北黄海北部海域潮余流的模拟研究

基于二维水动力模型,在仅考虑潮流作用条件下,通过计算欧拉余流和拉格朗日余流并结合粒子追踪方法研究了辽宁大连—朝鲜龙渊郡连线北侧的北黄海北部海域的潮余流结构和粒子运移的趋势。结果表明:欧拉余流和拉格朗日余流流速整体较小,呈现由南向北的流向,但在獐子岛及长山群岛的附近岛屿和朝鲜半岛沿岸的海域欧拉余流和拉格朗日余流流速较大。对比粒子追踪计算的结果与欧拉余流和拉格朗日余流的结果表明,流向与粒子运移路径基本一致。该海湾的余流及粒子运动规律特点对辽东半岛东岸及朝鲜半岛西侧海域的排污及污染控制有重要的借鉴意义。     

Climatic Controls on Watershed Reference Evapotranspiration Varied during 1961–2012 in Southern China

Reference evapotranspiration (ET_o) is an important hydrometeorological term widely used in understanding and projecting the hydrological effects of future climate and land use change. We conducted a case study in the Qinhuai River Basin that is dominated by a humid subtropical climate and mixed land uses in southern China. Long‐term (1961–2012) meteorological data were used to estimate ET_o by the FAO‐56 Penman–Monteith model. The individual contribution from each meteorological variable to the trend of ET_o was quantified. We found basin‐wide annual ET_o decreased significantly (p < 0.05) by 3.82 mm/yr during 1961–1987, due to decreased wind speed, solar radiation, vapor pressure deficit (VPD), and increased relative humidity (RH). However, due to the increased VPD and decreased RH, the ET_o increased significantly (p < 0.05) in spring, autumn, and annually at a rate of 2.55, 0.56, and 3.16 mm/yr during 1988–2012, respectively. The aerodynamic term was a dominant factor controlling ET_o variation in both two periods. We concluded the key climatic controls on ET_o have shifted as a result of global climate change during 1961–2012. The atmospheric demand, instead of air temperature alone, was a major control on ET_o. Models for accurately predicting ET_o and hydrological change under a changing climate must include VPD in the study region. The shifts of climatic control on the hydrological cycles should be considered in future water resource management in humid regions.     

市场导向的绿色技术创新机理与对策研究

基于对绿色技术创新的特殊属性、企业绿色技术创新环境和驱动力的转变分析,给出了市场导向对企业绿色技术创新的驱动机理。研究发现,企业绿色技术创新具有进度紧迫性、社会实用性、市场导向性及双重外部性等特殊属性,需借助市场机制来驱动企业绿色技术创新投入。市场导向下的企业绿色技术创新,就是要借助市场机制来优化企业绿色技术创新要素的配置效率。其中,市场供求机制有利于释放绿色技术创新要素的供需信号,市场竞争机制有利于提高绿色技术创新企业的市场竞争力;市场的价格机制有利于绿色技术创新企业的价值实现。最后,结合我国绿色技术创新发展实践提出6点建议:以解决突出矛盾为导向,精准设计市场规制措施;以优化顶层设计为起点,实现多主体协同发力;强化知识产权保护,制定绿色产业专利战略;多管齐下促进绿色消费,引导企业绿色技术创新;完善绿色标准和标识制度,倒逼绿色技术升级;建立绿色技术创新发展评估体系,有针对性地提高市场规制效率。     

Release characteristics of mercury in chemical looping combustion of bituminous coal

This study evaluated the release characteristics of mercury from bituminous coal in chemical looping combustion (CLC) using Australian iron ore as the oxygen carrier in a fixed bed reactor. The effects of several parameters, such as temperature in the fuel reactor (FR) and air reactor (AR), gasification medium in the FR, and reaction atmosphere in the AR, on mercury release characteristics, were investigated. The mercury speciation and release amount in the FR and AR under different conditions were further explored. The results indicate that most of the mercury in coal was released in the FR, while the rest of it was released in the AR. Hg⁰ was found to be the major species in the released mercury. The results also indicate that a higher temperature in the FR led to an increase in the total mercury release amount and a decrease in Hg⁰ proportion. However, a higher temperature in the AR resulted in a decrease in the total mercury release amount and Hg⁰ proportion. The increase in the H₂O/CO₂ ratio of gasification mediums in the FR was beneficial for the increase in the total mercury release amount and Hg⁰ proportion. A higher O₂ concentration in reaction atmosphere in AR had a negligible effect on the total mercury release amount, but a positive effect on Hg⁰ oxidization.     

中石化江苏成品油一次配送空间格局与优化

基于详实准确的政府及企业调研数据,以中石化江苏成品油一次配送为例,从配置效益和空间结构视角出发,借助运用地理网络分析和线性优化模型等方法,通过单位输油成本计算、优化情景构建计算和成品油配送格局比较分析,系统解析成品油一次配送空间格局与优化配置情况,从理论上尝试探讨其地理网络结构。研究发现：优化情境下的成本较2017年实际状况减少了30%左右,表明中石化江苏成品油一次配送效益不够优化;理论上,根据成品油“就近配置”原则,不同炼油企业各自在其优化情景区界内,配送单位输油成本较低的成品油;实际上,由于炼油企业的炼油能力差异、成品油输油通道不完善和分销中心油库设置差异等原因,不同炼油企业之间存在着相较优化情景区界或大或小的实际输油区界,且存在着某些分销中心油库同时接纳不同炼油企业成品油的现象,即存在混合输油区域。     

