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151.
Identification of sources of elevated concentrations of polycyclic aromatic hydrocarbons in an industrial area in Tianjin, China 总被引:2,自引:0,他引:2
Wentao Jiao Yonglong Lu Jing Li Jingyi Han Tieyu Wang Wei Luo Yajuan Shi Guang Wang 《Environmental monitoring and assessment》2009,158(1-4):581-592
The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) were determined by gas chromatography equipped with a mass spectrometry detector in 105 topsoil samples from an industrial area around Bohai Bay, Tianjin in the North of China. Results demonstrated that concentrations of PAHs in 104 soil samples from this area ranged from 68.7 to 5,590 ng g???1 dry weight with a mean of ∑16PAHs 814 ± 813 ng g???1, which suggests that there exists mid to high levels of PAH contamination. The concentration of ∑16PAHs in one soil sample from Tianjin Port was exceptionally high (48,700 ng g???1). Ninety-three of the 105 soil samples were considered to be contaminated with PAHs (>200 ng g???1), and 25 were heavily polluted (>1,000 ng g???1). The sites with high PAHs concentration are mainly distributed around chemical industry parks and near highways. Two low molecular weight PAHs, naphthalene and phenanthrene, were the dominant components in the soil samples, which accounted for 22.1% and 10.7% of the ∑16PAHs concentration, respectively. According to the observed molecular indices, house heating in winter, straw stalk combustion in open areas after harvest, and petroleum input were common sources of PAHs in this area, while factory discharge and vehicle exhaust were the major sources around chemical industrial parks and near highways. Biological processes were probably another main source of low molecular weight PAHs. 相似文献
152.
153.
Han Qu Hongting Diao Jiajun Han Bin Wang Gang Yu 《Frontiers of Environmental Science & Engineering》2023,17(1):12
Over the past decades, the plastic production has been dramatically increased. Indeed, a category of small plastic particles mainly with the shapes of fragments, fibers, or spheres, called microplastics (particles smaller than 5 mm) and nanoplastics (particles smaller than 1 μm) have attracted particular attention. Because of its wide distribution in the environment and potential adverse effects to animal and human, microplastic pollution has been reported as a serious environment problem receiving increased attention in recent years. As one of the commonly detected emerging contaminants in the environment, recent evidence indicates that the concentration of microplastics show an increasing trend, for the reason that up to 12.7 million metric tons of plastic litter is released into aquatic environment from land-based sources each year. Furthermore, microplastic exposure levels of model organisms in laboratory studies are usually several orders of magnitude higher than those found in environment, and the microplastics exposure conditions are also different with those observed in the environment. Additionally, the detection of microplastics in feces indicates that they can be excreted out of the bodies of animal and human. Hence, great uncertainties might exist in microplastics exposure and health risk assessment based on current studies, which might be exaggerated. Policies reduce microplastic emission sources and hence minimize their environmental risks are determined. To promote the above policies, we must first overcome the technical obstacles of detecting microplastics in various samples. 相似文献
154.
低压离子色谱法测定水和酸雨样品中的Li~+,Na~+,NH_4~+,K~+,Ca~(2+)和Mg~(2+)离子 总被引:3,自引:0,他引:3
本文介绍了低压离子色谱仪测定水样(井水、湖水、矿泉水、自来水)和酸雨中锂、钠、铵、钙、钾和镁离子的方法、欲测阳离子在阳离子交换柱上被分离,分别用1.4mmol·1~(-1)HNO_3和0.6mmol·1~(-1)乙二胺+1.2mmol·1~(-1)HNO_3溶液作流动相,流速为1.6ml·min~(-1).各离子的流分用电导检测.进样量为10μl时,Li~+,Na~+,NH_4~+,K~+,Ca~(2+)和Mg~(2+)离子的检出限(2倍噪音比),分别为0.020,0.050,0.100,0.250,2.5和1.0μg·ml~(-1). 相似文献
155.
单甲脒农药对土壤微生物种群和土壤酶活性的影响 总被引:9,自引:0,他引:9
研究了单甲脒(N'-2,4-二甲苯基-N-甲基甲脒,简称DMA)对土壤微生物种群和土壤酶活性的影响.田间试验表明,喷洒单甲脒盐酸盐(DMAH)于棉花植株对土壤微生物种群和土壤酶活性无明显影响.实验室试验表明,投加DMAH于土壤对土壤微生物种群有不同的抑制作用;当DMAH在土壤中的浓度为20mg/g时,好氧异养菌总量开始降低,硝化细菌和放线菌、真菌的土壤DMAH抑制浓度分别为0.5mg/g和0.1mg/g.DMAH对土壤酶活性的影响亦不相同,脱氢酶对土壤中DMAH含量为10mg/g时其活性即有明显的减弱,而过氧化氨酶对DMA的耐受性相当高,其活性的抑制浓度达500mg/g.试验还证明了土壤中DMA的微生物降解作用.当DMA在土壤中的浓度为50~500g/g时,其消解速率可从8.75mm·kg-1·d-1提高到48mg·kg-1·d-1. 相似文献
156.
我国是世界化学品生产和贸易的大国。大量化学品的生产和进出口贸易给我国化学品风险管理和风险评估带来了巨大挑战。在借鉴发达国家和经济组织对化学品风险管理经验和评估技术的基础上,我国在近年来也逐步开展了化学品的管理和控制,以应对当前日益突出的化学品环境安全和健康安全事故。本文从我国化学品管理与国外化学品风险管理之间的对比出发,在梳理化学品管理政策发展的过程中,重点就我国环境保护部门对有毒和进口化学品、新化学物质和废弃危险化学品以及质检部门对进出口工业化学品的管理和控制措施,以及化学品的评估技术进行了综述。通过与发达国家就化学品风险管理与评估技术的对比,指出我国目前化学品管理和评估的不足与欠缺,并提出一些可行的应对措施与办法,为完善我国化学品风险管理和评估提供一定的参考。 相似文献
157.
