Reactions of model compounds of phenol resin in sub- and supercritical water under an argon atmosphere

Model compounds of phenol resin were reacted in sub- and supercritical water to clarify the mechanism of the decomposition reaction of plastics in water. Cleavage reaction of methylene bonds was confirmed in the reactions of model compounds of phenol resin such as bis(hydroxyphenyl)methanes in sub- and supercritical water under an Ar atmosphere, although the methylene bond was stable in thermal reactions. It was also confirmed that sub- and supercritical water played important roles not only as a stable solvent thermally, but also as a chemical reagent. Received: July 19, 2000 / Accepted: September 14, 2000     

Dioxins in human milk and smoking of mothers

BACKGROUND: The relation between the levels of dioxins in human breast milk and the smoking habits of the mothers is controversial. To clarify this relationship, we analyzed data from the human milk survey in Japan. METHODS: The human milk survey has been conducted in Japan since 1997. Healthy pregnant women aged 20-39 years were recruited and 50 ml of breast milk was collected from them at 30 days after delivery. PCDDs, PCDFs, and dioxin-like PCBs were measured by using GC/MS. The smoking habits of the mothers were established by interviewing them soon after delivery and were classified into four categories: current smokers, ever smokers who quit smoking at the pregnancy, ever smokers who quit smoking before the pregnancy, and never smokers. The levels of dioxins in breast milk were compared in the four categories of smoking among 853 primiparas. In addition, we analyzed the association between dioxin levels and passive smoking among never smokers. The geometric means of the dioxin concentrations were calculated in order to compare the differences between dioxins. RESULTS: The geometric means of dioxin-like PCBs in milk of never smokers was the highest (9.2 pg TEQ/g fat); followed by ever smokers who quit smoking before the pregnancy, ever smokers who quit smoking at the pregnancy, and current smokers (7.5, 7.2, and 6.6 pg TEQ/g fat, respectively). The differences between these levels were statistically significant (ANOVA, p<0.001). No significant difference was observed between the level of dioxins in milk from never smokers subjected to passive smoking status and those who had not experienced passive smoking. CONCLUSION: The levels of dioxin-like PCBs in human milk were negatively related to the smoking habits of mothers.     

Stabilities of 58 volatile organic compounds in fused-silica-lined and SUMMA polished canisters under various humidified conditions

Fused-silica-lined (FSL) canisters and SUMMA polished (SUMMA) canisters were compared for the recoveries and the stabilities of 58 volatile organic compounds (VOCs) at low ppbv (volume/volume) levels under various humidified conditions using a three-stage preconcentration method followed by GC-MS analysis. The target VOCs included non-polar VOCs (e.g. halogenated hydrocarbons and aromatic hydrocarbons) and polar VOCs (e.g. alcohols, ketones, esters, ethers, nitriles and thiols). The three-stage preconcentration method was initially optimized for simultaneous analysis of non-polar and polar VOCs because determination of canister stability is dependent on the accuracy of analytical measurements. The method showed good linearity over the concentration range from 1 to 25 ppbv for all target analytes, and the correlation coefficients were higher than 0.9974. The method detection limits ranged from 0.023 to 0.39 ppbv. The test mixtures loaded in both type of canisters (n = 3) had concentrations of 1.7-2.5 ppbv per compound at ambient pressure under various humidified conditions (%RH = 1.6, 8.0, 27, 39, 53 and >99% with excess water present). All canister samples were initially analyzed on day 0 (after 6-12 h). The effect of competitive adsorption of water vapor and polar VOCs on active sites of interior surface was remarkably observed for SUMMA canisters. Polar VOCs had a greater requirement for water vapor to be present. The RH percentages that ensured good recovery on day 0 were RH > 8% for non-polar VOCs and RH > 27% for polar VOCs (except alcohols under the condition of RH > 99%). All thiols were not recovered from SUMMA canisters under all conditions. FSL canisters showed good recoveries of more than 86% for all VOCs under all conditions on day 0 (except alcohols under the condition of RH > 99%). The recoveries of alcohols in both canisters under the condition of RH > 99% displayed relatively low recoveries in the range 25-76% because of the partitioning effect into condensed water. The canister samples under the conditions of RH 8.0, 27, 53 and > 99% were analyzed for the stability test on days 3, 7, 14 and 28 after loading. All non-polar VOCs were reasonably stable in the FSL canisters under all examined conditions over 28 days. However, several polar VOCs that have relatively lower vapor pressure, e.g. MIBK, butyl acetate and alcohols except ethanol, showed unstable characteristics under relatively dry conditions (RH 8 and 27%) during 28 days. RH > 53% was needed to ensure good stabilities of all analytes except thiols with the recoveries of > 80% over 28 days for both canisters. Although the FSL canister showed good recoveries of more than 86% for thiols on day 0, drastic degradations were observed after day 3 and they were not detected after day 14.     

