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61.
光释光信号积分区间的选择对等效剂量(D e )的估算有重要影响。光释光衰减曲线并非单一的指数衰减,而由多个指数衰减函数组成,且每个衰减函数代表不同的信号组分。因矿物晶格陷阱类型不同,各组分有不同的衰减率、热稳定性等。本文对采自青藏高原东缘4个典型黄土分布区的黄土样品进行了系统的石英光释光组分分析和背景区间扣除研究。结果发现:(1)高原东缘黄土石英光释光信号由快、中、慢组分组成,并以快组分占主导,适合用单片再生剂量法测定等效剂量;(2)不同背景区间扣除对小于10 Gy样品等效剂量结果影响较小,误差范围内一致;(3)对大于10 Gy样品,选取早、晚不同背景区间扣除其等效剂量结果差异显著,两者差值占晚期背景扣除所得D e 值的10%—38%,且有随D e 值增加而增大的趋势,因此计算大于10 Gy样品D e 时应慎重选择积分区间。 相似文献
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63.
电化学氧化法去除微污染水中的氨氮 总被引:1,自引:1,他引:0
以低氯离子浓度下微污染水中的氨氮(NH4+-N)为研究对象,采用电化学氧化法对污染水中的氨氮进行去除。通过静态和正交实验得到了极板的最佳运行参数。实验结果表明:Cl-浓度在各影响因素中对NH4+-N去除影响最大,且在其他影响因素不变的条件下,通过改变电解电流是解决动态运行时NH4+-N去除率下降较经济有效的方法。最佳运行工艺条件为:电流密度10 mA/cm2,电解时间10 min,极板间距1 cm,溶液初始pH为7,Cl-浓度100 mg/L,面体比102 m2/m3,氨氮的平均去除率在80%以上。 相似文献
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65.
Manoj Menon Svetla Rousseva Nikolaos P. Nikolaidis Pauline van Gaans Panos Panagos Danielle Maia de Souza Kristin Vala Ragnarsdottir Georg J. Lair Liping Weng Jaap Bloem Pavel Kram Martin Novak Brynhildur Davidsdottir Gudrun Gisladottir David A. Robinson Brian Reynolds Tim White Lars Lundin Bin Zhang Christopher Duffy Stefano M. Bernasconi Peter de Ruiter Winfried E. H. Blum Steven A. Banwart 《Environmental science and pollution research international》2014,21(4):3191-3195
Soil is a complex natural resource that is considered non-renewable in policy frameworks, and it plays a key role in maintaining a variety of ecosystem services (ES) and life-sustaining material cycles within the Earth's Critical Zone (CZ). However, currently, the ability of soil to deliver these services is being drastically reduced in many locations, and global loss of soil ecosystem services is estimated to increase each year as a result of many different threats, such as erosion and soil carbon loss. The European Union Thematic Strategy for Soil Protection alerts policy makers of the need to protect soil and proposes measures to mitigate soil degradation. In this context, the European Commission-funded research project on Soil Transformations in European Catchments (SoilTrEC) aims to quantify the processes that deliver soil ecosystem services in the Earth's Critical Zone and to quantify the impacts of environmental change on key soil functions. This is achieved by integrating the research results into decision-support tools and applying methods of economic valuation to soil ecosystem services. In this paper, we provide an overview of the SoilTrEC project, its organization, partnerships and implementation. 相似文献
66.
微波辅助Cu(Ⅱ)-Fenton体系催化氧化处理对硝基苯酚废水 总被引:1,自引:0,他引:1
为了拓宽Fenton反应pH范围,提高降解效率、减少药剂用量,向Fenton体系中添加辅助催化剂Cu(Ⅱ),并对微波辅助催化氧化对硝基苯酚(PNP)模拟废水工艺进行了研究。提出微波辐照-放置处理工艺,并与普通全过程微波处理工艺进行了比较。结果表明,该体系处理工艺将Fenton反应最佳pH范围由2.0~3.5拓宽到2.0~5.5;在pH=5.0时,对于100 mg/L的PNP溶液,当[Cu2+]=0.8 mg/L、[Fe2+]=3.0 mg/L、[H2O2]=0.2 g/L,微波功率250 W,辐照2.0 min、放置4.0 min,PNP去除率可达98%以上;辅助催化剂Cu2+的加入增强了氧化效果,同时节约药品20%以上。通过对比实验发现,Cu2+与Fe2+发生了某种作用机制,联合促进了体系中·OH的生成。该反应体系不仅将传统Fenton反应体系狭窄的pH值范围延伸到接近中性的区域5.0~5.5,又可在短时间内使PNP去除率达到98%以上。 相似文献
67.
