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Kinetics and isotherms of Triton X-100 sorption on soil,base-extracted soil(BE),humic acid (HA) and humin (HM) were investigated respectively to get better understanding on characteristics of the surfactant sorptiun onto different soil organic matters(SOMs).It was demonstrated that the kinetics results could be satisfactorily described by the pseudo-second order model.The half of the time to reach equilibrium(t1/2) for different sorbents followed the sequence of soil>HA>BE>HM.Furthermore,the calculated equilibrium sorption capacity(Ceq) was found in the sequence of HA>BE>HM>soil,which agreed well with the experimental results.The isotherms of Triton X-100 sorption on soil and HA could be well described by the S-type isotherm,but BE and HM by the L-type.The isotherms of all the four sorbents were found reasonably fitted to the Langmuir equation.The Kd value,defined as the ratio of Triton X-100 in sorbent and in the equilibrium solution for given concentrations,generally followed the order of HM>HA>soil>BE.Separated HM and HA showed high affinity for Triton X-100,but the HA and HM in soil and BE were tightly bounded by the minerals.Thus,the HA on the soil surface might dominate the sorption,whereas the bounded HM would play a key role upon the surfactants being penetrated inside the soil. 相似文献
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合成氨-尿素生产建设项目环境风险评价 总被引:2,自引:1,他引:1
环境风险评价是化工建设项目环境影响评价的重要内容。以合成氨-尿素生产为例,按照环境风险评价技术导则的程序和方法进行化工项目环境风险识别和源项分析,指出液氨储罐燃烧爆炸、储罐或阀门破裂液氨泄漏、中压氨罐火灾爆炸及中压氨罐泄漏是合成氨-尿素生产中的重要风险事故,并利用多烟团模式对液氨储罐燃爆和泄漏两项最严重风险事故进行风险影响分析和最大风险值计算,结果表明,该项目事故风险最大值小于化工行业风险统计值,并提出事故风险的防范措施和对策。 相似文献
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尾矿库渗滤液中污染物会对区域地下水产生不利影响。根据拟建工程场地水文地质条件和气象资料,建立三维数值预测模型并分析非正常工况下两种典型污染情景对地下水环境的影响,预测结果显示:特征污染物As的质量浓度随时间推移逐渐变大;防渗层破损和无防渗情况下污染晕沿地下水流方向最远运移距离在第100 d、1 000 d、7 884 d时分别为72 m、225 m、262 m和78 m、335 m、391 m。由于下游河流及周边泉点为区内地下水排泄主要途径,污染物经排泄进入下游河流将对环境造成较大影响,故提出相应防范措施。 相似文献
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针对当前农村生活污水低碳氮比现状和处理难题,研发了拥有自主知识产权的MFBR泥膜共生污水处理工艺,并形成了一套分散式农村生活污水处理一体化设备,该设备集缺氧池、厌氧池、移动床曝气池、固定床曝气池及沉淀池于一体。研究考察了MFBR一体化设备用于处理湖南省某村庄生活污水的性能,结果表明:稳定运行后出水水质均达到《城镇污水处理厂污染物排放标准》(GB 18918—2002)一级A标,运行成本根据处理量在0.25~0.4元/m3。该设备可根据项目要求增减化学除磷系统,设备结构简单,运行成本低,对低碳氮比的生活污水处理效率高。 相似文献
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Study on pyrolysis and gasification of wood in MSW 总被引:4,自引:1,他引:3
NI Ming-jiang XIAO Gang CHI Yong YAN Jian-hu MIAO Qi ZHU Wen-li CEN Ke-fa 《环境科学学报(英文版)》2006,18(2):407-415
In order to develop municipal solid waste(MSW) pyrolysis/gasification and melting technology with low emission and high efficiency, it was planed that all the main components in MSW and some typical kinds of MSW were pyrolyzed/gasified to propose an expert system for raw MSW. In this paper, wood, which was a prevalent component in MSW, was pyrolyzed and gasified in fluidized-bed reactors at different apparent excess air ratios (EARs), temperatures and fluidizing velocities. For pyrolysis, with tem- perature increasing from 400℃ to 700℃, the yield of pyrolysis char decreased while that of pyrolysis gas increased (in this paper respectively from 28% to 20% and from 10% to 35%), and when temperature was 500℃, the yield of pyrolysis tar reached the highest, up to 38% in this paper. It was the optimum for gasification when temperature was 600℃ and apparent EAR was 0.4. Under the experimental conditions of this paper, gasification efficiency achieved 73%, lower heat value(LHV) reached 5800 kJ/(Nm^3) and yield of syngas was 2.01 Nm^3/kg. Lower fluidizing velocity was useful to upgrade gasification efficiency and LHV of syngas for wood gasification. Based on the results, the reactive courses and mechanism were analyzed respectively for wood pyrolysis and gasification. 相似文献