Public policy, private landholders: perspectives on policy mechanisms for sustainable land management

A variety of tools can be employed in support of environmental policy objectives, but achieving preferred outcomes also requires the cooperation of private landholders and others with vested interests in the land. The Land Stewardship project in the state of Victoria, Australia, is an initiative devoted to exploring the ways in which private landholders could be encouraged towards more sustainable land management. Following the view that the success of policy initiatives is contingent on effective stakeholder engagement, a component of the Land Stewardship project involved a dialogue with landholders about policy tools (e.g., regulation, economic instruments) that might be deployed to encourage improved land management practices. This paper provides an account of the views and attitudes of landholders, as revealed in a series of three workshops, which consisted of discussions about the factors influencing agriculture, participants' interpretations of sustainability, and policy methods. The focus of the paper is on what landholders believe to be the strengths and limitations of standard policy tools, and the essential requirements for these tools to deliver the best land management outcomes. One of the main findings of the project was a 'preference hierarchy' in respect of policy methods, according to which the strongest support was expressed for voluntary and education-based tools, followed by market-based instruments, with command-and-control regulation identified as a measure of 'last resort'. In the paper we reflect also on how the views and outlook of landholders should be positioned relative to other inputs in the design of policy interventions.     

“The right to food is nature too”: food justice and everyday environmental expertise in the Salvadoran permaculture movement

In El Salvador a growing permaculture movement attunes small-scale farming activities to principles of ecological observation. The premise is twofold: close-grained appreciation of already-interacting biophysical processes allows for the design of complementary social and agricultural systems requiring minimum energy inputs. Secondly, the insistence on campesino smallholders as actors in the design of sustainable food systems directly addresses decades of “top-down” developmental interventions, from Green Revolution experiments in the 1960s and 1970s to international food security programmes in the 1990s. Permaculture connects food insecurity to the delegitimisation of smallholder innovation and insists that, through sharing simple techniques, campesino farmers can contribute towards future-oriented questions of environmental sustainability. This repositioning is brought about through the mobilisation of pedagogical techniques that legitimise the experiences and expertise of small-scale farmers, while standardising experimental methods for testing, evaluating and sharing agroecological practices. Like food sovereignty and food justice movements, Salvadoran permaculture links hunger with longer histories of (uneven) capital accumulation and dispossession and renders campesino farmers its protagonists. By modelling a form of expertise premised in intimate involvement with specific environments, permaculture goes still further, seeking to dislodge a pervasive knowledge politics that situates some as knowers and innovators, and others as passive recipients. This grounds human rights in an ethos of caring for the “more-than-human” world and places emphasis on a corollary right as part of food justice, increasingly being demanded “from below”: the right to know.     

Principal components derived from soil physicochemical data explained a land degradation gradient,and suggested the applicability of new indexes for estimation of soil productivity in the Sakaerat Environmental Research Station,Thailand

To find a principal component (PC) that quantifies the degree of soil degradation, we analyzed various physicochemical characteristics of soils over a land degradation gradient related to aboveground vegetation in the Sakacrat Environmental Research Station (SERS), Thailand. The aboveground vegetative types representing the degradation gradient were bare ground (BG, highly degraded), dry dipterocarp forest (DDF, moderately disturbed) and dry evergreen forest (DEF, the original vegetation). Soils under these vegetative types were sampled in February (dry season). March just after temporal precipitation) and June (rainy season) 2001. Through the period of this research, the degradation was consistently explained by sandy texture, high bulk density, lower pH, high exchangeable acidity, poor mineral and organic nutrients and dryness. Principal component analysis (PCA) was applied to determine significant principal components (PCs) that clarify the differences in soil properties between the vegetative types and between the timing of soil sampling. The PC loadings suggested that the first PC was the component that indicates total fertility of soil in the site, while the fifth PC indicates the dry to wet seasonal transition. The first PC was named the total fertility component (TFC). The linear regression between the TFC score and recently proposed indexes, the soil fertility index (SFI) or the soil evaluation factor (SEF), was highly significant (p < 0.001), indicating that the SFI and the SEF are applicable to measuring total fertility of soils in the SERS.     