Wulff S Lindelöw Å Lundin L Hansson P Axelsson AL Barklund P Wijk S Ståhl G 《Environmental monitoring and assessment》2012,184(4):2453-2464
A revised Swedish forest health assessment system is presented. The assessment system is composed of several interacting components
which target information needs for strategic and operational decision making and accommodate a continuously expanding knowledge
base. The main motivation for separating information for strategic and operational decision making is that major damage outbreaks
are often scattered throughout the landscape. Generally, large-scale inventories (such as national forest inventories) cannot
provide adequate information for mitigation measures. In addition to broad monitoring programs that provide time-series information
on known damaging agents and their effects, there is also a need for local and regional inventories adapted to specific damage
events. While information for decision making is the major focus of the health assessment system, the system also contributes
to expanding the knowledge base of forest conditions. For example, the integrated monitoring programs provide a better understanding
of ecological processes linked to forest health. The new health assessment system should be able to respond to the need for
quick and reliable information and thus will be an important part of the future monitoring of Swedish forests. 相似文献
68.
Distribution and risk assessment of polycyclic aromatic hydrocarbons (PAHs) from Liaohe estuarine wetland soils 总被引:2,自引:0,他引:2
Thirty-one surface soil samples were collected from Liaohe estuarine wetland in October 2008 and May and August 2009. The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs), identified as priority pollutants by the US EPA, were measured by gas chromatography. PAHs were predominated by three- and four-ring compounds. The total PAH concentrations ranged from 704.7 to 1,804.5 μg/kg with a mean value of 1,001.9 μg/kg in October 2008, from 509.7 to 1,936.9 μg/kg with an average of 887.1 μg/kg in May 2009, and from 293.4 to 1,735.9 μg/kg with a mean value of 675.4 μg/kg in August 2009. The PAH concentration detected at most sites shared the same pattern, with maximum concentrations during the autumn (October) and minimum concentrations during the summer (August). The ecological risk assessment of PAHs showed that adverse effects would occasionally occur in the soils from Liaohe estuarine wetland based on the effects range low (ERL)/effects range median and the toxic equivalency factors. The results revealed that some of the individual PAHs were in excess of ERL which implied possible acute adverse biological effects. The BaP(eq) values in some sites surpassed the Dutch target value. Therewith, quite a part of soils in the wetland were subjected to potential ecological risks. 相似文献
69.
Ding Guanghui Li Xueyao Zhang Jing Zhang Nannan Li Ruijuan Wang Yingying Yang Zhanning Peijnenburg Willie J. G. M. 《Environmental science and pollution research international》2019,26(25):25538-25549
Environmental Science and Pollution Research - Environmental waters cover a range of water quality characteristics which could greatly affect the behavior and fate of C60 in the aquatic... 相似文献
70.
上海市郊春节期间大气颗粒物及其组分的粒径分布 总被引:5,自引:0,他引:5
利用电称低压冲击仪(ELPI)在线监测上海市嘉定区2009年春节前后不同粒径(50%切割粒径分别为:0.03、0.06、0.11、0.17、0.26、0.40、0.65、1.00、1.60、2.50、4.40、6.80μm)大气颗粒物的粒子数浓度变化.对比春节与非节日期间该地区大气颗粒物(<0.49、0.49—0.95、0.95—1.50、1.50—3.00、3.00—7.20、>7.20μm)中Na、Mg、Al、K、Ca、Ti、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、As、Se、Pb 17种元素,F-、Cl-、NO 2-、SO24-、NO 3-、Na+、NH 4+、K+、Mg2+、Ca2+10种离子与有机碳(OC)、元素碳(EC)质量浓度的粒径分布.结果表明,春节对于大气颗粒物粒子数浓度的影响主要集中在0.11—1.60μm.如果以3.00μm为界将大气颗粒物划分成细(≤3.00μm)和粗(>3.00μm)颗粒物时,春节影响体现在细颗粒的元素为:Na、As、Pb,且主要集中于<0.49μm颗粒中;春节影响集中于大颗粒(>7.20μm)的元素为:Ni、Co;没有受到显著影响的为:Ca、V、Mn、Fe、Z... 相似文献