• PANI/Ti(OH)n(4–n)+ exhibited excellent adsorption capacity and reusability.• Adsorption sites of Cr(VI) were hydroxyl, amino/imino group and benzene rings.• Sb(V) was adsorbed mainly through hydrogen bonds and Ti-O-Sb.• The formation of Cr-O-Sb in dual system demonstrated the synergistic adsorption.• PANI/TiO2 was a potential widely-applied adsorbent and worth further exploring. Removal of chromium (Cr) and antimony (Sb) from aquatic environments is crucial due to their bioaccumulation, high mobility and strong toxicity. In this work, a composite adsorbent consisting of Ti(OH)n(4–n)+ and polyaniline (PANI) was designed and successfully synthesized by a simple and eco-friendly method for the uptake of Cr(VI) and Sb(V). The synthetic PANI/TiO2 composites exhibited excellent adsorption capacities for Cr(VI) and Sb(V) (394.43 mg/g for Cr(VI) and 48.54 mg/g for Sb(V)), wide pH applicability and remarkable reusability. The adsorption of Cr(VI) oxyanions mainly involved electrostatic attraction, hydrogen bonding and anion-π interactions. Based on X-ray photoelectron spectroscopy and FT-IR analysis, the adsorption sites were shown to be hydroxyl groups, amino/imino groups and benzene rings. Sb(V) was adsorbed mainly through hydrogen bonds and surface complexation to form Ti-O-Sb complexes. The formation of Cr-O-Sb in the dual system demonstrated the synergistic adsorption of Cr(VI) and Sb(V). More importantly, because of the different adsorption sites, the adsorption of Cr(VI) and Sb(V) occurred independently and was enhanced to some extent in the dual system. The results suggested that PANI/TiO2 is a promising prospect for practical wastewater treatment in the removal of Cr(VI) and Sb(V) from wastewater owing to its availability, wide applicability and great reusability. 相似文献
Robust decision making, a growing approach to infrastructure planning under climate change uncertainty, aims to evaluate infrastructure performance across a wide range of possible conditions and identify the most robust strategies and designs. Robust decision making seeks to find potential weaknesses in systems in order to gird these through a combination of policy, infrastructure, and, in some cases, resilient or recovery strategies. A system can be explored by simulating many combinations of uncertain climatic and economic parameters; statistical clustering can identify parameter thresholds that lead to unacceptable performance. Often, however, uncertain variables are correlated, complicating the robustness analysis and casting doubt upon the thresholds identified. Here, we evaluate the impact of ordinary, hidden correlations in uncertainty parameters that drive simulation in robust decision making. We induced correlations between temperature and key climatic and economic parameters. We tested correlations of 0%, 30%, 60%, and 90% between temperature and the absolute value of precipitation, coefficient of variation, and downward surface solar radiation, and negative correlations between temperature and net variable benefit and the discount rate. We used a calibrated simulation model of a dam system regulating Lake Tana, Ethiopia, to compute the agricultural supply and net present value of the reservoirs. As the correlation strength increased, the results converged in a smaller region. We found that strong correlations depressed robustness scores of lower-performing alternatives and conversely increased results of the higher-performing alternatives. As the correlations increased in favorable alternatives, the failure thresholds became more extreme, speciously suggesting that only intense changes would result in poor performance. This overall analysis highlights the degree to which correlations of an interconnected climatic and economic system can impact outcomes of robust decision making and suggests methods to avoid confounding results.
Environmental Science and Pollution Research - The hydrolysis and photolysis of the chiral fungicide mandipropamid were investigated, and the potential enantioselectivity of mandipropamid in... 相似文献
• RED performance and stack resistance were studied by EIS and LSV.• Interface resistance were discriminated from Ohmic resistance by EIS.• Impacts of spacer shadow effect and concentration polarization were analyzed.• Ionic short current reduced the power density for more cell pairs.• The results enabled to predict RED performance with different configurations. Reverse electrodialysis (RED) is an emerging membrane-based technology for the production of renewable energy from mixing waters with different salinities. Herein, the impact of the stack configuration on the Ohmic and non-Ohmic resistances as well as the performance of RED were systematically studied by using in situ electrochemical impedance spectroscopy (EIS). Three different parameters (membrane type, number of cell pairs and spacer design) were controlled. The Ohmic and non-Ohmic resistances were evaluated for RED stacks equipped with two types of commercial membranes (Type I and Type II) supplied by Fujifilm Manufacturing Europe B.V: Type I Fuji membranes displayed higher Ohmic and non-Ohmic resistances than Type II membranes, which was mainly attributed to the difference in fixed charge density. The output power of the stack was observed to decrease with the increasing number of cell pairs mainly due to the increase in ionic shortcut currents. With the reduction in spacer thickness from 750 to 200 µm, the permselectivity of membranes in the stack decreased from 0.86 to 0.79 whereas the energy efficiency losses increased from 31% to 49%. Overall, the output of the present study provides a basis for understanding the impact of stack design on internal losses during the scaling-up of RED. 相似文献
Microbial remediation, especially the application of probiotics, has recently gained popularity in improving water quality and maintaining aquatic animal health. The efficacy and mechanism of mixed Bacillus for improvement of water quality and its effects on aquatic microbial community structure remain unknown. To elucidate these issues, we applied two groups of mixed Bacillus (Bacillus megaterium and Bacillus subtilis (A0?+?BS) and Bacillus megaterium and Bacillus coagulans (A0?+?BC)) to the aquaculture system of Crucian carp. Our results showed that the improvement effect of mixed Bacillus A0?+?BS on water quality was better than that of A0?+?BC, and the NH4+-N, NO2?-N, NO3?-N, and total phosphorus (TP) concentrations were reduced by 46.3%, 76.3%, 35.6%, and 80.3%, respectively. In addition, both groups of mixed Bacillus increased the diversity of the bacterial community and decreased the diversity of the fungal community. Microbial community analysis showed that mixed Bacillus A0?+?BS increased the relative abundance of bacteria related with nitrogen and phosphorus removal, such as Proteobacteria, Actinobacteria, Comamonas, and Stenotrophomonas, but decreased the relative abundance of pathogenic bacteria (Acinetobacter and Pseudomonas) and fungi (Epicoccum and Fusarium). Redundancy analysis showed that NH4+-N, NO2?-N, and TP were the primary environmental factors affecting the microbial community in aquaculture water. PICRUST analysis indicated that all functional pathways in the A0?+?BS group were richer than those in other groups. These results indicated that mixed Bacillus A0?+?BS addition produced good results in reducing nitrogenous and phosphorus compounds and shaped a favorable microbial community structure to further improve water quality.