Perspectives on area-based conservation and its meaning for future biodiversity policy

During 2021, Parties to the Convention on Biological Diversity (CBD) are expected to meet in Kunming, China, to agree on a new global biodiversity framework aimed at halting and reversing biodiversity loss, encouraging the sustainable use of biodiversity, and ensuring the equitable sharing of its benefits. As the post-2020 global biodiversity framework evolves, parties to the convention are being exposed to a range of perspectives on the conservation and sustainable use of biodiversity, relating to the future framework as a whole or to aspects of it. Area-based conservation measures are one such aspect, and there are diverse perspectives on how new targets might be framed in relation to these measures. These perspectives represent different outlooks on the relationship between human and nonhuman life on Earth. However, in most cases there is a lack of clarity on how they would be implemented in practice, the implications this would have for biodiversity and human well-being, and how they would contribute to achieving the 2050 Vision for Biodiversity of “living in harmony with nature.” We sought to clarify these issues by summarizing some of these perspectives in relation to the future of area-based biodiversity conservation. We identified these perspectives through a review of the literature and expert consultation workshops and compiled them into 4 main groups: Aichi+, ambitious area-based conservation perspectives, new conservation, and whole-earth conservation. We found that although the perspectives Aichi+ and whole earth are in some cases at odds with one another, they also have commonalities, and all perspectives have elements that can contribute to developing and implementing the post-2020 global biodiversity framework and achieving the longer term CBD 2050 Vision.     

Development of plant communities on set-aside in England

A survey of land taken out of production from the early 1990s onwards under the European Union's set-aside policy in England was carried out in 2008, to record plant communities in set-aside of different ages, effects of distance from the field edge, sowing and soil type. Communities were classified using the Countryside Vegetation System (CVS), Ellenberg indicators and Grime CSR strategy. Species richness declined with distance from the field boundary. Annuals declined with age of set-aside. In older set-aside, perennials dominated, 40-50% of species were grasses, and grasses covered over 70% of the area. Sown areas had a higher proportion of grass species and a lower proportion of wind-dispersed species. Perennial forbs increased over time in naturally regenerated swards but decreased on sown swards. Annuals and grasses were more prevalent on light soils, with more bare ground on heavy soils. Most transects fell into CVS aggregate classes ‘tall grassland/herb’ and ‘fertile grassland’. Ellenberg fertility values decreased initially but then stabilised. Competitor scores increased, and ruderal scores declined, with age. In general, the rate of change declined with age. Although few sites had plant communities of significant conservation interest, the value of set-aside is likely to be primarily to maintain botanical diversity in intensively farmed areas, as well as providing food and habitat for fauna.     

Differential aggressiveness between fire salamander (<Emphasis Type="Italic">Salamandra infraimmaculata</Emphasis>) larvae covaries with their genetic similarity

Responding differentially to kin and non-kin is known to be adaptive in many species. One example is the inclusive fitness benefits of reducing aggression toward closer relatives. Little is known, however, about the ability of animals to assess differential degrees of genetic relatedness and to respond accordingly with differential levels of aggression. In the present study, we tested whether aggressiveness between body mass-matched pairs of fire salamander (Salamandra infraimmaculata) larvae covaried with the genetic similarity between them. We quantified aggressiveness at three levels of genetic similarity by selecting pairs within and across pools from recently genotyped populations. We also assessed aggression between pairs of siblings. Aggression and associated injuries decreased as genetic similarity increased across the groups. These findings suggest that cannibalistic salamanders can assess their degree of genetic relatedness to conspecifics and vary their behavioral responses depending on the degree of similarity between them along a genetic relatedness continuum.