Review and assessment of models for predicting the migration of radionuclides from catchments

The present paper summarises the results of the review and assessment of models developed for predicting the migration of radionuclides from catchments to water bodies. The models were classified and evaluated according to their main methodological approaches. A retrospective analysis of the principles underpinning the model development in relation to experimental finding and results was carried out. It was demonstrated that most of the various conceptual approaches of different modellers can be integrated in a general, harmonised perspective supported by a variety of experimental evidences. Shortcomings and advantages of the models were discussed.     

Equity and sustainability over the next fifty years: An exercise in economic visioning

A simplistic aggregate model of global economic activity supports a 50-year visioning exercise with targets defined in terms of aggregate measures of global equity (convergence) and sustainability (contraction). Some ambitious combinations of these targets turn out to be infeasible even under the most favorable modeling assumptions. No contraction target (no reduction in fossil fuel consumption relative to the present) was possible, for example, if international capital transfers pushed per capita incomes in low-income countries above 33% of levels achieved in high-income countries. Lower prices for renewable alternatives to exhaustible resources generally made sustainability targets easier to achieve, but lower prices for renewable resources also made equity targets more difficult to achieve. Improved substitution between capital and labor made equity targets easier to achieve in relative terms, but improved substitution between capital and labor could make any given sustainability target more or less difficult to achieve. All the results suggest that it is possible to overstate the purported conflict between achieving sustainability and equity targets. The very transfers of international capital that would promote relative equity between high-income and low-income countries could also work to spread the incidence of achieving any sustainability target more evenly across their boundaries.Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.     

Primary and secondary organic winter aerosols in Mediterranean cities under different mixing layer conditions (Barcelona and Granada)

Environmental Science and Pollution Research - PM10 was collected during an EMEP winter campaign of 2017–2018 in two urban background sites in Barcelona (BCN) and Granada (GRA), two...     

A novel survey of raptor collections in Europe and their potential to provide samples for pan-European contaminant monitoring

Environmental Science and Pollution Research - This paper provides a novel survey of current collections of frozen raptor carcasses and tissue samples in natural history museums (NHMs),...     

Isotopic fractionation between seawater and the shell of <Emphasis Type="Italic">Scrobicularia plana</Emphasis> (Bivalvia) and its application for age validation

This study analyzed the isotopic profiles of four aragonitic shells of Scrobicularia plana in conjunction with measured seawater temperatures and salinities. Comparison of δ¹⁸O_SHELL with expected values revealed fractionation of δ¹⁸O in near equilibrium with the ambient environment. Growth cessation occurred between November and March. Carbonate deposition stopped when temperatures were <12°C. Analysis of δ¹³C_SHELL values suggested that carbon in the shell does not reflect the DIC in ambient water, likely due to the incorporation of metabolic carbon. An ontogenetic trend of increasing δ¹³C values over time was observed, likely related to changes in metabolic activity. Annual growth patterns were inferred from δ¹⁸O_SHELL profiles and compared with internal and external growth lines. Estimations of age based on external lines were unreliable, resulting in overestimation of age and underestimation of growth rates, likely due to the disturbance lines being wrongly identified as annual. Analysis of internal lines may lead to over- or underestimation of age and was more reliable in recent portions of the shell.     

Drivers of freelance career success

Recent evidence shows that the frequently proclaimed collapse of the traditional career model is actually not supported by job tenure data. This paper argues that the observed stability of job tenure might be explained by an increasing number of shamrock organizations. This organizational form has three types of workers: core employees, professional freelancers, and routine workers. In such an organization, two very different career models coexist. The organization largely determines the career of the core employee, whereas the individual essentially shapes that of the professional freelancer. This paper studies extensively the career of this second group: the professional freelancer, a growing phenomenon in many developed countries but not yet the focus of many career studies. We develop a freelance career success model on basis of the intelligent career framework augmented by insights from literature on entrepreneurship. Data are from a web survey with responses from about 1600 independent professionals in the Netherlands, in combination with 51 in‐depth interviews. We provide two main contributions. First, we report findings from the first large‐scale quantitative study into freelance career success. Second, this study enhances our understanding of the success of the modern career by building bridges between career and entrepreneurship literatures. We conclude that the external environment in which an individual freelancer operates is the most important factor determining career success. The study therefore suggests that more work needs to be performed on the relationship between the environment and individual career success. Copyright © 2012 John Wiley & Sons, Ltd.     

Blast phenomena in urban tunnel systems

Traffic infrastructure in urbanised areas is increasingly projected in tunnels underground or covered over, these days. A consequence is that in case of an incident with hazardous materials the safety level for fellow road users in tunnels is considerably less than it is in surface infrastructure. To reduce the consequences of incidents for fellow tunnel users, urban tunnels are sometimes interrupted by open spaces of limited length. Open spaces allow, for instance, the release of smoke in case of a fire. In this way, possible lethal effects are limited to the tunnel section in which the incident occurred. To what extent an open space may also be effective in the mitigation of blast effects from an explosion in a tunnel system is subject of this paper.

To this end, the blast effects originating from the rupture of a 50 m³ LPG pressure vessel in an urban tunnel system have been computed by numerical simulation. The results show that an open space in a tunnel system has a significant mitigating effect on the blast effects indeed. However, as a consequence of the ingress of a high-velocity jet flow that follows on a primary blast wave, a second blast wave develops in the tunnel section following on an open space. The strength of this second blast wave is not very dependent on the length of the open space. It shows that an open space in a tunnel system may not always limit the lethal effects of explosion incidents in tunnels to the tube in which the incident occurred. The second blast wave in the tunnel section following on an open space may have lethal consequences for fellow tunnel users by car window failure.     

The impact of career customization on work outcomes: Boundary conditions of manager support and employee age

The current paper investigated the longitudinal effects of mass career customization (MCC) on job attitudes and objective career outcomes of employees in a professional service firm in the Netherlands. On the basis of theory on individualization of career trajectories, it was expected that the possibility for employees to customize their careers would be positively related to their job attitudes and subsequent objective career success, as indicated by their levels of affective commitment, work engagement, and received salary and bonuses. However, these effects were expected to occur primarily under the combination of high manager support for implementation of career customization and, on the basis of lifespan theory, older workers, as customization fulfills their increased heterogeneous career preferences. A three‐wave longitudinal study largely showed support for the study hypotheses; the relation between MCC use and work engagement and subsequent career success was stronger for older workers who received support for MCC, whereas the relation between MCC use and commitment was negative for older workers who received low support. The study shows the benefits of career customization in organizations by showing the conditions under which these benefits will manifest. Copyright © 2015 John Wiley & Sons, Ltd.