The impact of career customization on work outcomes: Boundary conditions of manager support and employee age

The current paper investigated the longitudinal effects of mass career customization (MCC) on job attitudes and objective career outcomes of employees in a professional service firm in the Netherlands. On the basis of theory on individualization of career trajectories, it was expected that the possibility for employees to customize their careers would be positively related to their job attitudes and subsequent objective career success, as indicated by their levels of affective commitment, work engagement, and received salary and bonuses. However, these effects were expected to occur primarily under the combination of high manager support for implementation of career customization and, on the basis of lifespan theory, older workers, as customization fulfills their increased heterogeneous career preferences. A three‐wave longitudinal study largely showed support for the study hypotheses; the relation between MCC use and work engagement and subsequent career success was stronger for older workers who received support for MCC, whereas the relation between MCC use and commitment was negative for older workers who received low support. The study shows the benefits of career customization in organizations by showing the conditions under which these benefits will manifest. Copyright © 2015 John Wiley & Sons, Ltd.     

Levels and determinants of beta(1-->3)-glucans and fungal extracellular polysaccharides in house dust of (pre-)school children in three European countries

BACKGROUND: Mold growth is believed to be one causative factor underlying the association between dampness in buildings and increased respiratory morbidity. Measurements of beta(1-->3)-glucans and fungal extracellular polysaccharides (EPS) are used as markers of mold exposure in field studies. Little is known about their levels and determinants in homes. OBJECTIVE: To study levels and determinants of beta(1-->3)-glucan and EPS levels in mattress and living room floor dust in three European countries. METHODS: Mattress and living room floor dust was collected in the homes of 1065 German, Dutch, and Swedish (pre-)school children. All samples were analyzed for beta(1-->3)-glucans and EPS in one central laboratory. Determinants were assessed by questionnaire. RESULTS: Amounts of dust, EPS and beta(1-->3)-glucan levels differed between countries. Amounts of dust, beta(1-->3)-glucan and EPS levels for mattresses were only weakly correlated with those for living room floors. Floor dust beta(1-->3)-glucan loads, EPS loads and EPS concentrations were strongly correlated with the amount of dust sampled, which is largely determined by the type of floor that was sampled (carpeted floors had 5-20 higher amounts of dust). None of the other determinants was consistently and statistically significantly associated with amounts of dust, beta(1-->3)-glucan and EPS concentrations on floors and mattresses. CONCLUSION: Mattress dust and floor dust are two different measures of exposure to the investigated mold components. Living room floor beta(1-->3)-glucan and EPS loads and EPS concentrations are largely determined by the type of floor sampled. Differences between countries can only partly be explained by the determinants studied.     

Does your facility have a dust problem: Methods for evaluating dust explosion hazards

The hazards of dust explosions prevailing in plants are dependent on a large variety of factors that include process parameters, such as pressure, temperature and flow characteristics, as well as equipment properties, such as geometry layout, the presence of moving elements, dust explosion characteristics and mitigating measures. A good dust explosion risk assessment is a thorough method involving the identification of all hazards, their probability of occurrence and the severity of potential consequences. The consequences of dust explosions are described as consequences for personnel and equipment, taking into account consequences of both primary and secondary events.While certain standards cover all the basic elements of explosion prevention and protection, systematic risk assessments and area classifications are obligatory in Europe, as required by EU ATEX and Seveso II directives. In the United States, NFPA 654 requires that the design of the fire and explosion safety provisions shall be based on a process hazard analysis of the facility, process, and the associated fire or explosion hazards. In this paper, we will demonstrate how applying such techniques as SCRAM (short-cut risk analysis method) can help identify potentially hazardous conditions and provide valuable assistance in reducing high-risk areas. The likelihood of a dust explosion is based on the ignition probability and the probability of flammable dust clouds arising. While all possible ignition sources are reviewed, the most important ones include open flames, mechanical sparks, hot surfaces, electric equipment, smoldering combustion (self-ignition) and electrostatic sparks and discharges. The probability of dust clouds arising is closely related to both process and dust dispersion properties.Factors determining the consequences of dust explosions include how frequently personnel are present, the equipment strength, implemented consequence-reducing measures and housekeeping, as risk assessment techniques demonstrate the importance of good housekeeping especially due to the enormous consequences of secondary dust explosions (despite their relatively low probability). The ignitibility and explosibility of the potential dust clouds also play a crucial role in determining the overall risk.Classes describe both the likelihood of dust explosions and their consequences, ranging from low probabilities and limited local damage, to high probability of occurrence and catastrophic damage. Acceptance criteria are determined based on the likelihood and consequence of the events. The risk assessment techniques also allow for choosing adequate risk reducing measures: both preventive and protective. Techniques for mitigating identified explosions risks include the following: bursting disks and quenching tubes, explosion suppression systems, explosion isolating systems, inerting techniques and temperature control. Advanced CFD tools (DESC) can be used to not only assess dust explosion hazards, but also provide valuable insight into protective measures, including suppression and venting.     