基于控制单元划分的南海区广佛跨界水环境治理工程效果评估

针对南海区广佛跨界区域的水系分布特点划分控制单元,通过对2018年区域内治水工程的调研分析,定量分析治水工程效果。跨界区域各控制单元中,水口水道的COD和NH₃-N削减量最大,占比分别为42.9%和62.9%;西南涌的TP削减量最大,占比为60.1%;按行政区划分析大沥镇对COD和NH₃-N的削减贡献最大,占比分别为29.8%和35.4%;狮山镇对TP的削减贡献最大,占比为62.9%。通过建立污染物削减量与水质指标的响应关系,对控制单元合理性进行分析,并提出相应的污染防治对策,可为管理部门制定水污染防治计划及环境整治工程提供技术支持。     

城市雨洪过程模拟GPU加速计算效率研究

为量化分析GPU加速技术在城市雨洪过程模拟计算中效率提升效果,采用基于GPU技术的数值模型,对不同降雨及网格分辨率情形下的典型城市雨洪过程进行模拟,并对比分析GPU加速计算效率及其规律。结果表明:城市雨洪过程模拟中,GPU加速技术较CPU技术具有优势,不同情形下可提速23.88~158.72倍;在大暴雨和高分辨率网格条件下,GPU模型的提速效果更加明显,相较于短重现期降雨及低分辨率网格情形提升0.29%~8.43%,表明该技术适用于大范围高分辨率问题的模拟。该成果可为城市洪涝过程快速模拟预报提供技术支持。     

Nitrate removal from aqueous solutions by magnetic cationic hydrogel: Effect of electrostatic adsorption and mechanism

Excessive nitrate(NO_3~-) is among the most problematic surface water and groundwater pollutants.In this study,a type of magnetic cationic hydrogel(MCH) is employed for NO_3~-adsorption and well characterized herein.Its adsorption capacity is considerably pHdependent and achieves the optimal adsorption(maximum NO_3~--adsorption capacity is95.88±1.24 mg/g) when the pH level is 5.2-8.8.The fitting result using the homogeneous surface diffusion model indicates that the surface/film diffusion controls the adsorption rate,and NO_3~-approaches the center of MCH particles within 30 min.The diffusion coefficient(D_s) and external mass transfer coefficient(k_F) in the liquid phase are1.15 × 10~(-6) cm~2/min and 4.5 × 10~(-6) cm/min,respectively.The MCH is employed to treat surface water that contains 10 mg/L of NO_3~-,and it is found that the optimal magnetic separation time is 1.6 min.The high-efficiency mass transfer and magnetic separation of MCH during the adsorption-regeneration process favors its application in surface water treatment.Furthermore,the study of the mechanism involved reveals that both-N~+(CH_3)_3 groups and NO_3~-are convoluted in adsorption via electrostatic interactions.It is further found that ion exchange between NO_3~-and chlorine occurs.     

Emissions of intermediate volatility organic compound from waste cooking oil biodiesel and marine gas oil on a ship auxiliary engine

Ship auxiliary engines contribute large amounts of air pollutants when at berth.Biodiesel,including that from waste cooking oil(WCO),can favor a reduction in the emission of primary pollutant when used with internal combustion engines.This study investigated the emissions of gaseous intermediate-volatile organic compounds(IVOCs) between WCO biodiesel and marine gas oil(MGO) to further understand the differences in secondary organic aerosol(SOA) production of exhausts.Results revealed that WCO exhaust exhibited similar IVOC composition and volatility distribution to MGO exhaust,despite the differences between fuel contents.While WCO biodiesel could reduce IVOC emissions by 50% as compared to MGO,and thus reduced the SOA production from IVOCs.The compositions and volatility distributions of exhaust IVOCs varied to those of their fuels,implying that fuel-component-based SOA predicting model should be used with more cautions when assessing SOA production of WCO and MGO exhausts.WCO biodiesel is a cleaner fuel comparing to conventional MGO on ship auxiliary engines with regard to the reductions in gaseous IVOC emissions and corresponding SOA productions.Although the tests were conducted on test bench,the results could be considered as representative due to the widely applications of the test engine and MGO fuel on real-world ships.     

2017—2018年秋冬季唐山市PM2.5中元素组成特征及来源解析

为研究唐山市大气PM_2.5中元素组成特征及其来源,于2017年10月19日—2018年1月31日（秋冬季）在唐山市的超级站（典型城市站点）、开平站（工业站点）和古冶站（工业站点）开展了PM_2.5的手工连续采样,定量分析测定了PM_2.5中23种无机元素.结果表明:Si、Al、Ca和Na等地壳元素的质量浓度均在10月最高,在1月最低.10月,ρ（Cr）在开平站最高（0.020 0 μg/m3）,随后逐月略微降低,其主要受钢铁冶炼工业的减产和限产影响.多数重金属元素质量浓度在11月或12月最高,包括Zn、Pb、Mn、Cu、Ni、Se、V、Cd和Co,其可能受燃煤取暖影响.Cd、Zn、Pb和Cu四种元素的富集因子值分别为2 677、616、422和77,均达到极强富集,且均受人为排放源影响最大.基于因子分析法得出,唐山市大气PM_2.5中元素的主要来源有燃煤源、钢铁工业源与扬尘源的混合源、交通源以及土壤扬尘源,其方差贡献率分别为56.3%、21.6%、7.1%、5.4%.研究显示,秋冬季唐山市大气颗粒物PM_2.5中元素最主要的污染来源为工业源、燃煤源和扬尘源.