A Combustion Method for the Determination of Solvent Vapors at Low Concentrations in Air

The nitrogen-containing products of smog chamber reactions have been the subject of much controversy. Concern has arisen over nitrogen products because of the almost universally poor nitrogen balance reported for irradiated mixtures of hydrocarbons and nitrogen oxides. Some possible nitrogen-containing products, such as molecular nitrogen, nitrous oxide, and nitroolefins have been investigated and shown to be unimportant. The nitrogen products most often measured are peroxyacetyl nitrate and residual nitrogen dioxide. These two products rarely comprise more than 70% of the initial nitrogen at the end of an experiment, and often account for less than 50%. Previous experiments in which total nitrate was determined in the gas phase and on the vessel walls at the end of irradiation have shown very good nitrogen balances. The assumption has been made that the nitrate arises from nitric acid formed on the walls by adsorbed N₂O₅.

In the work reported here, all major nitrogen-containing compounds have been monitored continuously for the first time. Nitric oxide and nitrogen dioxide have been monitored by chemilumines-cence and automated Saltzman techniques. Methyl, ethyl, and peroxyacetyl nitrate have been determined by gas chromatogra-phy. Two methods, one continuous and one integrated, have been specially developed to measure nitric acid both in the smog chambers and in the atmosphere. Continuous determination of these compounds yields good nitrogen balances throughout the irradiations.

Profiles of the nitrogen-containing species from irradiated HC/ NO_x mixtures are discussed in terms of nitrogen products and nitrogen balance. Differences in product distribution for different hydrocarbon systems are also considered. Using rate information from the nitrogen compound profiles, important reactions leading to nitrogen-containing products are identified. Interference with the chemiluminescent technique by HON0₂, PAN, and C₂H₅ONO₂ is discussed.     

Projected Freshwater Withdrawals Under Efficiency Scenarios for Electricity Generation and Municipal Use in the United States for 20301

Chen, Limin, Sujoy B. Roy, and Robert A. Goldstein, 2012. Projected Freshwater Withdrawals Under Efficiency Scenarios for Electricity Generation and Municipal Use in the United States for 2030. Journal of the American Water Resources Association (JAWRA) 1‐16. DOI: 10.1111/jawr.12013 Abstract: Water withdrawals in the United States (U.S.) have been relatively uniform over the past two decades on a nationally aggregated basis, although on a more highly resolved geographical basis, increases have occurred, largely associated with growth in population and the cooling needs for new electricity generation. Using recent county‐level water use data, we develop projections for five different scenarios, bracketing a range of future conditions, and representing different levels of efficiency in the municipal and electricity generation sectors, where the municipal sector includes public and self‐supplied domestic withdrawals. Starting with the 2005 estimate of 347 billion gallons per day (bgd) of freshwater withdrawal in the continental U.S., our analysis shows that under a business‐as‐usual scenario of growth, there will be a need for additional water over current levels: 11 bgd in the municipal sector, with a smaller requirement for new electricity generation (1 bgd). However, we also estimate that withdrawals could be reduced significantly over current levels, through increased water use efficiencies in the electric power and municipal sectors. The study shows that if water withdrawals are to be held at their current levels for the thermoelectric and municipal sectors individually at a county level over the next 25 years, large improvements in efficiency will be needed in many parts of the Southeast and Southwest.     

Congenital cervical teratoma,associated with agenesis of corpus callosum and a subarachnoid cyst

Cervical teratoma is a neoplasm composed of embryonic tissues with representation of all three germ layers. We report an extremely rare case of fetal cervical teratoma presenting at 24 weeks of gestation. A submaxillary mass and agenesis of corpus callosum were identified on ultrasonography, associated with agenesis of corpus callosum and a subarachnoid cyst. Copyright © 2005 John Wiley & Sons, Ltd.     

Monitoring of methylene blue monomers and dimers to control the bacterialogical water quality including application to photocatalysis

Environmental Science and Pollution Research - In this study, we propose the development of a rapid and reliable method to control and to monitor microbial water quality. The methylene blue (MB)...     

A review of the public health impacts of unconventional natural gas development

The public health impact of hydraulic fracturing remains a high profile and controversial issue. While there has been a recent surge of published papers, it remains an under-researched area despite being possibly the most substantive change in energy production since the advent of the fossil fuel economy. We review the evidence of effects in five public health domains with a particular focus on the UK: exposure, health, socio-economic, climate change and seismicity. While the latter would seem not to be of significance for the UK, we conclude that serious gaps in our understanding of the other potential impacts persist together with some concerning signals in the literature and legitimate uncertainties derived from first principles. There is a fundamental requirement for high-quality epidemiological research incorporating real exposure measures, improved understanding of methane leakage throughout the process, and a rigorous analysis of the UK social and economic impacts. In the absence of such intelligence, we consider it prudent to incentivise further research and delay any proposed developments in the UK. Recognising the political realities of the planning and permitting process, we make a series of recommendations to protect public health in the event of hydraulic fracturing being approved in the UK.