New characterisation method of electrical and electronic equipment wastes (WEEE)

Innovative separation and beneficiation techniques of various materials encountered in electrical and electronic equipment wastes (WEEE) is a major improvement for its recycling. Mechanical separation-oriented characterisation of WEEE was conducted in an attempt to evaluate the amenability of mechanical separation processes. Properties such as liberation degree of fractions (plastics, metals ferrous and non-ferrous), which are essential for mechanical separation, are analysed by means of a grain counting approach. Two different samples from different recycling industries were characterised in this work. The first sample is a heterogeneous material containing different types of plastics, metals (ferrous and non-ferrous), printed circuit board (PCB), rubber and wood. The second sample contains a mixture of mainly plastics. It is found for the first sample that all aluminium particles are free (100%) in all investigated size fractions. Between 92% and 95% of plastics are present as free particles; however, 67% in average of ferromagnetic particles are liberated. It can be observed that only 42% of ferromagnetic particles are free in the size fraction larger than 20 mm. Particle shapes were also quantified manually particle by particle. The results show that the particle shapes as a result of shredding, turn out to be heterogeneous, thereby complicating mechanical separation processes. In addition, the separability of various materials was ascertained by a sink–float analysis and eddy current separation. The second sample was separated by automatic sensor sorting in four different products: ABS, PC–ABS, PS and rest product. The fractions were characterised by using the methodology described in this paper. The results show that the grade and liberation degree of the plastic products ABS, PC–ABS and PS are close to 100%. Sink–float separation and infrared plastic identification equipment confirms the high plastic quality. On the basis of these findings, a global separation flow sheet is proposed to improve the plastic separation of WEEE.     

Anammox: an option for ammonium removal in bioreactor landfills

Experiments carried out in bioreactor landfill simulators demonstrated that more than 40% of the total N was transferred into the liquid and gas phases during the incubation period of 380 days. Ammonium, an end product of protein degradation and important parameter to consider during landfill closure, tends to accumulate up to inhibitory levels in the leachate of landfills especially in landfills with leachate recirculation. Most efforts to remove ammonium from leachate have been focused on ex situ and partial in situ methods such as nitrification, denitrification and chemical precipitation. Besides minimal contributions from other N-removal processes, Anammox (Anaerobic Ammonium Oxidation) bacteria were found to be active within the simulators. Anammox is considered to be an important contributor to remove N from the solid matrix. However, it was unclear how the necessary nitrite for Anammox metabolism was produced. Moreover, little is known about the nature of residual nitrogen in the waste mass and possible mechanisms to remove it. Intrusion of small quantities of O₂ is not only beneficial for the degradation process of municipal solid waste (MSW) in bioreactor landfills but also significant for the development of the Anammox bacteria that contributed to the removal of ammonium. Volatilisation and Anammox activity were the main N removal mechanisms in these pilot-scale simulators. The results of these experiments bring new insights on the behaviour, evolution and fate of nitrogen from solid waste and present the first evidence of the existence of Anammox activity in bioreactor landfill simulators.     

Vehicle routing for the eco-efficient collection of household plastic waste

Plastic waste is a special category of municipal solid waste. Plastic waste collection is featured with various alternatives of collection methods (curbside/drop-off) and separation methods (source-/post-separation). In the Netherlands, the collection routes of plastic waste are the same as those of other waste, although plastic is different than other waste in terms of volume to weight ratio. This paper aims for redesigning the collection routes and compares the collection options of plastic waste using eco-efficiency as performance indicator. Eco-efficiency concerns the trade-off between environmental impacts, social issues and costs. The collection problem is modeled as a vehicle routing problem. A tabu search heuristic is used to improve the routes. Collection alternatives are compared by a scenario study approach. Real distances between locations are calculated with MapPoint. The scenario study is conducted based on real case data of the Dutch municipality Wageningen. Scenarios are designed according to the collection alternatives with different assumptions in collection method, vehicle type, collection frequency and collection points, etc. Results show that the current collection routes can be improved in terms of eco-efficiency performance by using our method. The source-separation drop-off collection scenario has the best performance for plastic collection assuming householders take the waste to the drop-off points in a sustainable manner. The model also shows to be an efficient decision support tool to investigate the impacts of future changes such as alternative vehicle type and different response rates.     

