perm, 150 μg L(-1); and C3 Perm, 200 μg L(-1)) tested. A decrease in CAT was noted in the digestive gland of the H. trunculus exposed to permethrin at the concentration of 200 μg L(-1) during the pre-spawning and post-spawning phases. H. trunculus in post-spawning was more sensitive to cadmium and permethrin than in the pre-spawning phase. The biochemical responses to pollutants (cadmium and permethrin) represented by CAT may act as a biomarker of exposure in this species.