以壳聚糖/蒙脱土插层复合物为载体,吸附法制备固定化多酚氧化酶,并以此催化氧化去除水中的苯酚、4-氯苯酚和2,4-二氯苯酚.考察了固定化多酚氧化酶的制备条件,对酚类化合物的催化氧化条件、动力学特性以及固定化酶的重复使用性能.结果表明,固定化多酚氧化酶的最佳制备条件为p H 5.0,酶与载体质量比20 mg·g-1,固定化6 h,所得固定化酶的载酶量为12.12 mg·g-1,每克单位载体酶活为12.76×103U·g-1.固定化多酚氧化酶对酚类化合物的最佳去除条件为:苯酚溶液p H 7.0,温度30℃;4-氯苯酚溶液p H 5.0,温度20℃;2,4-二氯苯酚溶液p H 5.0,温度30℃.在最佳反应条件下,酶与底物质量比为20 mg·mg-1时,固定化多酚氧化酶对苯酚、4-氯苯酚和2,4-二氯苯酚溶液去除率分别为63.6%、85.8%和87.8%.苯酚、4-氯苯酚和2,4-二氯苯酚的米氏常数Km值依次减小,最大反应速率Vmax依次增大,表明固定化酶对2,4-二氯苯酚的亲和力最强,催化速度最快.固定化酶循环使用6次(24 h)后对苯酚、4-氯苯酚和2,4-二氯苯酚的去除率分别为15.7%、24.2%和27.8%. 相似文献
158.
Lamei Lei Liang Peng Xianghui Huang Bo-Ping Han 《Environmental monitoring and assessment》2014,186(5):3079-3090
The tropical cyanobacterium Cylindrospermopsis raciborskii is of particular concern for its invasive characteristics and production of the toxin cylindrospermopsin (CYN). The present study represents the first attempt to determine the distribution of C. raciborskii and CYN in tropical China. The presence of C. raciborskii and CYN, as well as the composition of phytoplankton, was determined from a total of 86 samples from 25 urban reservoirs for drinking water supply in Dongguan City of South China. The presence of C. raciborskii was observed in 21 of the 25 reservoirs and confirmed that this species has been widely distributed in the investigated reservoirs. C. raciborskii accounted for between 0.1 and 90.3 % of the total phytoplankton biomass and contributed to the majority of the phytoplankton in some reservoirs such as Tangkengbian and Xiagongyan. Its biomass was negatively correlated with NO3 ?-N concentration and Secchi depth. Dissolved CYN was detected in more than one-half of the reservoirs with concentrations up to 8.25 μg L?1, and it positively correlated with C. raciborskii biomass. Dissolved microcystins (MCs) were detected in 12 of the 25 reservoirs with a maximum concentration 1.99 μg L?1. Our data strongly suggest that C. raciborskii and CYN could be important health hazards in urban reservoirs of South China and that more data are needed for further assessment. 相似文献
159.
NaOH溶液对有机相苯酚反萃取的研究 总被引:8,自引:0,他引:8
本文系统进行了NaOH溶液对负载苯酚的TBP+煤油溶剂的反萃取平衡实验。考虑苯酚的支萃取平衡和解离平衡,建立了反萃取的计算模式,并证明了模型的可行性。本文还讨论了NaOH溶液浓度,油水相比,萃取平衡分配系数,溶剂中的负载苯酚浓度和NaOH溶液中初始酚含量对反萃取率的影响。 相似文献
160.
Multivariate Analysis of Interactions Between Phytoplankton Biomass and Environmental Variables in Taihu Lake, China 总被引:1,自引:0,他引:1
Phytoplankton variation in large shallow eutrophic lakes is characterized by high spatial and temporal heterogenity. Understanding
the pattern of phytoplankton variation and the relationships between it and environmental variables can contribute to eutrophic
lakes management. In this study Taihu Lake, one of the largest eutrophic fresh water lake in China, was taken as study area.
The water body of Taihu Lake was divided into five regions viz. Wuli bay (WB), Meilian Bay (MB), West Taihu Lake (WTL), Main
Body of Taihu Lake (MBTL) and East Taihu Lake (ETL). Concentrations of chlorophyll-a and the related environmental variables
were determined in each region in the period 2000–2003. Factor analysis and multivariate analysis were applied to evaluate
the interactions between phytoplankton variation and environmental variables. Results showed that the highest average concentrations
of TN, TP and Chl-a were observed in WB, followed in a descending order by MB and WTL, and the lowest concentrations of TN,
TP and Chl-a were observed in MBTL and ETL. Chl-a and TP concentrations in most regions (except ETL) declined during the study
period. It suggested that to some extent the lake was recovering from eutrophication. However, persistent ascending of TN
and NH4–N in all five regions indicated the deteriorating of water quality in the study period. Results of multivariate showed that
the relationships between phytoplankton biomass and environmental variables varied among regions. TP illustrated itself a
controlling role on phytoplankton in WB, MB, WTL and MBTL according to the significant positive relations to phytoplankton
biomass in these regions. Nitrogen could be identified as a limiting factor to phytoplankton biomass in ETL in view of the
positive correlations between TN and phytoplankton and between NH4–N and phytoplankton. Spatial variation of interactions between phytoplankton and environmental parameters suggested proper
eutrophication control measures were needed to restore ecological system in each region of Taihu Lake. 相似文献