Groundwater Remediation via Marcro Porous Polymer Extraction

Akzo Nobel's Macro Porous Polymer Extraction (MPPE) technology effectively removes dissolved hydrocarbons from groundwater via liquid-liquid extraction with an innovative medium. Excellent performance in removal of chlorinated, aromatic, and aliphatic solvents, coupled with simple, robust design, make MPPE an attractive process for groundwater remediation applications. Hydrocarbon-contaminated water is passed through a column packed with MPPE particles. An extraction fluid, immobilized within the polymer matrix, removes the hydrocarbons from the water. All hydrocarbons with affinity for the extraction fluid (compared to water) are removed. Regeneration is accomplished in situ with low-pressure steam. The steam volatilizes the hydrocarbons but not theimmobilized extraction fluid. Volatilized hydrocarbons are condensed and then separated from condensate by gravity. The hydrocarbon product is available for recycle or reuse. MPPE systems achieve removal efficiencies of 99.99 percent for wide varieties and combinations of aliphatic, aromatic, and chlorinated compounds. For a broad range of mass loadings and effluent requirements, especially rigorous ones, the MPPE system offers lower investment and operating costs than traditional water treatment technologies. Currently, 14 industrial units are running or under construction in the United States and Europe. Eight of these are treating groundwater.     

LCA comparison of windrow composting of yard wastes with use as alternative daily cover (ADC)

This study compared the environmental impacts of composting yard wastes in windrows with using them in place of soil as alternative daily cover (ADC) in landfills. The Life Cycle Assessment was made using the SimaPro LCA software and showed that the ADC scenario is more beneficial for the environment than windrow composting. ADC use is also a less costly means of disposal of yard wastes. This finding applies only in cases where there are sanitary landfills in the area that are equipped with gas collection systems and can use yard wastes as alternative daily cover. Otherwise, the environmentally preferable method for disposal of source-separated yard wastes is composting rather than landfilling.     

Characterisation of major component leaching and buffering capacity of RDF incineration and gasification bottom ash in relation to reuse or disposal scenarios

Thermal treatment of refuse derived fuel (RDF) in waste-to-energy (WtE) plants is considered a promising solution to reduce waste volumes for disposal, while improving material and energy recovery from waste. Incineration is commonly applied for the energetic valorisation of RDF, although RDF gasification has also gained acceptance in recent years. In this study we focused on the environmental properties of bottom ash (BA) from an RDF incineration (RDF-I, operating temperature 850-1000 °C) and a RDF gasification plant (RDF-G, operating temperature 1200-1400 °C), by evaluating the total composition, mineralogy, buffering capacity, leaching behaviour (both at the material’s own pH and as a function of pH) of both types of slag. In addition, buffering capacity results and pH-dependence leaching concentrations of major components obtained for both types of BA were analysed by geochemical modelling. Experimental results showed that the total content of major components for the two types of BA was fairly similar and possibly related to the characteristics of the RDF feedstock. However, significant differences in the contents of trace metals and salts were observed for the two BA samples as a result of the different operating conditions (i.e. temperature) adopted by the two RDF thermal treatment plants. Mineralogy analysis showed in fact that the RDF-I slag consisted of an assemblage of several crystalline phases while the RDF-G slag was mainly made up by amorphous glassy phases. The leached concentrations of major components (e.g. Ca, Si) at the natural pH of each type of slag did not reflect their total contents as a result of the partial solubility of the minerals in which these components were chemically bound. In addition, comparison of total contents with leached concentrations of minor elements (e.g. Pb, Cu) showed no obvious relationship for the two types of BA. According to the compliance leaching test results, the RDF-G BA would meet the limits of the Italian legislation for reuse and the European acceptance criteria for inert waste landfilling. RDF-I BA instead would meet the European acceptance criteria for non hazardous waste landfilling. A new geochemical modelling approach was followed in order to predict the leaching behaviour of major components and the pH buffering capacity of the two types of slags on the basis of independent mineralogical information obtained by XRD analysis and the bulk composition of the slag. It was found that the combined use of data regarding the mineralogical characterization and the buffering capacity of the slag material can provide an independent estimate of both the identity and the amount of minerals that contribute to the leaching process. This new modelling approach suggests that only a limited amount of the mineral phases that control the pH, buffering capacity and major component leaching from the solid samples is available for leaching, at least on the time scale of the applied standard leaching tests. As such, the presented approach can contribute to gain insights for the identification of the types and amounts of minerals that control the leaching properties and pH buffering capacity of solid residues such as RDF incineration and gasification bottom ash.