Comparison of biochar- and activated carbon-supported zerovalent iron for the removal of Se(IV) and Se(VI): influence of pH,ionic strength,and natural organic matter

Biochar (BC) and activated carbon (AC) were both produced from corn straw. Biochar-supported zerovalent iron (BC-ZVI) and activated carbon-supported zerovalent iron (AC-ZVI) were synthesized and applied for Se(IV)/Se(VI) removal. The sorption capacity of BC-ZVI for Se(IV) and Se(VI) was reported at 62.52 and 35.39 mg g^?1, higher than that of AC-ZVI (56.02 and 33.24 mg g^?1), respectively, due to its higher iron content and more positive charges. The spectroscopic analyses showed that Se(IV)/Se(VI) were reduced to Se(0)/Se(-II) of less toxicity and solubility. The effects of various factors such as pH, ionic strength, co-existing cations and anions, and natural organic matter (NOM) were also investigated. Ionic strength showed no significant effect on Se(IV)/Se(VI) removal, but pH was critical. The presence of NO₃^? and SO₄^2? did not cause obvious inhibition to the removal, while PO₄^3? inhibited the sorption capacity of BC-ZVI and AC-ZVI for Se(IV)/Se(VI) significantly. Common cations (K⁺, Ca²⁺, and Mg²⁺) were found to slightly enhance the removal, while NOM significantly decreased the sorption capacity of BC-ZVI and AC-ZVI for Se(IV)/Se(VI). Besides, NOM showed stronger inhibition effect on AC-ZVI than that on BC-ZVI. These results indicated that BC-ZVI, compared with AC-ZVI, could be a promising sorbent to remove Se(IV)/Se(VI) due to its low cost and high efficiency.

     

Amelioration of toxicopathological effects of cadmium with silymarin and milk thistle in male Japanese quail (Coturnix japonica)

Environmental Science and Pollution Research - Cadmium is an important widely distributed heavy metal in the environment due to its several industrial uses, while milk thistle is an important herb...     

Is Globalization Detrimental to CO<Subscript>2</Subscript> Emissions in Japan? New Threshold Analysis

Using annual data from 1970 to 2014, this paper examines the effects of globalization on CO₂ emissions in Japan while accounting for economic growth and energy consumption as potential determinants of carbon emissions. The structural breaks and asymmetries arising due to policy shifts require attention, and hence, an asymmetric threshold version of the ARDL model is utilized. The results show the presence of threshold asymmetric cointegration between variables. Threshold-based positive and negative shocks arising from globalization increase carbon emissions, while the impact of the latter is more profound. Energy consumption (economic growth) also has a significant positive effect on carbon emissions. Globalization, economic growth, and energy consumption significantly increase carbon emissions in the short run. We suggest that policy makers in Japan consider globalization and energy consumption as policy tools in formulating their policies regarding protecting sustainable environmental quality in the long run. Otherwise, the Japanese economy may continue to face environmental consequences such as undesirable climate change and massive warming at the micro and macro levels as a result of potential shocks arising from globalization and energy consumption.     

Metal accumulation in Raphanus sativus and Brassica rapa: an assessment of potential health risk for inhabitants in Punjab,Pakistan

Pakistan is an agricultural country and due to the shortage of clean water, most of the irrigated area (32,500 ha) of Pakistan was supplied with wastewater (0.876?×?109 m³/year). Concentrations of heavy metals in radish (Raphanus sativus) and turnip (Brassica rapa) taken from vegetable fields in Sargodha, Pakistan, were measured. Untreated wastewater was used persistently for a long time to irrigate these vegetable fields. A control site was selected that had a history of fresh groundwater irrigation. Mean metal concentrations were found for irrigation water, soil, and vegetables. In irrigation water, concentrations of Mo and Pb at three sites and Se at sites II and III were higher than the recommended limits. In vegetables, concentrations of Mo and Pb were above the maximum permissible limits. High bioconcentration factor was observed for Zn (12.61 in R. sativus and 11.72 in B. rapa) at site I and high pollution load index was found for Pb (3.89 in R. sativus and 3.87 in B. rapa) at site II. The differences in metal concentrations found in samples depended upon different soil nature and assimilation capacities of vegetables at different sites which in turn depended upon different environmental cues. The entrance of metal and metalloids to human body may happen through different pathways; however, the food chain is the chief route through which metals are transferred from vegetables to individuals. Health risk index observed for metals, (Mo, As, Ni, Cu, and Pb) higher than 1 indicated high risk through consumption of these vegetables at three sites.

     

Impact of climate factors on cyanobacterial dynamics and their interactions with water quality in South Taihu Lake,China

Cyanobacterial bloom events in South Taihu Lake cause serious water quality problems and disturb aesthetic view of lake’s environment. In this study, correlations between cyanobacterial blooms and hydro-meteorological factors, including water quality, temperature and precipitation were investigated. Results demonstrated that South Taihu Lake was heavily affected by cyanobacteria and the proliferation of cyanobacteria due to variations in hydro-meteorological factors and water quality conditions. Water quality parameters, including COD, NH₃-N, TN and TP improved significantly since 2008 even at an elevated cyanobacterial bloom situation. Correlation analyses have shown that the development of cyanobacterial density and chlorophyll a concentration was sensitive to a wider temperature variation. The optimum temperature for cyanobacteria was 20°C, while extremely low and high temperatures were found to suppress their growth. Moreover, unusual rainfall patterns were measured during the study period (2003–2009), which showed an adverse impact on cyanobacterial development. Findings from this study suggested that seasonal lake’s water quality monitoring; suitable treatment of cyanobacterial blooms and strict policy implementation can solve the water quality issues in highly eutrophic lakes like Taihu.     

PTFE-coated non-stick cookware and toxicity concerns: a perspective

PTFE is used as an inner coating material in non-stick cookware. This unique polymer coating prevents food from sticking in the pans during the cooking process. Such cookware is also easy to wash. At normal cooking temperatures, PTFE-coated cookware releases various gases and chemicals that present mild to severe toxicity. Only few studies describe the toxicity of PTFE but without solid conclusions. The toxicity and fate of ingested PTFE coatings are also not understood. Moreover, the emerging, persistent, and well-known toxic environmental pollutant PFOA is also used in the synthesis of PTFA. There are some reports where PFOA was detected in the gas phase released from the cooking utensils under normal cooking temperatures. Due to toxicity concerns, PFOA has been replaced with other chemicals such as GenX, but these new alternatives are also suspected to have similar toxicity. Therefore, more extensive and systematic research efforts are required to respond the prevailing dogma about human exposure and toxic effects to PTFE, PFOA, and GenX and other alternatives.     

Chemical speciation and bioavailability of rare earth elements (REEs) in the ecosystem: a review

Rare earths (RE), chemically uniform group of elements due to similar physicochemical behavior, are termed as lanthanides. Natural occurrence depends on the geological circumstances and has been of long interest for geologist as tools for further scientific research into the region of ores, rocks, and oceanic water. The review paper mainly focuses to provide scientific literature about rare earth elements (REEs) with potential environmental and health effects in understanding the research. This is the initial review of RE speciation and bioavailability with current initiative toward development needs and research perceptive. In this paper, we have also discussed mineralogy, extraction, geochemistry, analytical methods of rare earth elements. In this study, REEs with their transformation and vertical distribution in different environments such as fresh and seawater, sediments, soil, weathering, transport, and solubility have been reported with most recent literature along key methods of findings. Speciation and bioavailability have been discussed in detail with special emphasis on soil, plant, and aquatic ecosystems and their impacts on the environment. This review shows that REE gained more importance in last few years due to their detrimental effects on living organisms, so their speciation, bioavailability, and composition are much more important to evaluate their health risks and are discussed thoroughly as well.     

Characteristics of volatile compound emission and odor pollution from municipal solid waste treating/disposal facilities of a city in Eastern China

Transfer station, incineration plant, and landfill site made up the major parts of municipal solid waste disposal system of S city in Eastern China. Characteristics of volatile compounds (VCs) and odor pollution of each facility were investigated from a systematic perspective. Also major index related to odor pollution, i.e., species and concentration of VCs, olfactory odor concentration, and theoretic odor concentration, was quantified. Oxygenated compounds and hydrocarbons were the most abundant VCs in the three facilities. Different chemical species were quantified, and the following average concentrations were obtained: transfer station, 54 VCs, 2472.47 μg/m³; incineration plant, 75 VCs, 33,129.25 μg/m³; and landfill site, 71 VCs, 1694.33 μg/m³. Furthermore, the average olfactory odor concentrations were 20,388.80; 50,677.50; and 4951.17, respectively. The highest odor nuisance was detected in the waste tipping port of the incineration plant. A positive correlation between the olfactory and chemical odor concentrations was found with R ² = 0.918 (n = 15, P < 0.01). The result shows odor pollution risk transfer from landfill to incineration plant when adopting thermal technology to deal with the non-source-separated waste. Strong attention thus needs to be paid on the enclosed systems in incineration plant to avoid any accidental odor emission.

     

Bacillus safensis with plant-derived smoke stimulates rice growth under saline conditions

Environmental Science and Pollution Research - Salinity is a worldwide environmental problem of agricultural lands. Smoke and plant growth-promoting bacteria (PGPR) are individually used to improve...